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We report Molecular Dynamics (MD) simulations of a generic hydrophobic nanopore connecting two reservoirs which are initially at different Na+ concentrations, as in a biological cell. The nanopore is impermeable to water under equilibrium…

Biological Physics · Physics 2009-11-10 J. Dzubiella , R. J. Allen , J. -P. Hansen

Tasker type III polar terminations of ionic crystals carry a net surface charge as well as a dipole moment and are fundamentally unstable. In contact with electrolytes, such polar surfaces can be stabilized by adsorption of counter ions…

Chemical Physics · Physics 2019-03-22 Thomas Sayer , Michiel Sprik , Chao Zhang

This work presents a scalable method to produce robust all-solid electric double layer capacitors (EDLCs), compatible with roll-to-roll processes and structural laminate composite fabrication. It consists in sandwiching and pressing an…

We examine some of the optical properties of a metamaterial consisting of thin layers of alternating metal and dielectric. We can model this material as a homogeneous effective medium with anisotropic dielectric permittivity. When the…

Optics · Physics 2009-11-13 B. Wood , J. B. Pendry , D. P. Tsai

Ionic liquids (ILs) are an exciting class of electrolytes finding applications in many areas from energy storage to solvents, where they have been touted as ``designer solvents'' as they can be mixed to precisely tailor the physiochemical…

Plasmons in two-dimensional electron gas (2DEG) strips with grounded electrodes (a gate or side contacts) are investigated. We consider two systems: (a) the 2DEG strip with a highly conducting gate and (b) the 2DEG strip with semi-infinite…

Mesoscale and Nanoscale Physics · Physics 2016-08-31 A. Satou , V. Ryzhii

The association between polyelectrolytes (PEs) of the same size but opposite charge is systematically studied in terms of the potential of mean force (PMF) along their center-of-mass reaction coordinate via coarse-grained, implicit-solvent,…

Soft Condensed Matter · Physics 2017-06-05 Xiao Xu , Matej Kanduč , Jianzhong Wu , Joachim Dzubiella

Electrophoretic (EP) mobility reversal is commonly observed for strongly charged macromolecules in multivalent salt solutions. This curious effect takes place, e.g., when a charged polymer, such as DNA, adsorbs excess counterions so that…

Soft Condensed Matter · Physics 2023-03-28 Xiang Yang , Sahin Buyukdagli , Alberto Scacchi , Maria Sammalkorpi , Tapio Ala-Nissila

Motivated by recent experiments, we present a theoretical investigation of how the electro-osmotic flow occurring in a capillary is modified when its charged surfaces are coated by charged polymers. The theoretical treatment is based on a…

Mesoscale and Nanoscale Physics · Physics 2015-07-17 Umberto Marini Bettolo Marconi , Michele Monteferrante , Simone Melchionna

We demonstrate the phenomenon of induced-charge capacitive deionization (ICCDI) that occurs around a porous and conducting particle immersed in an electrolyte, under the action of an external electric field. The external electric field…

Fluid Dynamics · Physics 2016-12-21 S. Rubin , M. E. Suss , P. M. Biesheuvel , M. Bercovici

The electronic structure of materials is fundamentally governed by their crystal symmetry. While most research on two-dimensional materials has focused on hexagonal lattices, such as graphene, hexagonal boron nitride, and transition metal…

Materials Science · Physics 2026-04-21 Zhonghui Han , Lanting Feng , Guodong Yu , Shengjun Yuan

Similarly-charged polymers in solution, known as polyelectrolytes, are known to form aggregated structures in the presence of oppositely charged counterions. Understanding the dependence of the equilibrium phases and the dynamics of the…

Soft Condensed Matter · Physics 2017-07-03 Anvy Moly Tom , Ravindran Rajesh , Satyavani Vemparala

It is found that the electric field can be enhanced strongly inside a permittivity-near-zero object in free space, when the transverse cross section of the object is small and the length along the propagation direction of the incident wave…

Optics · Physics 2015-05-19 Yi Jin , Pu Zhang , Sailing He

We describe a novel method to measure the surface charge densities on optical fibers placed in the vicinity of a trapped ion, where the ion itself acts as the probe. Surface charges distort the trapping potential, and when the fibers are…

We formulate a general mean-field theory of a flat electric double layer in ionic liquids and electrolyte solutions with ions possessing static polarizability and a permanent dipole moment on a charged electrode. We establish a new…

Statistical Mechanics · Physics 2021-08-17 Yu. A. Budkov , S. V. Zavarzin , A. L. Kolesnikov

Induced-charge electrophoresis (ICEP) has mostly been analyzed for asymmetric particles in an infinite fluid, but channel walls in real systems further break symmetry and lead to dielectrophoresis (DEP) in local field gradients. Zhao and…

Materials Science · Physics 2007-12-05 Mustafa Sabri Kilic , Martin Z. Bazant

For the past two and a half decades, anomalous heating of trapped ions from nearby electrode surfaces has continued to demonstrate unexpected results. Caused by electric-field noise, this heating of the ions' motional modes remains an…

Atomic Physics · Physics 2021-10-05 D. A. Hite , K. S. McKay , D. P. Pappas

The atomistic structure of the graphene buffer layer on Si-terminated SiC is studied using a modified environment-dependent interatomic potential (EDIP). The investigation of equilibrium state by conjuguate gradients suffers from a complex…

Materials Science · Physics 2011-07-26 Evelyne Lampin , Catherine Priester , Christophe Krzeminski , Laurence Magaud

We present a quantitative analysis of the steady state electronic transport in a resistive switching device. The device is composed of a thin film of Ag$_{2}$S (solid electrolyte) contacted by a Pt nano-contact acting as ion-blocking…

Materials Science · Physics 2017-12-11 Monica Morales-Masis , Hans-Dieter Wiemhofer , Jan M. van Ruitenbeek

Next-generation lithium-ion batteries with silicon anodes have positive characteristics due to higher energy densities compared to state-of-the-art graphite anodes. However, the large volume expansion of silicon anodes can cause high…

Numerical Analysis · Mathematics 2024-04-03 R. Schoof , G. F. Castelli , W. Dörfler