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The angular dependence (x-ray linear dichroism) of the Cr K pre-edge in MgAl2O4:Cr3+ spinel is measured by means of x-ray absorption near edge structure spectroscopy (XANES) and compared to calculations based on density functional theory…

We present a unified description of several methods of chiral discrimination based exclusively on electric-dipole interactions. It includes photoelectron circular dichroism (PECD), enantio-sensitive microwave spectroscopy (EMWS),…

Atomic Physics · Physics 2019-01-02 Andres F. Ordonez , Olga Smirnova

Energy-loss magnetic chiral dichroism (EMCD) is a versatile method for studying magnetic properties on the nanoscale. However, the classical EMCD technique is notorious for its low signal to noise ratio (SNR). Here, we study the theoretical…

Instrumentation and Detectors · Physics 2019-03-12 Stefan Löffler , Walid Hetaba

Circular dichroism (CD) observed by photoemission, being sensitive to the orbital and spin angular momenta of the electronic states, is a powerful probe of the nontrivial surface states of topological insulators, but the experimental…

Mesoscale and Nanoscale Physics · Physics 2017-05-30 C. -Z. Xu , Y. Liu , R. Yukawa , L. -X. Zhang , I. Matsuda , T. Miller , T. -C. Chiang

We investigate the interaction between a monolayer of WS2 and a chiral plasmonic metasurface. WS2 possesses valley excitons that selectively couple with one-handed circularly polarised light. At the same time, the chiral plasmonic…

Optics · Physics 2023-10-31 Fernando Lorén , Cyriaque Genet , Luis Martín-Moreno

Photons with spin angular momentum possess intrinsic chirality which underpins many phenomena including nonlinear optics1, quantum optics2, topological photonics3 and chiroptics4. Intrinsic chirality is weak in natural materials, and recent…

Chiroptical enantioselective sensing is gaining traction across various applications. However, intrinsic molecular chiroptical responses are weak, and existing amplification approaches add synthesis, manufacturing, or operational complexity…

Photoionization of randomly oriented chiral molecules with circularly polarized light leads to a strong forward/backward asymmetry in the photoelectron angular distribution. This chiroptical effect, referred to as Photoelectron Circular…

The expected features of diluted magnetic semiconductors still remain in controversial issue, concerning whether or not s, p-d (f) exchange interactions indeed modify the host semiconductor band structure. To solve this doubt, a new scheme…

Materials Science · Physics 2012-01-31 XueJiao Huang , HouZhi Zheng , LiGuo Wang , Lin Chen , JianHua Zhao

All-dielectric metasurfaces can produce structural colors, but the most advantageous design criteria are still being investigated. This work numerically studies how the two-dimensional shape of nanoparticles affects the colorimetric…

Optics · Physics 2025-08-06 Zaid Haddadin , Anna My Nguyen , Lisa V. Poulikakos

Magnetic fields break the symmetry of the interaction of atoms with photons with different polarizations, yielding chirality and anisotropy properties. The dependence of the absorption spectrum on the polarization, a phenomenon known as…

Solar and Stellar Astrophysics · Physics 2025-01-08 René D. Rohrmann

We present a unique experimental design that enables the measurement of photoelectron circular dichroism (PECD) from chiral molecules in aqueous solution. The effect is revealed from the intensity difference of photoelectron emission into a…

It is shown theoretically that a nonchiral, two-dimensional array of metallic spheres exhibits optical activity as manifested in calculations of circular dichroism. The metallic spheres occupy the sites of a rectangular lattice and for…

Optics · Physics 2009-11-13 Vassilios Yannopapas

A chiral near field with a highly contorted electromagnetic field builds a bridge to match the chiral molecules and light wavelengths with large size differences. It significantly enhances the circular dichroism of chiral molecules and has…

Optics · Physics 2022-03-23 Li Hu , Zhiguang Sun , Yingdong Nie , Yingzhou Huang , Yurui Fang

Plasmonic nanocrystals with hot spots are able to localize optical energy in small spaces. In such physical systems, near-field interactions between molecules and plasmons can become especially strong. This paper considers the case of a…

Mesoscale and Nanoscale Physics · Physics 2017-04-19 Lucas V. Besteiro , Hui Zhang , Jérôme Plain , Gil Markovich , Zhiming Wang , Alexander O. Govorov

Recently developed circularly polarized X-ray light sources can probe ultrafast chiral electronic and nuclear dynamics through spatially localized resonant core transitions. We present simulations of time-resolved circular dichroism (TRCD)…

Chemical Physics · Physics 2017-02-08 Jérémy R. Rouxel , Markus Kowalewski , Shaul Mukamel

Chirality is an intriguing property of certain molecules, materials or artificial nanostructures, which allows them to interact with the spin angular momentum of the impinging light field. Due to their chiral geometry, they can distinguish…

Optics · Physics 2016-11-03 Peter Banzer , Pawel Wozniak , Uwe Mick , Israel De Leon , Robert W. Boyd

X-ray circular dichroism (XCD), defined as the difference in absorption or scattering intensity between X-rays of opposite polarizations, arises from the breaking of spatial inversion or time-reversal symmetry and is thus sensitive to…

An implementation of the multiple-scattering approach to x-ray magnetic circular dichroism (XMCD) in K-edge x-ray absorption spectroscopy is presented. The convergence problems due to the cluster size and the relativistic corrections are…

Condensed Matter · Physics 2009-10-28 Ch. Brouder , M. Alouani , K. H. Bennemann

Altermagnets are a new class of magnetic materials that are promising for spintronics technology. Here it is shown that in altermagnets, the circular dichroism (CD) in resonant photoelectron diffraction (RPED) contains a time-reversal odd…

Materials Science · Physics 2025-09-26 Peter Krüger