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We measure the two-dimensional elastic modulus $E^\text{2D}$ of atomically clean defect-engineered graphene with a known defect distribution and density in correlated ultra-high vacuum experiments. The vacancies are introduced via…

We report combined first-principle and tight-binding (TB) calculations to simulate the effects of chemical edge modifications on structural and electronic properties. The C-C bond lengths and bond angles near the GNR edge have considerable…

Materials Science · Physics 2007-05-23 Z. F. Wang , Qunxiang Li. Huaixiu Zheng , Hao Ren , Haibin Su , Q. W. Shi , Jie Chen

Graphene, the one-atom-thick sp2 hybridized carbon crystal, displays unique electronic, structural and mechanical properties, which promise a large number of interesting applications in diverse high tech fields. Many of these applications…

Mesoscale and Nanoscale Physics · Physics 2016-09-27 Tommaso Cavallucci , Khatuna Kakhiani , Riccardo Farchioni , Valentina Tozzini

The effect of hydrogenation on the topography and the electronic properties of graphene and graphite surfaces are studied by scanning tunneling microscopy and spectroscopy. The surfaces are chemically modified using Ar/H2 plasma. Analyzing…

Mesoscale and Nanoscale Physics · Physics 2012-05-17 Andres Castellanos-Gomez , Magdalena Wojtaszek , Arramel , Nikolaos Tombros , Bart J. van Wees

We demonstrate high-resolution modification of suspended multi-layer graphene sheets by controlled exposure to the focused electron beam of a transmission electron microscope. We show that this technique can be used to realize, on…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Michael D. Fischbein , Marija Drndic

Oxygen is widely used to tune the performance of chalcogenide phase-change materials in the usage of phase-Change random access memory (PCRAM) which is considered as the most promising next-generation non-volatile memory. However, the…

Materials Science · Physics 2016-12-23 Linggang Zhu , Zhen Li , Jian Zhou , Naihua Miao , Zhimei Sun

Using molecular simulation and continuum dielectric theory, we consider how electrochemical kinetics are modulated by twist angle in bilayer graphene electrodes. By establishing a connection between twist angle and the screening length of…

Statistical Mechanics · Physics 2024-11-06 Leonardo Coello Escalante , David T. Limmer

The penetration of atomic hydrogen through defect-free graphene was generally predicted to have a barrier of at least several eV, which is much higher than the 1 eV barrier measured for hydrogen-gas permeation through pristine graphene…

Materials Science · Physics 2023-07-26 Wenqi Xiong , Weiqing Zhou , Pengzhan Sun , Shengjun Yuan

At high pressure, the typical behavior of elements dictated by the periodic table - including oxidation numbers, stoichiometries in compounds, and reactivity, to name but a few - is altered dramatically. As pressure is applied, the…

Materials Science · Physics 2022-05-11 Katerina P. Hilleke , Tiange Bi , Eva Zurek

Defects change essentially not only electronic but also chemical properties of graphene being centers of its chemical activity. Their functionalization is a way to modify electronic and crystal structure of graphene which may be important…

Materials Science · Physics 2009-01-05 D. W. Boukhvalov , M. I. Katsnelson

High entropy oxides (HEOs) are a class of materials with vast compositional space and tunable properties, making them attractive for applications in thermoelectrics, magnetism, ionic conduction, and beyond. However, their metastable nature…

Friction is a ubiquitous phenomenon that greatly affects our everyday lives and is responsible for large amounts of energy loss in industrialised societies. Layered materials such as graphene have interesting frictional properties and are…

Applied Physics · Physics 2020-02-04 David Andersson , Astrid S. de Wijn

Understanding the influence that copper substrate surface symmetry and oxygen impurities have on the growth of graphene by chemical vapor deposition is important for developing techniques for producing high quality graphene. Therefore, we…

Twist, as a simple and unique degree of freedom, could lead to enormous novel quantum phenomena in bilayer graphene. A small rotation angle introduces low-energy van Hove singularities (VHSs) approaching the Fermi level, which result in…

Materials Science · Physics 2018-02-07 Wei-Jie Zuo , Jia-Bin Qiao , Dong-Lin Ma , Long-Jing Yin , Gan Sun , Jun-Yang Zhang , Li-Yang Guan , Lin He

Graphene oxide can be used as a precursor to graphene but the quality of graphene flakes is highly heterogeneous. Scanning-Raman-Microscopy (SRM) is used to characterize films of graphene derived from flakes of graphene oxide with an almost…

We describe the results of atomic-level stick-slip friction measurements performed on chemically-modified graphite, using atomic force microscopy (AFM). Through detailed molecular dynamics simulations, coarse-grained simulations, and…

Materials Science · Physics 2014-06-23 Alex Smolyanitsky , Shuze Zhu , Zhao Deng , Teng Li , Rachel J. Cannara

Graphene nanomeshes (GNMs) are novel materials that recently raised a lot of interest. They are fabricated by forming a lattice of pores in graphene. Depending on the pore size and pore lattice constant, GNMs can be either semimetallic or…

Materials Science · Physics 2020-08-21 Sarah Gamal , Mohamed M. Fadlallah , Lobna M. Salah , Ahmed A. Maarouf

The transmission electron microscope (TEM) has become an essential tool for innovation in nanoscience, material science, and biology. Despite these instruments being widely used across both industry and academia, academics may hesitate to…

Instrumentation and Detectors · Physics 2022-12-07 Patrick McBean , Zachary Milne , Arjun Kanthawar , Cameron O'Byrne , Khalid Hattar , Lewys Jones

Wrinkles in monolayer graphene (GN) affect the GN electronic and transport properties. Defined network of wrinkles can be reached by placing the GN on the substrate decorated with the nanoparticles (NPs). In order to explain mechanism…

Mesoscale and Nanoscale Physics · Physics 2015-12-02 Barbara Pacakova , Jana Vejpravova , Anton Repko , Alice Mantlikova , Martin Kalbac

In view of a formal topology, two common terms, namely, connectivity and adjacency, determine the quality of C-C bonds of sp2 nanocarbons. The feature is the most sensitive point of the inherent topology of the species so that such external…

Materials Science · Physics 2013-01-15 Elena Sheka , Vera Popova , Nadezhda Popova