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Inclusion of heavy metal atoms in a polymer backbone allows transitions between the singlet and triplet manifolds. Interfacial dissociation of triplet excitons constitutes a viable mechanism for enhancing photovoltaic (PV) efficiencies in…

Materials Science · Physics 2009-08-10 K. Yang , U. Scherf , S. Guha

Development of advanced optical data storage, information encryption, and security labeling technologies requires low-cost materials exhibiting local, pronounced, and diverse modification of their structure-dependent optical properties…

One of the main challenges for perovskite solar cells (PSC) is their stability, due to environment-induced perovskite decomposition. The resulting decomposition compounds are mobile and may, therefore, react with charge carrier extraction…

Applied Physics · Physics 2019-09-30 Svetlana Sirotinskaya , Roland Schmechel , Niels Benson

Under external stimuli, lead halide perovskites exhibit large atomic fluctuations, impacting optical and electron transport properties that affect device performance in operational settings. However, a thorough understanding of the atomic…

Ni et al. report minimum bulk trap densities of 10^11 cm-3 and 1-4 orders change in interfacial trap densities derived from drive-level capacitance profiling of lead halide perovskites. From basic electrostatic arguments, we show that such…

Applied Physics · Physics 2020-12-01 Sandheep Ravishankar , Thomas Unold , Thomas Kirchartz

The integrated device of a perovskite solar cell with a Li-ion battery is an innovative solution for decentralized energy storage in smart electronic devices. In this study, we examine the stability of Li ions intercalated in a CsPbI$_3$…

Materials Science · Physics 2025-12-02 Wei Wei , Julian Gebhardt , Daniel F. Urban , Christian Elsässer

The buried interface between the electron transport layer and the perovskite layer suffers from severe interface defects and imperfect energy level alignment. To address this issue, this study employs a multifunctional organic molecule,…

Materials Science · Physics 2024-09-02 Xianhu Wu , Jieyu Bi , Guanglei Cu , Nian Liu , Gaojie Xia , Jilong Sun , Jiaxin Jiang , Ning Lu , Ping Li , Chunyi Zhao , Zewen Zuo , Min Gu

In this work, layered perovskite SBN was investigated in a new doped form for hole as well as electron transport layer (HTL/ETL) in perovskite solar cells. This work was targeted to conclude the effect of tin doping in lanthanum-bismuth…

Materials Science · Physics 2019-05-16 Anurag Pritam , Vaibhav Shrivastava

We explore the interface properties of perovskite heterostructure CsPbBr$_3$/CsPbI$_3$ through first-principles calculations. The structural interface is formed by the bonding of Cs-Br and Cs-I with bond length of $\sim$4.106 and 3.922 \AA.…

Materials Science · Physics 2022-02-15 Jagadish Kumar , K. P. S. S. Hembram

Owing to their exceptional semiconducting properties, hybrid inorganic-organic perovskites show great promise as photovoltaic absorbers. In these materials, long-range diffusion of charge carriers allows for most of the photogenerated…

Halide perovskites belong to an important family of semiconducting materials with unique electronic properties that enable a myriad of applications, especially in photovoltaics and optoelectronics. Their optical properties, including…

Perovskite-organic tandem solar cells (P-O TSCs) hold great promise for next-generation thin-film photovoltaics, with steadily improving power conversion efficiency (PCE). However, the development of optimal interconnecting layers (ICLs)…

Lead halide perovskite-based photoactive layers are nowadays employed for a large number of optoelectronic applications, from solar cells to photodetectors and light-emitting diodes, because of their excellent absorption, emission and…

Perovskite solar cells (PSCs) have emerged as strong contenders for the next generation of photovoltaic (PV) technologies due to their exceptional light absorption properties, tunability, and affordability in manufacturing. Here, we…

Optics · Physics 2026-02-02 Kawshik Nath , Bibekananda Nath , Ahmed Zubair

Halide perovskites are highly promising light-harvesting materials with strong ionic character, enabling in principle the combination of a solar cell and a Li-ion battery in one integrated photo-battery device. Here, we investigate Li ions…

Materials Science · Physics 2024-03-05 Wei Wei , Julian Gebhardt , Daniel F. Urban , Christian Elsässer

We compare three representative high performance PV materials: halide perovskite MAPbI3, CdTe, and GaAs, in terms of photoluminescence (PL) efficiency, PL lineshape, carrier diffusion, and surface recombination, over multiple orders of…

Lead halide perovskites have emerged as promising materials for optoelectronic applications due to their exceptional properties. In the all-inorganic CsPbBr3 perovskites, ferroelastic domains formed during phase transitions enhance bulk…

Achieving control over the transport properties of charge-carriers is a crucial aspect of realizing high-performance electronic materials. In metal-halide perovskites, which offer convenient manufacturing traits and tunability for certain…

The presence of unreacted lead iodide in organic-inorganic lead halide perovskite solar cells is widely correlated with an increase in power conversion efficiency. We investigate the mechanism for this increase by identifying the role of…

Halide double perovskites have recently been proposed as potential environmentally friendly alternatives to organic group and lead based hybrid halide perovskites. In particular, Cs2BiAgX6 have been synthesized and found to exhibit tunable…

Applied Physics · Physics 2019-05-03 Yunting Liang
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