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The Full Configuration Interaction Quantum Monte Carlo (FCIQMC) method has proved able to provide near-exact solutions to the electronic Schr\"odinger equation within a finite orbital basis set, without relying on an expansion about a…

Computational Physics · Physics 2016-08-24 Jennifer Kersten , George H. Booth , Ali Alavi

In this study, we utilize the many-body expansion (MBE) framework to decompose electronic structures into fragments by incrementing the virtual orbitals. Our work aims to accurately solve the ground and excited state energies of each…

Chemical Physics · Physics 2023-10-09 Enhua Xu , Yuma Shimomoto , Seiichiro L. Ten-no , Takashi Tsuchimochi

We present a family of many-body models which are exactly solvable analytically. The models are an extended n-body interaction Lipkin-Meshkov-Glick model which considers spin-flip terms which are associated with the interaction of an…

Quantum Physics · Physics 2008-11-26 I. Fuentes-Schuller , P. Barberis-Blostein

This work explores the ability of classical electronic structure methods to efficiently represent (compress) the information content of full configuration interaction (FCI) wave functions. We introduce a benchmark set of four hydrogen model…

Chemical Physics · Physics 2020-08-20 Nicholas H. Stair , Francesco A. Evangelista

Individuals with a locked-in state live with severe whole-body paralysis that limits their ability to communicate with family and loved ones. Recent advances in the brain-computer interface (BCI) technology have presented a potential…

Neurons and Cognition · Quantitative Biology 2023-07-18 Evan Canny , Mariska J. Vansteensel , Sandra M. A. van der Salm , Gernot R. Müller-Putz , Julia Berezutskaya

Background: Ab initio many-body methods have been developed over the past ten years to address mid-mass nuclei... As progress in the design of inter-nucleon interactions is made, further efforts must be made to tailor many-body methods.…

Nuclear Theory · Physics 2017-02-01 J. Ripoche , D. Lacroix , D. Gambacurta , J. -P. Ebran , T. Duguet

Multi-configurational electronic structure theory delivers the most versatile approximations to many-electron wavefunctions, flexible enough to deal with all sorts of transformations, ranging from electronic excitations, to open-shell…

Chemical Physics · Physics 2024-05-07 Kalman Szenes , Maximilian Moerchen , Paul Fischill , Markus Reiher

We report on the findings of a blind challenge devoted to determining the frozen-core, full configuration interaction (FCI) ground state energy of the benzene molecule in a standard correlation-consistent basis set of double-$\zeta$…

We present the concept, derivation, and implementation of dynamical configuration interaction, a quantum embedding theory that combines Green's function methodology with the many-body wave function. In a strongly-correlated active space, we…

Chemical Physics · Physics 2019-04-03 Marc Dvorak , Patrick Rinke

Highly accurate results for the homogeneous electron gas (HEG) have only been achieved to date within a diffusion Monte Carlo (DMC) framework. Here, we introduce a newly developed stochastic technique, Full Configuration Interaction Quantum…

Quantum Gases · Physics 2012-02-22 James J. Shepherd , George Booth , Andreas Grüneis , Ali Alavi

The electron-phonon interaction plays a crucial role in many fields of physics and chemistry. Nevertheless, its actual calculation by means of modern many-body perturbation theory is weakened by the use of model Hamiltonians that are based…

Materials Science · Physics 2015-05-15 Andrea Marini , Samuel Poncé , Xavier Gonze

We present an exact ansatz for the eigenstate problem of mixed fermion-boson systems that can be implemented on quantum devices. Based on a generalization of the electronic contracted Schr\"odinger equation (CSE), our approach guides a…

Quantum Physics · Physics 2024-08-26 Samuel Warren , Yuchen Wang , Carlos L. Benavides-Riveros , David A. Mazziotti

Non-orthogonal configuration interaction (NOCI) is a generalization of the standard orthogonal configuration interaction (CI) method and offers a highly flexible framework for describing ground and excited electronic states. However, this…

Chemical Physics · Physics 2024-12-24 Daniel Graf , Alex J. W. Thom

Finite element methods based on cut-cells are becoming increasingly popular because of their advantages over formulations based on body-fitted meshes for problems with moving interfaces. In such methods, the cells (or elements) which are…

Computational Engineering, Finance, and Science · Computer Science 2022-07-18 Chennakesava Kadapa , Xinyu Wang , Yue Mei

We introduce a family of methods for the full configuration interaction problem in quantum chemistry, based on the fast randomized iteration (FRI) framework [L.-H. Lim and J. Weare, SIAM Rev. 59, 547 (2017)]. These methods, which we term…

Chemical Physics · Physics 2023-09-25 Samuel M. Greene , Robert J. Webber , Jonathan Weare , Timothy C. Berkelbach

Electronic resonances are metastable states that can decay by electron loss. They are ubiquitous across various fields of science, such as chemistry, physics, and biology. However, current theoretical and computational models for resonances…

Chemical Physics · Physics 2025-04-15 Yann Damour , Anthony Scemama , Fábris Kossoski , Pierre-François Loos

Multi-access edge computing (MEC) is an emerging paradigm that pushes resources for sensing, communications, computing, storage and intelligence (SCCSI) to the premises closer to the end users, i.e., the edge, so that they could leverage…

Networking and Internet Architecture · Computer Science 2022-04-19 Yiqin Deng , Xianhao Chen , Guangyu Zhu , Yuguang Fang , Zhigang Chen , Xiaoheng Deng

This article reviews recent progress in understanding the physics of many-body localisation (MBL) in disordered and interacting quantum many-body systems, from the perspective of ergodicity breaking on the associated Fock space. This…

Disordered Systems and Neural Networks · Physics 2024-12-09 Sthitadhi Roy , David E. Logan

Recent developments of experimental techniques in the field of ultra-cold gases open a path to study the crossover from 'few' to 'many' on the quantum level. In this case, accurate description of inter-particle correlations is very…

Quantum Gases · Physics 2018-03-23 Marcin Płodzień , Dariusz Wiater , Andrzej Chrostowski , Tomasz Sowiński

Recently, multi-fidelity Bayesian optimization (MFBO) has been successfully applied to many engineering design optimization problems, where the cost of high-fidelity simulations and experiments can be prohibitive. However, challenges remain…

Numerical Analysis · Mathematics 2025-10-14 Jingyi Wang , Nai-Yuan Chiang , Tucker Hartland , J. Luc Peterson , Jerome Solberg , Cosmin G. Petra