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Interface engineering in perovskite oxide superlattices has developed into a flourishing field, enabling not only further tuning of the exceptional properties, but also giving access to emergent physical phenomena. Here, we reveal a new…

Materials Science · Physics 2015-03-13 X. Z. Lu , X. G. Gong , H. J. Xiang

Charge dipole moment and spin moment rarely coexist in single-phase bulk materials except in some multiferroics. Despite the progress in the past decade, for most multiferroics their magnetoelectric performance remains poor due to the…

Materials Science · Physics 2015-10-13 P. X. Zhou , S. Dong , H. M. Liu , C. Y. Ma , Z. B. Yan , C. G. Zhong , J. -M. Liu

Using ion-implanted $^8$Li $\beta$-detected NMR, we study the evolution of the correlated metallic state of LaNiO$_3$ in a series of LaNiO$_3$/LaAlO$_3$ superlattices as a function of bilayer thickness. Spin-lattice relaxation measurements…

We present a systematic approach to modeling the electrical and structural properties of charge-mismatched superlattices from first principles. Our strategy is based on bulk calculations of the parent compounds, which we perform as a…

Materials Science · Physics 2015-06-18 Claudio Cazorla , Massimiliano Stengel

Ferroelectric-based photovoltaics have shown great promise as a source of renewable energy, thanks to their in-built charge separation capability, yet their efficiency is often limited by low charge carrier mobilities. In this work, we…

Materials Science · Physics 2019-08-14 J. Kane Shenton , David R. Bowler , Wei Li Cheah

Hybrid halide perovskites exhibit nearly 20% power conversion efficiency, but the origin of their high efficiency is still unknown. Here, we compute the shift current, a dominant mechanism of bulk photovoltaic (PV) effect for ferroelectric…

Materials Science · Physics 2014-10-14 Fan Zheng , Hiroyuki Takenaka , Fenggong Wang , Nathan Z. Koocher , Andrew M. Rappe

Artificial superlattices designed with ferromagnetic Pr0.85Ca0.15MnO3 insulating layer and ferroelectric Ba0.6Sr0.4TiO3 layer were grown on (100) SrTiO3 substrates. The magnetotransport properties were measured with the current…

Strongly Correlated Electrons · Physics 2009-11-10 P. Murugavel , P. Padhan , W. Prellier

We show that an electrically soft ferroelectric host can be used to tune the photoluminescence (PL) response of rare-earth emitter ions by external electric field. The proof of this concept is demonstrated by changing the PL response of…

Materials Science · Physics 2017-09-20 Deepak Kumar Khatua , Abhijeet Kalaskar , Rajeev Ranjan

We report the emergence of a transverse dielectric response in PbTiO$_{3}$/SrTiO$_{3}$ superlattices hosting polar vortex structures. Using second-principles simulations, we find that an electric field applied along one direction induces…

Materials Science · Physics 2025-05-30 Fernando Gómez-Ortiz , Ramamoorthy Ramesh , Javier Junquera

Ferroelectric BaTiO3 films with large polarization have been integrated with Si(001) by pulsed laser deposition. High quality c-oriented epitaxial films are obtained in a substrate temperature range of about 300 deg C wide. The deposition…

Materials Science · Physics 2018-01-25 Jike Lyu , Ignasi Fina , Raul Solanas , Josep Fontcuberta , Florencio Sanchez

(LaNiO3)n/(SrMnO3)2 superlattices were grown using ozone-assisted molecular beam epitaxy. In situ reflection high energy electron diffraction and x-ray scattering has been used to characterize the structural properties of the superlattices,…

Materials Science · Physics 2009-11-13 S. J. May , T. S. Santos , A. Bhattacharya

The effect of layer-by-layer heterostructuring and epitaxial strain on lattice instabilities and related ferroelectric properties is investigated from first principles for the [001]-(PbTiO$_3$)$_1$(PbZrO$_3$)$_1$ superlattice and pure…

Materials Science · Physics 2009-11-10 Claudia Bungaro , K. M. Rabe

Electric-field controlled exchange bias in a heterostructure composed of the ferromagnetic manganite La0.7Sr0.3MO3 and the ferroelectric antiferromagnetic BiFeO3 has recently been demonstrated experimentally. By means of a microscopic model…

Strongly Correlated Electrons · Physics 2011-07-19 M. J. Calderon , S. Liang , R. Yu , J. Salafranca , S. Dong , S. Yunoki , L. Brey , A. Moreo , E. Dagotto

While BiFeO3-based solid solutions show great promise for applications in energy conversion and storage, realizing this promise necessitates understanding the structure-property relationship in particular pertaining to the relaxor-like…

By combining ab initio simulations including an on-site Coulomb repulsion term and Boltzmann theory, we explore the thermoelectric properties of (LaNiO$_3$)$_n$/(LaAlO$_3$)$_n$(001) superlattices ($n=1,3$) and identify a strong dependence…

Materials Science · Physics 2018-05-17 Benjamin Geisler , Rossitza Pentcheva

Heterostructure engineering provides an efficient way to obtain several unconventional phases of LaNiO3, which is otherwise paramagnetic, metallic in bulk form. In this work, a new class of short periodic superlattices, consisting of LaNiO3…

Strongly Correlated Electrons · Physics 2019-10-18 S. Middey , Ranjan Kumar Patel , D. Meyers , Xiaoran Liu , M. Kareev , P. Shafer , J. -W. Kim , P. J. Ryan , J. Chakhalian

Layers of perovskites, found in 3D materials, 2D heterostructures, and nanotubes, often distort from high symmetry to facilitate dipole polarisation that is exploitable in many applications. Using density-functional theory calculations,…

Materials Science · Physics 2025-11-14 Shaowen Xu , Jeffrey R. Reimers , Fanhao Jia , Wei Ren

Despite symmetrical polarization, the magnitude of a light-induced voltage is known to be asymmetric with respect to poling sign in many photovoltaic (PV) ferroelectrics (FEs). This asymmetry remains unclear and is often attributed to…

Materials Science · Physics 2023-06-01 S. Semak , V. Kapustianyk , Yu. Eliyashevskyy , O. Bovgyra , M. Kovalenko , U. Mostovoi , B. Doudin , B. Kundys

Coherent manipulation of lattice vibrations using ultrafast light pulses enables access to nonequilibrium 'hidden' phases with designed functionalities in quantum materials. However, expanding the understanding of nonlinear light-phonon…

Using density-functional theory, we demonstrate that the formal layer charges of the metallic samarium nickelate electrode influence the spontaneous ferroelectric polarization of the barium titanate in SmNiO$_3$/BaTiO$_3$ capacitors. We…

Materials Science · Physics 2024-11-18 Edith Simmen , Nicola A. Spaldin
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