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We present a brief survey of methods that utilize computer simulations and quantum and statistical mechanics in the analysis of electrochemical systems. The methods, Molecular Dynamics and Monte Carlo simulations and quantum-mechanical…

Chemical Physics · Physics 2009-10-15 P. A. Rikvold , I. Abou Hamad , T. Juwono , D. T. Robb , M. A. Novotny

We analyze quantum interference and decoherence effects in single-molecule junctions both experimentally and theoretically by means of the mechanically controlled break junction technique and density-functional theory. We consider the case…

Mesoscale and Nanoscale Physics · Physics 2012-09-26 Stefan Ballmann , Rainer Härtle , Pedro B. Coto , Marcel Mayor , Mark Elbing , Martin R. Bryce , Michael Thoss , Heiko B. Weber

Mean-field molecular dynamics based on path integrals is used to approximate canonical quantum observables for particle systems consisting of nuclei and electrons. A computational bottleneck is the sampling from the Gibbs density of the…

Numerical Analysis · Mathematics 2023-11-30 Xin Huang , Petr Plechac , Mattias Sandberg , Anders Szepessy

Quantum computing aims at exploiting quantum phenomena to efficiently perform computations that are unfeasible even for the most powerful classical supercomputers. Among the promising technological approaches, photonic quantum computing…

Proton transfer reactions are fundamental to many chemical and biological systems, where quantum effects such as tunneling, delocalization, and zero-point motion play key kinetic control roles. However, classical methods capable of…

We explore the near-term intersection of quantum computing with the transport sector. To support near-term integration, we introduce a framework for assessing the suitability of transport optimization problems for obtaining potential…

We study the dynamics of quantum excitations inside macromolecules which can undergo conformational transitions. In the first part of the paper, we use the path integral formalism to rigorously derive a set of coupled equations of motion…

Soft Condensed Matter · Physics 2015-06-04 L. Boninsegna , P. Faccioli

Simulation of the interaction of light with matter, including at the few-photon level, is important for understanding the optical and optoelectronic properties of materials, and for modeling next-generation non-linear spectroscopies that…

Quantum Physics · Physics 2023-02-09 Steve M. Young , Hartmut Häffner , Mohan Sarovar

We present a quaternion-inspired formalism specifically developed to evaluate the electric current that traverses a single molecule subjected to an externally applied voltage. The molecule of interest is covalently connected to two small…

Mesoscale and Nanoscale Physics · Physics 2014-08-06 Augusto C. L. Moreira , Celso P. de Melo

There is a pressing need to develop new rechargeable battery technologies that can offer higher energy storage, faster charging, and lower costs. Despite the success of existing methods for the simulation of battery materials, they can…

We propose an efficient approach for simultaneous prediction of thermal and electronic transport properties in complex materials. Firstly, a highly efficient machine-learned neuroevolution potential is trained using reference data from…

Materials Science · Physics 2024-04-08 Zheyong Fan , Yang Xiao , Yanzhou Wang , Penghua Ying , Shunda Chen , Haikuan Dong

Optimally-shaped electromagnetic fields have the capacity to coherently control the dynamics of quantum systems and thus offer a promising means for controlling molecular transformations relevant to chemical, biological, and materials…

Quantum Physics · Physics 2021-06-08 Alicia B. Magann , Matthew D. Grace , Herschel A. Rabitz , Mohan Sarovar

Quantum computation is based on implementing selected unitary transformations which represent algorithms. A generalized optimal control theory is used to find the driving field that generates a prespecified unitary transformation. The…

Quantum Physics · Physics 2009-11-07 Jose P. Palao , Ronnie Kosloff

A user friendly scheme based on the quantum kinetic equation is developed for studying thermal transport phenomena in the presence of interactions and disorder. We demonstrate that this scheme is suitable for both a systematic perturbative…

Disordered Systems and Neural Networks · Physics 2015-05-14 Karen Michaeli , Alexander M. Finkel'stein

Molecular dynamics simulations at a constant electric potential are an essential tool to study electrochemical processes, providing microscopic information on the structural, thermodynamic, and dynamical properties. Despite the numerous…

Quantum computing promises to revolutionize several scientific and technological domains through fundamentally new ways of processing information. Among its most compelling applications is digital quantum simulation, where quantum computers…

Quantum Physics · Physics 2026-02-05 Laurin E. Fischer

An ab initio quantum-classical mixed scheme for the time evolution of electrode-device-electrode systems is introduced to study nuclear dynamics in quantum transport. Two model systems are discussed to illustrate the method. Our results…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Claudio Verdozzi , Gianluca Stefanucci , Carl-Olof Almbladh

We investigate multi-terminal quantum transport through single monocyclic aromatic annulene molecules, and their derivatives, using the nonequilibrium Green function approach in the self-consistent Hartree-Fock approximation. A new device…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 D. M. Cardamone , C. A. Stafford , S. Mazumdar

As the characteristic lengths of advanced electronic devices are approaching the atomic scale, ab initio simulation method, with fully consideration of quantum mechanical effects, becomes essential to study the quantum transport phenomenon…

Mesoscale and Nanoscale Physics · Physics 2019-07-17 Meng Ye , Xiangwei Jiang , Shu-Shen Li , Lin-Wang Wang

The search for new, application-specific quantum computers designed to outperform any classical computer is driven by the ending of Moore's law and the quantum advantages potentially obtainable. Photonic networks are promising examples,…

Quantum Physics · Physics 2018-04-10 Bogdan Opanchuk , Laura Rosales-Zarate , Margaret D Reid , Peter D Drummond
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