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We investigate band-gap tuning of bilayer graphene between hexagonal boron nitride sheets, by external electric fields. Using density functional theory, we show that the gap is continuously tunable from 0 to 0.2 eV, and is robust to…

Materials Science · Physics 2015-05-20 Ashwin Ramasubramaniam , Doron Naveh , ELias Towe

In heterostructures consisting of atomically thin crystals layered on top of one another, lattice mismatch or rotation between the layers results in long-wavelength moir\'e superlattices. These moir\'e patterns can drive significant band…

Mesoscale and Nanoscale Physics · Physics 2019-10-01 Nathan R. Finney , Matthew Yankowitz , Lithurshanaa Muraleetharan , K. Watanabe , T. Taniguchi , Cory R. Dean , James Hone

Hexagonal borocarbonitrides (BCN) are a class of 2D materials, which display excellent catalytic activity for water splitting. Here, we report analysis of thermal stability, phonons and thermal conductivity of BCN monolayers over a wide…

Mesoscale and Nanoscale Physics · Physics 2018-10-17 Himanshu Chakraborty , Santosh Mogurampelly , Vivek K. Yadav , Umesh V. Waghmare , Michael L. Klein

Heterostructures made from van der Waals materials provide a template to investigate proximity effects at atomically sharp heterointerfaces. In particular, near-field charge and energy transfer in heterostructures made from semiconducting…

Motivated by the observation of polarization superlattices in twisted multilayers of hexagonal boron nitride ($h$-BN), we address the possibility of using these heterostructures for tailoring the properties of multilayer graphene by means…

Mesoscale and Nanoscale Physics · Physics 2023-05-29 Marta Brzezińska , Oleg V. Yazyev

We predict the stabilities of \alpha-graphynes and their boron nitride analogues(\alpha-BNyne), which are considered as competitors of graphene and two-dimensional hexagonal BN. Based on first-principles plane wave method, we investigated…

Materials Science · Physics 2013-02-11 V. Ongun Özçelik , S. Ciraci

Graphene devices on standard SiO2 substrates are highly disordered, exhibiting characteristics far inferior to the expected intrinsic properties of graphene[1-12]. While suspending graphene above the substrate yields substantial improvement…

Mesoscale and Nanoscale Physics · Physics 2010-10-19 C. R. Dean , A. F. Young , I. Meric , C. Lee , L. Wang , S. Sorgenfrei , K. Watanabe , T. Taniguchi , P. Kim , K. L. Shepard , J. Hone

In this work, we perform ab initio calculations, based on the density functional theory, of the effects on the graphene bilayer when we intercalate carbon atoms between the layers. We use the unit cell of the bilayer to construct larger…

Mesoscale and Nanoscale Physics · Physics 2020-01-31 A. K. M. Pinto , N. F. Frazão , D. L. Azevedo , F. Moraes

In our previous study, we have predicted the novel two-dimensional honeycomb monolayers of pnictogen. In particular, the structure and properties of the honeycomb monolayer of nitrogen, which we call nitrogene, are very unusual. In this…

Materials Science · Physics 2016-10-04 Jie-Sen Li , Wei-Liang Wang , Dao-Xin Yao

We calculate theoretically the disorder-limited conductivity of monolayer and bilayer graphene on hexagonal boron nitride (h-BN) substrates, comparing our theoretical results with the recent experimental results. The comparison leads to a…

Mesoscale and Nanoscale Physics · Physics 2011-03-17 S. Das Sarma , E. H. Hwang

We report the first observation of substitutional silicon atoms in single-layer hexagonal boron nitride (h-BN) using aberration corrected scanning transmission electron microscopy (STEM). The medium angle annular dark field (MAADF) images…

Materials Science · Physics 2020-01-29 Mohammad Reza Ahmadpour Monazam , Ursula Ludacka , Hannu-Pekka Komsa , Jani Kotakoski

Single layer core/shell structures consisting of graphene as core and hexagonal boron nitride as shell are studied using first-principles plane wave method within density functional theory. Electronic energy level structure is analysed as a…

Mesoscale and Nanoscale Physics · Physics 2014-08-05 S. Cahangirov , S. Ciraci

In 2015, a new two dimensional (2D) carbon allotrope, called phagraphene, was theoretically proposed. Based on this structure, we propose here a new boron nitride structure called phaBN. It is composed by three types of rings: pentagons,…

Materials Science · Physics 2020-12-09 J. M. Pontes , N. F. Frazão , David L. Azevedo , Jonas R. F. Lima

We model boron and nitrogen doped/codoped monolayer graphene to study its stability, interaction energy, electronic and thermal properties using density functional theory. It is found that a doped graphene sheet with non-bonded B or N atoms…

Mesoscale and Nanoscale Physics · Physics 2020-03-18 Nzar Rauf Abdullah , Hunar Omar Rashid , Mohammad T. Kareem , Chi-Shung Tang , Andrei Manolescu , Vidar Gudmundsson

We investigate the impact of monoatomic vacancies in 2D materials on the performance of magnetic tunnel junction (MTJ) devices using first-principles calculations within Density Functional Theory (DFT). Specifically, we analyze the…

Vertical and lateral heterogeneous structures of two-dimensional (2D) materials have paved the way for pioneering studies on the physics and applications of 2D materials. A hybridized hexagonal boron nitride (h-BN) and graphene lateral…

Silicon represents a common intrinsic impurity in graphene, commonly bonding to either three or four carbon neighbors respectively in a single or double carbon vacancy. We investigate the effect of the latter defect (Si-C$_4$) on the…

The role of defects in van der Waals heterostructures made of graphene and hexagonal boron nitride (h-BN) is studied by a combination of ab initio and model calculations. Despite the weak van der Waals interaction between layers, defects…

Materials Science · Physics 2017-01-04 B. Sachs , T. O. Wehling , M. I. Katsnelson , A. I. Lichtenstein

We have carried out ab initio electronic structure calculations on graphane (hydrogenated graphene) with single and double vacancy defects. Our analysis of the density of states reveal that such vacancies induce the mid gap states and…

Materials Science · Physics 2010-02-11 Bhalchandra S. Pujari , D. G. Kanhere

Graphene monolayer is a material with zero band gap, because of which its applications in optoelectronics are limited. The question arises, can we modify the optoelectronic properties of graphene by doping it with other atoms? Synthesis of…

Materials Science · Physics 2026-03-18 Samayita Das , Alok Shukla
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