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We report the first observation of substitutional silicon atoms in single-layer hexagonal boron nitride (h-BN) using aberration corrected scanning transmission electron microscopy (STEM). The medium angle annular dark field (MAADF) images…

Materials Science · Physics 2020-01-29 Mohammad Reza Ahmadpour Monazam , Ursula Ludacka , Hannu-Pekka Komsa , Jani Kotakoski

Optically addressable defect qubits in wide band gap materials are favorable candidates for room temperature quantum information processing. The two-dimensional (2D) hexagonal boron nitride (hBN) is an attractive solid state platform with a…

Materials Science · Physics 2024-09-10 Song Li , Anton Pershin , Adam Gali

Hexagonal boron nitride (hBN), having an in-plane hexagonal structure in the sp2 arrangement of atoms, proclaims structural similarity with graphene with only a small lattice mismatch. Despite having nearly identical atomic arrangements and…

Materials Science · Physics 2023-06-09 Vidyotma Yadav , Tanuja mohanty

We investigate theoretically the electronic structure of graphene and boron nitride (BN) lateral heterostructures, which were fabricated in recent experiments. The first-principles density functional calculation demonstrates that a huge…

Mesoscale and Nanoscale Physics · Physics 2016-07-04 Dong Zhang , Maosheng Miao , Fuhua Yang , Haiqing Lin , Kai Chang

Phagraphene is a novel 2D carbon allotrope with interesting electronic properties which has been recently theoretically proposed. Phagraphene is similar to a defective graphene structure with an arrangement of pentagonal, heptagonal and…

Materials Science · Physics 2017-04-07 Luiz Felipe C. Pereira , Bohayra Mortazavi , Meysam Makaremi , Timon Rabczuk

Hexagonal boron nitride (h-BN), one of the hallmark van der Waals (vdW) layered crystals with an ensemble of attractive physical properties, is playing increasingly important roles in exploring two-dimensional (2D) electronics, photonics,…

Mesoscale and Nanoscale Physics · Physics 2020-01-07 Yanan Wang , Jaesung Lee , Xu-Qian Zheng , Yong Xie , Philip X. -L. Feng

We calculate the electronic structure in quasiperiodic double-moir\'e systems of graphene sandwiched by hexagonal boron nitride, and identify the topological invariants of energy gaps. We find that the electronic spectrum contains a number…

Mesoscale and Nanoscale Physics · Physics 2021-08-04 Hiroki Oka , Mikito Koshino

Two-dimensional (2D) nitride materials such as hexagonal boron nitride (h-BN), graphitic carbon nitride (g-C$_3$N$_4$), and beryllonitrene (BeN$_4$) have emerged as promising candidates for next generation electronic, optoelectronic, and…

Materials Science · Physics 2025-10-16 Shreya G. Sarkar , Kuneh Parag Shah , Brahmananda Chakraborty

Today, 2D semiconductor materials have been extended into the nitrogen group: phosphorene, arsenene, antimonene and even nitrogene. Motivated by them, based upon first-principles density functional calculations, we propose a new…

Mesoscale and Nanoscale Physics · Physics 2016-03-11 Hang Xiao , Feng Hao , Xiangbiao Liao , Xiaoyang Shi , Yayun Zhang , Xi Chen

Defect states in 2D materials present many possible uses but both experimental and computational characterization of their spectroscopic properties is difficult. We provide and compare results from 13 DFT and ab initio computational methods…

Computational Physics · Physics 2018-02-12 Jeffrey R. Reimers , Ali Sajid , Rika Kobayashi , Michael J. Ford

Integration of individual two-dimensional materials into heterostructures is a crucial step which enables development of new and technologically interesting functional systems of reduced dimensionality. Here, well-defined lateral…

Mesoscale and Nanoscale Physics · Physics 2018-06-19 Marin Petrović , Michael Horn-von Hoegen , Frank-J. Meyer zu Heringdorf

Two-dimensional (2D) crystals, such as graphene, hexagonal boron nitride and transitional metal dichalcogenides, have attracted tremendous amount of attention over the past decade due to their extraordinary thermal, electrical and optical…

Materials Science · Physics 2017-02-16 Y. Zhao , Z. Wan , U. Hetmaniuk , M. P. Anantram

We use a tight binding approach and density functional theory calculations to study the band structure of graphene/hexagonal boron nitride bilayer system in the most stable configuration. We show that an electric field applied in the…

Materials Science · Physics 2010-11-10 J. Slawinska , I. Zasada , Z. Klusek

Dielectrics are insulating materials used in many different electronic devices and play an important role in all of them. Current advanced electronic devices use dielectric materials with a high dielectric constant and avoid high leakage…

Applied Physics · Physics 2019-05-17 Fei Hui

We performed calculations of electronic, optical and transport properties of graphene on hBN with realistic moir\'e patterns. The latter are produced by structural relaxation using a fully atomistic model. This relaxation turns out to be…

Mesoscale and Nanoscale Physics · Physics 2015-11-05 G. J. Slotman , M. M. van Wijk , Pei-Liang Zhao , A. Fasolino , M. I. Katsnelson , Shengjun Yuan

We predict the stabilities of \alpha-graphynes and their boron nitride analogues(\alpha-BNyne), which are considered as competitors of graphene and two-dimensional hexagonal BN. Based on first-principles plane wave method, we investigated…

Materials Science · Physics 2013-02-11 V. Ongun Özçelik , S. Ciraci

Boron nitride (BN) is an exceptional material and among its polymorphs, two-dimensional (2D) hexagonal and three-dimensional (3D) cubic BN (h-BN and c-BN) phases are most common. The phase stability regimes of these BN phases are still…

Recently synthesized two-dimensional (2D) boron, borophene, exhibits a novel metallic behavior rooted in the s-p orbital hybridization, distinctively different from other 2D materials such as sulfides/selenides and semi-metallic graphene.…

Titanium nitride halides, TiNX (X = F, Cl, Br, I) in the {\alpha}-phase (orthorhombic) are exciting quasi two-dimensional (2D) electronic systems exhibiting a fascinating series of electronic ground states under different conditions.…

Materials Science · Physics 2020-04-22 M. M. Hossain , S. H. Naqib

Boron nitride structures have excellent thermal and chemical stabilities. Based on state-of-art theoretical calculations, we propose a wide gap semiconducting BN crystal with a three-dimensional hyperhoneycomb structure (Hp-BN), which is…

Materials Science · Physics 2017-10-18 Jin Yu , Lihua Qu , Edo van Veen , Mikhail I. Katsnelson , Shengjun Yuan