Related papers: Mapping the Trap-State Landscape in 2D Metal-Halid…
The successful development of optoelectronic devices is contingent on a detailed understanding of interactions between light and excited energy states in photoactive materials. In 2D perovskites, excitons are the dominant photogenerated…
In this work we probe the sub-gap energy states within polycrystalline and single crystal lead halide perovskites to better understand their intrinsic photophysics behaviors. Through combined temperature and intensity-dependent optical…
Metal-halide perovskites are a versatile material platform for light-harvesting and light-emitting applications as their variable chemical composition allows the optoelectronic properties to be tailored to specific applications. Halide…
Understanding and controlling charge carrier recombination dynamics is essential for enhancing the performance of metal halide perovskite optoelectronic devices. In this study, we present a machine learning-assisted intensity-modulated…
Electric force microscopy was used to record the light-dependent impedance spectrum and the probe transient photoconductivity of a film of butylammonium lead iodide, BA$_{2}$PbI$_{4}$, a 2D Ruddlesden--Popper perovskite semiconductor. The…
Determining the nature of the optical excited state (excitons or free carriers) in nanostructured materials is crucial for device design, as optoelectronic and photovoltaic technologies require different considerations regarding the…
The application of ultrathin two-dimensional (2D) perovskites in near-infrared and visible-range optoelectronics has been limited owing to their inherent wide bandgaps, large excitonic binding energies and low optical absorption at higher…
Halide perovskites have emerged as disruptive semiconductors for applications including photovoltaics and light emitting devices, with modular optoelectronic properties realisable through composition and dimensionality tuning. Layered…
Optical pump-probe techniques like absorption spectroscopy and microwave conductivity are widely used to characterize the carrier dynamics in perovskites for optoelectronic applications. In contrast to the prevalent assumption of…
Two-dimensional Ruddlesden-Popper hybrid lead halide perovskites have become a major topic in perovskite optoelectronics. Here, we aim to unravel the ultrafast dynamics governing the evolution of charge carriers and excitons in these…
Organic-inorganic perovskite as a promising candidate for solar energy harvesting has attracted immense interest for its low-cost preparation and extremely high quantum efficiency. However, the fundamental understanding of the photophysics…
Mixed-halide lead perovskites, with photoexcited charge-carrier properties suitable for high-efficiency photovoltaics, hold significant promise for high-efficiency tandem solar cells. However, phase segregation under illumination, where an…
The observation of reversible de-mixing phenomena in mixed-halide perovskites under illumination is one of the most challenging as well as intriguing aspects of this class of materials. On the one hand, it poses critical constraints to the…
Metal halide perovskites exhibit coupled electronic and ionic properties that determine their photovoltaic performance and operational stability. Understanding and quantifying ionic transport are therefore essential for advancing perovskite…
Electronic trap states are a critical yet unavoidable aspect of semiconductor devices, impacting performance of various electronic devices such as transistors, memory devices, solar cells, and LEDs. The density, energy level, and position…
Quasi-two-dimensional (quasi-2D) metal halide perovskites exhibit rich phase heterogeneity that profoundly influences light-matter interactions and charge transport. However, the fundamental mechanisms governing carrier transfer across…
Two-dimensional halide perovskites are among intensely studied materials platforms profiting from solution based growth and chemical flexibility. They feature exceptionally strong interactions among electronic, optical as well as…
Understanding the nature of the photoexcitation and ultrafast charge dynamics pathways in organic halide perovskite nanocubes and their aggregation into superlattices is key for the potential applications as tunable light emitters, photon…
Halide perovskites have remarkable properties for relatively crudely processed semiconductors, including large optical absorption coefficients and long charge carrier lifetimes. Thanks to such properties, these materials are now competing…
The spectacular performance of halide perovskites in optoelectronic devices is rooted in their tolerance to defects. Previous studies showed that defects in these materials generate shallow electronic states. However, how these shallow…