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We discuss the non-equilibrium critical phenomena in liquids, and the models for these phenomena based on local equilibrium and extended scaling assumptions. Special situations are proposed for experimental tests of the theory.…

Statistical Mechanics · Physics 2009-10-31 Alexander Patashinski

The concept of entropy has been pivotal in the formulation of thermodynamics. For systems driven away from thermal equilibrium, a comparable role is played by entropy production and dissipation. Here we provide a comprehensive picture how…

Soft Condensed Matter · Physics 2025-05-15 Robin Bebon , Joshua F. Robinson , Thomas Speck

This paper deals with Coulomb gases at an intermediate temperature regime. We define a local empirical field and identify a critical temperature scaling. We show that if the scaling of the temperature is supercritical, the local empirical…

Probability · Mathematics 2023-05-23 David Padilla-Garza

We divide the free energy near the critical point into two parts. One is the regular part, the other is the singular part. The singular part is assumed to be a concrete possible form. The singular part in this form is different from Widom…

Statistical Mechanics · Physics 2007-05-23 Jianxiang Tian , Yuanxing Gui

The coupling constant dependence is derived in time-dependent {\em current} density functional theory. The scaling relation can be used to check approximate functionals and in conjunction with the adiabatic connection formula to obtain the…

Materials Science · Physics 2009-11-11 Maxime Dion , Kieron Burke

Entropy accumulation near a quantum critical point was expected based on general scaling arguments, and has recently been explicitly observed. We explore this issue further in two canonical models for quantum criticality, with particular…

Strongly Correlated Electrons · Physics 2011-04-04 Jianda Wu , Lijun Zhu , Qimiao Si

We find a thermodynamic description of gas-liquid criticality that is different from van der Waals and mean-field theories. At the critical temperature there is no critical point; a liquid phase coexists with a vapor phase with densities…

Statistical Mechanics · Physics 2012-07-13 Leslie V. Woodcock

Differential geometry is powerful tool to analyze the vapor-liquid critical point on the surface of the thermodynamic equation of state. The existence of usual condition of the critical point $\left( \partial p/\partial V\right) _{T}=0$…

Statistical Mechanics · Physics 2022-05-06 J. S. Yu , X. Zhou , J. F. Chen , W. K. Du , X. Wang , Q. H. Liu

A novel algorithm is presented that yields precise estimates of coexisting liquid and gas densities, $\rho^{\pm}(T)$, from grand canonical Monte Carlo simulations of model fluids near criticality. The algorithm utilizes data for the…

Statistical Mechanics · Physics 2009-11-10 Young C. Kim , Michael E. Fisher

By combining accurate liquid-vapor coexistence and heat-capacity data, we have unambiguously separated two non-analytical contributions of liquid-gas asymmetry in fluid criticality and proved the validity of "complete scaling" [Fisher et…

Statistical Mechanics · Physics 2009-11-11 Mikhail A. Anisimov , Jingtao Wang

We analyze the critical gas-liquid phase behavior of arbitrary fluid mixtures in their coexistence region. We focus on the setting relevant for polydisperse colloids, where the overall density and composition of the system are being…

Soft Condensed Matter · Physics 2019-11-22 Pablo de Castro , Peter Sollich

We present simulations of stochastic fluid dynamics in the vicinity of a critical endpoint belonging to the universality class of the Ising model. This study is motivated by the challenge of modeling the dynamics of critical fluctuations…

Nuclear Theory · Physics 2024-07-23 Chandrodoy Chattopadhyay , Josh Ott , Thomas Schaefer , Vladimir V. Skokov

We analyze the entropic equation of state for a many-particle interacting system in a scale-free network. The analysis is performed in terms of scaling functions which are of fundamental interest in the theory of critical phenomena and have…

Statistical Mechanics · Physics 2011-11-23 C. von Ferber , R. Folk , Yu. Holovatch , R. Kenna , V. Palchykov

We show that for any liquid or solid with strong correlation between its $NVT$ virial and potential-energy equilibrium fluctuations, the temperature is a product of a function of excess entropy per particle and a function of density,…

Soft Condensed Matter · Physics 2012-03-13 Trond S. Ingebrigtsen , Lasse Bøhling , Thomas B. Schrøder , Jeppe C. Dyre

It is shown that the existence of single critical point of the fluid described by van der Waals equation of state is not the hypothesis and it is the consequence of the thermodynamic conditions of liquid-vapor phase equilibrium. It is also…

Statistical Mechanics · Physics 2017-12-06 Ikhtier H. Umirzakov

We consider the scaling behavior of thermodynamic quantities in the one-dimensional transverse-field Ising model near its quantum critical point (QCP). Our study has been motivated by the question about the thermodynamical signatures of…

Strongly Correlated Electrons · Physics 2018-06-20 Jianda Wu , Lijun Zhu , Qimiao Si

Isothermal interfacial zones are investigated starting from a local energy which can be considered as the sum of two terms: one corresponding to a medium with a uniform composition equal to the local one and a second one associated with the…

Mathematical Physics · Physics 2008-12-18 Henri Gouin

The liquid-vapour phase transition near a weakly attractive surface is studied by simulations of the coexistence curves of water in hydrophobic pores. There is a pronounced gradual density depletion of the liquid phase near the surface…

Statistical Mechanics · Physics 2009-11-10 I. Brovchenko , A. Geiger , A. Oleinikova

This paper is the fourth in a series devoted to identifying and explaining the properties of strongly correlating liquids, i.e., liquids where virial and potential energy correlate better than 90% in their thermal equilibrium fluctuations…

Soft Condensed Matter · Physics 2013-01-29 Nicoletta Gnan , Thomas B. Schrøder , Ulf R. Pedersen , Nicholas P. Bailey , Jeppe C. Dyre

Pole-skipping offers compelling evidence for the hydrodynamic origin of chaotic behavior in strongly coupled quantum systems. We demonstrate that the cumulative effect of higher-order corrections to the hydrodynamic diffusive mode, captured…

High Energy Physics - Theory · Physics 2025-05-21 Hyun-Sik Jeong