Related papers: Theory of inhomogeneous rod-like Coulomb fluids
While important for many industrial applications, chemical reactions responsible for charging of solids in water are often poorly understood. We theoretically investigate the charging kinetics of solid-liquid interfaces, and find that the…
Noticing that the space of the solutions of a first order Hamiltonian field theory has a pre-symplectic structure, we describe a class of conserved charges on it associated to the momentum map determined by any symmetry group of…
Mobile charge in an electrolytic solution can in principle be represented as the divergence of ionic polarization. After adding explicit solvent polarization a finite volume of electrolyte can then be treated as a composite non-uniform…
In this thesis we study field theoretic viewpoints on certain fluid mechanical phenomena. In the Higgs mechanism, the weak gauge bosons acquire masses by interacting with a scalar field, leading to a vector boson mass matrix. On the other…
For inhomogeneous classical Coulomb fluids in thermal equilibrium, like the jellium or the two-component Coulomb gas, there exists a variety of exact sum rules which relate the particle one-body and two-body densities. The necessary…
The free energy of ion solvation can be decomposed into enthalpic and entropic contributions. This helps to understand the connection between the dielectric properties and the underlying forces. We present a simple linear-response model of…
We develop a theory of polymers in a nematic solvent by exploiting an analogy with two-dimensional quantum bosons at zero temperature. We argue that the theory should also describe polymers in an {\sl isotropic} solvent. The dense phase is…
We adopt a field theoretical approach to study the structure and thermodynamics of a homogeneous Maier-Saupe nematogenic fluid interacting with anisotropic Yukawa potential. In the mean field approximation we retrieve the standard…
The mesoscopic field theory for ionic systems [A. Ciach and G. Stell, J. Mol. Liq. 87, 255 (2000)] is extended to the system with charged boundaries. A very simple expression for the excess grand potential functional of the charge density…
We use the functional integral technique of Edwards and Lenard to solve the statistical mechanics of a one dimensional Coulomb gas with boundary interactions leading to surface charging. The theory examined is a one dimensional model for a…
The osmotic coefficient of solutions of rod-like polyelectrolytes is considered by comparing current theoretical treatments and simulations to recent experimental data. The discussion is restricted to the case of monovalent counterions and…
We develop a coarse-graining procedure for two-dimensional models of fluctuating loops by mapping them to interface models. The result is an effective field theory for the scaling limit of loop models, which is found to be a Liouville…
We study equilibrium statistical mechanics of classical point counter-ions, formulated on 2D Euclidean space with logarithmic Coulomb interactions (infinite number of particles) or on the cylinder surface (finite particle numbers), in the…
The equilibrium density profiles in a classical multicomponent plasma near a hard wall made with a dielectric material characterized by a relative dielectric constant $\ew$ are studied from the first Born-Green-Yvon equation combined with…
In this paper, we study the polyatomic Boltzmann equation based on continuous internal energy, focusing on physically relevant collision kernels of the hard potentials type with integrable angular part. We establish three main results:…
We study the ionic distribution near a charged surface. A new method for performing Monte Carlo simulations in this geometry is discussed. A theory is then presented that allows us to accurately reproduce the density profiles obtained in…
Non-relativistic conformal field theory describes many-body physics at unitarity. The correlation functions of the system are fixed by the requirement of conformal invariance. In this article, we discuss the correlation functions of scalar…
The electrostatic interaction between two non-identical, moderately charged colloids situated in close proximity of each other at a fluid interface is studied. By resorting to a well-justified model system, this problem is analytically…
The lattice fluid model of the system with short range and long range Coulomb interactions is suggested. In the framework of the collective variables method, the screening of the Coulomb interactions in the bulk is considered. It is shown…
A simple model is proposed for the direct correlation function (DCF) for simple fluids consisting of a hard-core contribution, a simple parametrized core correction, and a mean-field tail. The model requires as input only the free energy of…