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Exploring inelastic and reactive collisions on the quantum level is a main goal of the developing field of ultracold chemistry. We present first experimental studies of inelastic collisions of metastable ultracold triplet molecules in the…

Adopting the fully quantal triaxial particle rotor model, the candidate chiral doublet bands in odd-$A$ nuclei $^{103}$Rh and $^{105}$Rh with $\pi g_{9/2}^{-1}\otimes\nu h^{2}_{11/2}$ configuration are studied. For the doublet bands in both…

Nuclear Theory · Physics 2011-03-22 B. Qi , S. Q. Zhang , S. Y. Wang , J. Meng , T. Koike

The rovibrational spectrum of the molecular ion H$_2$CCCH$^+$ was investigated in a 4~K cryogenic ion trap instrument employing the leak-out spectroscopy method. Transitions within the fundamental $\nu_1$ (C-H stretch) and the combination…

We report the results of theoretical investigation of electronic structure of ThF$^+$ cation which is one of the most interesting systems to search for the electron electric dipole moment (eEDM) [H. Loh, K.C. Cossel, M.C. Grau, K.-K. Ni,…

Atomic Physics · Physics 2015-05-01 L. V. Skripnikov , A. V. Titov

We investigated the vibrational energies in the 2p^2A^"_2 and 3d^2E^" states of the triatomic deuterium molecule D_3. The experiments were performed using a fast neutral beam photoionization spectrometer recently developed at Freiburg. A…

Chemical Physics · Physics 2009-10-30 U. Mueller , M. Braun , R. Reichle , R. F. Salzgeber

The reaction dynamics of O(3P) + O2(3Sigma_g-) collisions in the O3(1A') electronic ground state is characterized on a high-level MRCI+Q/aug-cc-pVQZ potential energy surface represented as a reproducing kernel. For the atom exchange…

Chemical Physics · Physics 2026-03-12 Raidel Martin-Barrios , Abhirami Vijayakumar , Jingchun Wang , Markus Meuwly

A potential energy surface for the lowest quartet electronic state of lithium trimer is developed and used to study spin-polarized Li + Li_2 collisions at ultralow kinetic energies. The potential energy surface allows barrierless atom…

Chemical Physics · Physics 2009-11-13 Marko T. Cvitas , Pavel Soldan , Jeremy M. Hutson , Pascal Honvault , Jean-Michel Launay

Within the framework of non-relativistic quantum mechanics, the ro-vibrational energy spectra of the improved deformed exponential-type potential model are obtained using the Greene-Aldrich approximation scheme and an appropriate coordinate…

Chemical Physics · Physics 2020-01-15 Uduakobong S. Okorie , Akpan N. Ikot , Ephraim O. Chukwuocha

We present an accurate theoretical determination of rovibrational energy levels of the hydrogen molecule and its isotopologues in its electronic ground state. We consider all significant corrections to the Born-Oppenheimer approximation,…

A theoretical rate constant for the associative detachment reaction Rb($^{2}S$)$+$OH$^{-}$($^{1}\Sigma^{+}$)$\rightarrow \,$ RbOH($^{1}\Sigma^{+}$)$+\,e^{-}$ of 4$\,\times$10$^{-10}$cm$^{3}$s$^{-1}$ at 300 K has been calculated. This result…

Chemical Physics · Physics 2016-06-22 Milaim Kas , Jérôme Loreau , Jacques Liévin , Nathalie Vaeck

The diquark model is used to calculate the electromagnetic polarizabilities and charge radii of the nucleons for three different potentials. Making the scalar diquark lower in mass introduces a mixing angle $\theta $ between the $\left|…

High Energy Physics - Phenomenology · Physics 2009-10-28 H. Liebl , Gary R. Goldstein

The transfer of weakly bound KRb molecules from levels just below the dissociation threshold into the vibrational ground state with shaped laser pulses is studied. Optimal control theory is employed to calculate the pulses. The complexity…

Atomic Physics · Physics 2011-04-15 Mamadou Ndong , Christiane P. Koch

Vibrational-excitation cross sections of ground electronic state of carbon dioxide molecule by electron-impact through the CO2-(2\Pi) shape resonance is considered in the separation of the normal modes approximation. Resonance curves and…

Chemical Physics · Physics 2016-11-01 V. Laporta , J. Tennyson , R. Celiberto

In this work, the spectrum of ground state and excited baryons (N, {\Delta}, , , and {\Omega} particles) has been investigated by using a non-relativistic quantum mechanics under the Killingbeck plus isotonic oscillator potentials. Using…

Nuclear Theory · Physics 2016-09-06 Nasrin Salehi

For molecules and solids containing heavy elements, accurate electronic structure calculations require accounting not only for electronic correlations but also for relativistic effects. In molecules, relativity can lead to severe changes in…

Chemical Physics · Physics 2025-10-17 Gaurav Harsha , Vibin Abraham , Dominika Zgid

We observe "trilobite-like" states of ultracold 85Rb2 molecules, in which a ground-state atom is bound by the electronic wavefunction of its Rydberg-atom partner. We populate these states through the ultraviolet excitation of weakly-bound…

Atomic Physics · Physics 2015-06-15 M. A. Bellos , R. Carollo , J. Banerjee , E. E. Eyler , P. L. Gould , W. C. Stwalley

We explore the electronic structure of ultralong-range pentaatomic Rydberg molecules from a merger of a Rydberg atom and two ground state heteronuclear diatomic molecules. Our focus is on the interaction of Rb($23s$) and Rb($n=20$, $l\ge…

We report the creation of a sample of over 1000 ultracold $^{87}$RbCs molecules in the lowest rovibrational ground state, from an atomic mixture of $^{87}$Rb and Cs, by magnetoassociation on an interspecies Feshbach resonance followed by…

This work presents a study on the nonrelativistic quantum motion of a charged particle in a rotating frame, considering the Aharonov-Bohm effect and a uniform magnetic field. We derive the equation of motion and the corresponding radial…

The triaxiality in nuclear low-lying states has attracted great interests for many years. Recently, the reduced transition probabilities for levels near the ground state in $^{110}$Ru have been measured and provided strong evidences for a…

Nuclear Theory · Physics 2018-04-18 Z. Shi , Z. P. Li