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We introduce an efficient scheme for the molecular dynamics of electronic systems by means of quantum Monte Carlo. The evaluation of the (Born-Oppenheimer) forces acting on the ionic positions is achieved by two main ingredients: i) the…

Strongly Correlated Electrons · Physics 2007-05-23 Sandro Sorella , Claudio Attaccalite

Resonant vibrational excitation cross sections and the corresponding rate coefficients for electron-N$_2$ collisions occurring through the N$_2^-(\textrm{X}\ ^2\Pi_g)$ resonant state are reviewed. New calculations are performed using…

Plasma Physics · Physics 2015-06-18 V. Laporta , D. A. Little , R. Celiberto , J. Tennyson

We present a new analysis of the helicity parton distributions of the nucleon. The analysis takes into account the available data from inclusive and semi-inclusive polarized deep inelastic scattering, as well as from polarized pp scattering…

High Energy Physics - Phenomenology · Physics 2008-11-26 Daniel de Florian , Rodolfo Sassot , Marco Stratmann , Werner Vogelsang

The reliability of the approximations commonly adopted in the calculation of static optical (hyper)polarizabilities is tested against exact results obtained for an interesting toy-model. The model accounts for the principal features of…

Chemical Physics · Physics 2009-11-07 Luca Del Freo , Francesca Terenziani , Anna Painelli

We report on the calculation of the ground-state atomic kinetic energy, $E_{k}$, and momentum distribution of solid Ne by means of the diffusion Monte Carlo method and Aziz HFD-B pair potential. This approach is shown to perform notably for…

Other Condensed Matter · Physics 2009-11-13 C. Cazorla , J. Boronat

We propose a method, based on a Generalized Heisenberg Algebra (GHA), to reproduce the anharmonic spectrum of diatomic molecules. The theoretical spectrum generated by GHA allows us to fit the experimental data and to obtain the…

Chemical Physics · Physics 2009-11-11 J. de Souza , N. M. Oliveira-Neto , C. I. Ribeiro-Silva

A faithful description of chemical processes requires exploring extended regions of the molecular potential energy surface (PES), which remains challenging for strongly correlated systems. Transferable deep-learning variational Monte Carlo…

Chemical Physics · Physics 2026-03-27 P. Bernát Szabó , Zeno Schätzle , Frank Noé

Recently, Tao and Mo (TM) derived a meta-generalized gradient approximation functional based on a model exchange-correlation hole. In this work, the performance of this functional is assessed on standard test sets, using the…

Chemical Physics · Physics 2017-01-04 Yuxiang Mo , Guocai Tian , Roberto Car , Viktor N. Staroverov , Gustavo E. Scuseria , Jianmin Tao

We have developed a formulation of density functional perturbation theory for the calculation of vibrational frequencies in molecules and solids, which uses numerical atomic orbitals as a basis set for the electronic states. The (harmonic)…

Materials Science · Physics 2007-05-23 J. M. Pruneda , S. K. Estreicher , J. Junquera , J. Ferrer , P. Ordejon

We leverage the power of neural quantum states to describe the ground state wave function of solid and liquid atomic hydrogen, including both electronic and protonic degrees of freedom. For static protons, the resulting Born-Oppenheimer…

Strongly Correlated Electrons · Physics 2026-04-27 David Linteau , Saverio Moroni , Giuseppe Carleo , Markus Holzmann

The detection of vibrational excitations of individual molecules on surfaces by scanning tunneling spectroscopy does not obey strict selection rules but rather propensity rules. The experimental verification of these is challenging because…

The complexity of many-body quantum wave functions is a central aspect of several fields of physics and chemistry where non-perturbative interactions are prominent. Artificial neural networks (ANNs) have proven to be a flexible tool to…

Nuclear Theory · Physics 2021-07-14 Corey Adams , Giuseppe Carleo , Alessandro Lovato , Noemi Rocco

Variational optimization of neural-network quantum state representations has achieved FCI-level accuracy for ground state calculations, yet computing optical properties involving excited states remains challenging. In this work, we present…

Chemical Physics · Physics 2025-06-10 Wei Liu , Rui-Hao Bi , Wenjie Dou

We examine the eigenfrequencies of gravitational waves from the protoneutron stars (PNSs) provided via the core-collapse supernovae, focusing on how the frequencies depend on the dimension of numerical simulations especially for the early…

High Energy Astrophysical Phenomena · Physics 2020-07-29 Hajime Sotani , Tomoya Takiwaki

We obtained a density-dependent analytical expression of binding energy per nucleon for different neutron-proton asymmetry of the nuclear matter (NM) with a polynomial fitting, which manifests the results of effective field theory motivated…

Nuclear Theory · Physics 2021-02-03 Ankit Kumar , H. C. Das , Manpreet Kaur , M. Bhuyan , S. K. Patra

This work presents the bound-state spectra of Morse oscillator, which remains one of the oldest important model potentials for molecules. Accurate ro-vibrational energies are obtained by means of a generalized pseudospectral method that…

Quantum Physics · Physics 2013-07-19 Amlan K. Roy

We use ab initio molecular dynamics simulations to quantify structural and thermodynamic properties of a model proton transfer reaction that converts a neutral glycine molecule, stable in the gas phase, to the zwitterion that predominates…

Soft Condensed Matter · Physics 2009-11-11 Kevin Leung , Susan B. Rempe

We present the results of 3D, high-resolution calculations of neutron star mergers. Using Newtonian gravity, but adding the forces from the emission of gravitational waves, we solve the hydrodynamics equations using the smoothed particle…

Astrophysics · Physics 2016-02-09 S. Rosswog , M. B. Davies

Level density $\rho$ is derived for a finite system with strongly interacting nucleons at a given energy E, neutron N and proton Z particle numbers, projection of the angular momentum M, and other integrals of motion, within the…

Nuclear Theory · Physics 2023-08-22 A. G. Magner , A. I. Sanzhur , S. N. Fedotkin , A. I. Levon , U. V. Grygoriev , S. Shlomo

A new method for extracting neutron densities from intermediate energy elastic proton-nucleus scattering observables uses a global Dirac phenomenological (DP) approach based on the Relativistic Impulse Approximation (RIA). Data sets for…

Nuclear Theory · Physics 2009-11-07 B. C. Clark , S. Hama , L. J. Kerr