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A new approach is described to the evaluation of the S-matrix in three-dimensional atom-diatom reactive quantum scattering theory. The theory is developed based on natural collision coordinates where progress along the reaction coordinate…

Chemical Physics · Physics 2007-05-23 Ashot S. Gevorkyan , Gabriel G. Balint-Kurti , Gunnar Nyman

The random phase approximation (RPA) for the correlation energy functional of density functional theory has recently attracted renewed interest. Formulated in terms of the Kohn-Sham (KS) orbitals and eigenvalues, it promises to resolve some…

Other Condensed Matter · Physics 2009-11-13 Hong Jiang , Eberhard Engel

The dynamical properties of nuclei, carried by the concept of phonon quasiparticles (QP), are central to the field of condensed matter. While the harmonic approximation can reproduce a number of properties observed in real crystals, the…

Materials Science · Physics 2023-12-19 Aloïs Castellano , J. P. Alvarinhas Batista , Matthieu J. Verstraete

Including quantum mechanical effects on the dynamics of nuclei in the condensed phase is challenging, because the complexity of exact methods grows exponentially with the number of quantum degrees of freedom. Efforts to circumvent these…

Chemical Physics · Physics 2015-06-23 Mariana Rossi , Hanchao Liu , Francesco Paesani , Joel Bowman , Michele Ceriotti

This companion paper to [D. Picconi et al., J. Chem. Phys. 150 (2019)] presents quantum dynamical simulations, using the Gaussian-based multiconfigurational time-dependent Hartree (G-MCTDH) method, of time-resolved coherent Raman…

Chemical Physics · Physics 2019-03-27 David Picconi , Jeffrey A. Cina , Irene Burghardt

We study amorphous solids with strong elastic disorder and find an un-jamming instability that exists, inter alia, in an harmonic model built using Euclidean random matrices (ERM). Employing the Zwanzig-Mori projection operator formalism…

Soft Condensed Matter · Physics 2024-05-13 Florian Vogel , Philipp Baumgärtel , Matthias Fuchs

We derive a self-consistent time-dependent harmonic approximation for the quantum sine-Gordon model out of equilibrium and apply the method to the dynamics of tunnel-coupled one-dimensional Bose gases. We determine the time evolution of…

Quantum Gases · Physics 2019-08-26 Yuri D. van Nieuwkerk , Fabian H. L. Essler

A variationally improved Sturmian approximation for solving time-independent Schr\"odinger equation is developed. This approximation is used to obtain the energy levels of a quartic anharmonic oscillator, a quartic potential, and a Gaussian…

Quantum Physics · Physics 2009-11-07 Ali Mostafazadeh

The harmonic approximation of ionic fluctuations and the linear coupling between phonons and electrons provide the standard framework to compute, from first principles, the contribution of nuclear dynamics and its interaction with electrons…

Materials Science · Physics 2026-03-04 Raffaello Bianco , Ion Errea

Synchronization is a phenomenon where interacting particles lock their motion and display non-trivial dynamics. Despite intense efforts studying synchronization in systems without clear classical limits, no comprehensive theory has been…

Quantum Physics · Physics 2022-03-23 Berislav Buca , Cameron Booker , Dieter Jaksch

We introduce a quantum algorithm for simulating the time-dependent Dirac equation in 3+1 dimensions using discrete-time quantum walks. Thus far, promising quantum algorithms have been proposed to simulate quantum dynamics in…

The dynamics of entanglement and uncertainty relation is explored by solving the time-dependent Schr\"{o}dinger equation for coupled harmonic oscillator system analytically when the angular frequencies and coupling constant are arbitrarily…

Quantum Physics · Physics 2018-03-30 DaeKil Park

We investigate the time evolution of a classical ensemble of isolated periodic chains of O(N)-symmetric anharmonic oscillators. Our method is based on an exact evolution equation for the time dependence of correlation functions. We discuss…

High Energy Physics - Phenomenology · Physics 2016-08-25 Gian Franco Bonini , Christof Wetterich

We use coherent states as a time-dependent variational ansatz for a semiclassical treatment of the dynamics of anharmonic quantum oscillators. In this approach the square variance of the Hamiltonian within coherent states is of particular…

Condensed Matter · Physics 2009-10-31 John Schliemann , Franz G. Mertens

Phonon anharmonicity is ubiquitous in real materials and is crucial for understanding thermal properties and phase stability. In this work, we show that anharmonic phonon modes can be obtained by maximizing their vibration stability during…

Materials Science · Physics 2026-05-15 Wenjing Li , Yong Lu , Fawei Zheng

We derive the stochastic equations and consider the non-Markovian dynamics of a system of multiple two-level atoms in a common quantum field. We make only the dipole approximation for the atoms and assume weak atom-field interactions. From…

Quantum Physics · Physics 2015-03-17 C. H. Fleming , N. I. Cummings , Charis Anastopoulos , B. L. Hu

In this paper we review our recent work on the theoretical approach to quantum Loschmidt echoes, i.e. various properties of the so called echo dynamics -- the composition of forward and backward time evolutions generated by two slightly…

Quantum Physics · Physics 2009-11-10 Tomaz Prosen , Thomas H. Seligman , Marko Znidaric

The accurate computational determination of chemical, materials, biological, and atmospheric properties has critical impact on a wide range of health and environmental problems, but is deeply limited by the computational scaling of…

Chemical Physics · Physics 2021-06-09 Debadrita Saha , Srinivasan S. Iyengar , Philip Richerme , Jeremy M. Smith , Amr Sabry

The accuracy of the noninteracting electron approximation is examined for a model of vibrationally coupled electron transport in single molecule junction. In the absence of electronic-vibrational coupling, steady state transport in this…

Mesoscale and Nanoscale Physics · Physics 2017-01-04 Haobin Wang , Michael Thoss

We investigate time evolution of prepared vibrational state (system) coupled to a reservoir with dense spectrum of its vibrational states. We assume that the reservoir has an equidistant spectrum, and the system - reservoir coupling matrix…

Statistical Mechanics · Physics 2009-11-13 V. A. Benderskii , L. A. Falkovsky , E. I. Kats