Related papers: Reductionist approach to chemical rate constants u…
Starting from a simple classical framework and employing some stochastic concepts, the basic ingredients of the quantum formalism are recovered. It has been shown that the traditional axiomatic structure of quantum mechanics can be rebuilt,…
We show that classical particle mechanics (Hamiltonian and Lagrangian consistent with relativistic electromagnetism) can be derived from three fundamental assumptions: infinite reducibility, deterministic and reversible evolution, and…
We propose a new approach to study the long time dynamics of the wave kinetic equation in the statistical description of acoustic turbulence. The approach is based on rewriting the discrete version of the wave kinetic equation in the form…
Two crucial for the breakdown of the master equation arguments are put forward. The first one is related to the violence of a fundamental requirement to the notion of state (thermodynamical) variable, namely: a state variable is defined…
This work is a follow-up to our previous work "A numerical approach related to defect-type theories for some weakly random problems in homogenization" (preprint available on this archive). It extends and complements, both theoretically and…
Equilibrium free energy differences are given by exponential averages of nonequilibrium work values; such averages, however, often converge poorly, as they are dominated by rare realizations. I show that there is a simple and intuitively…
We establish an operational theory of coherence (or of superposition) in quantum systems, by focusing on the optimal rate of performance of certain tasks. Namely, we introduce the two basic concepts - "coherence distillation" and "coherence…
Given an energy-dissipating port-Hamiltonian system, we characterise the exponential decay of the energy via the model ingredients under mild conditions on the Hamiltonian density $\mathcal{H}$. In passing, we obtain generalisations for…
For the first time, the energy diffusion approximation is confronted at the percent level with the exact numerical modeling of thermal decay of a metastable state. The latter is performed using the quasistationary decay rates resulting from…
We call \emph{Alphabet model} a generalization to N types of particles of the classic ABC model. We have particles of different types stochastically evolving on a one dimensional lattice with an exchange dynamics. The rates of exchange are…
That the speed of light is a universal constant is a logical consequence of Maxwell's equations. Here we show the converse is also true. Electromagnetism (EM) and electrodynamics (ED), in all details, can be derived from two simple…
\emph{Probabilistic hysteresis} is a manifestation of irreversibility in a small, isolated classical system [Sci. Rep. 9, 14169]: after a slow cyclic sweep of a control parameter, the probability that a microcanonical ensemble returns to…
We establish an extended version of the kinetic theory of the relativistic axionically active multi-component plasma, which is based on the inclusion of a unit time-like vector field, associated with the velocity of dynamic aether, into the…
We study two different physical scenarios of thermonuclear reactions in stellar plasmas proceeding through a narrow resonance at low energy or through the low energy wing of a wide resonance at high energy. Correspondingly, we derive two…
The principle of minimal energy, which has been set up in the preceding papers for systems of non-identical particles (e.g. positronium), is now generalized to include also identical particles. Since the latter kind of particles feels also…
Ionic conductivity in solid electrolytes is commonly expected to exhibit Arrhenius dependence on temperature, determined by a well-defined activation energy. Consequently, a standard approach involves calculating this energy using…
Multiphysics problems involving two or more coupled physical phenomena are ubiquitous in science and engineering. This work develops a new partitioned exponential approach for the time integration of multiphysics problems. After a possible…
The answers to many unsolved problems lie in the intractable chemical space of molecules and materials. Machine learning techniques are rapidly growing in popularity as a way to compress and explore chemical space efficiently. One of the…
Classical causal models, such as Granger causality and structural equation modeling, are largely restricted to acyclic interactions and struggle to represent cyclic and higher-order dynamics in complex networks. We introduce a causal…
We have incorporated our experimentally derived thermal rate coefficients for C + H$_3^+$ forming CH$^+$ and CH$_2^+$ into a commonly used astrochemical model. We find that the Arrhenius-Kooij equation typically used in chemical models does…