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Contact integrators are a family of geometric numerical schemes which guarantee the conservation of the contact structure. In this work we review the construction of both the variational and Hamiltonian versions of these methods. We…

Numerical Analysis · Mathematics 2021-06-22 Alessandro Bravetti , Marcello Seri , Federico Zadra

Molecular dimers are widely utilized as a tool to investigate the structure-property relationships behind the complex photophysical processes of condensed-phase systems, where structural tuning remains a challenge. This approach often…

From studying the time evolution of the single electron density matrix within a density functional tight-binding formalism we study in a fully atomistic picture the electronic excitation transfer between two photosynthetic pigments in real…

Chemical Physics · Physics 2015-02-03 María Belén Oviedo , Cristián G. Sánchez

Cavity-mediated light-matter coupling can dramatically alter opto-electronic and physico-chemical properties of a molecule. Ab initio theoretical predictions of these systems need to combine non-perturbative, many-body electronic structure…

Quantum Physics · Physics 2024-06-19 Derek S. Wang , Tomáš Neuman , Johannes Flick , Prineha Narang

Owing to the possibility of controlling its specific mechanical behaviors up taken by irradiated by light at particular wavelengths, the photoisomerization hydrogels have a broad range of potential applications. A theory connecting the…

Chemical Physics · Physics 2023-05-16 Xinyu Liu , Qingsheng Yang , Wei Rao

The physics of light-matter interactions is strongly constrained by both the small value of the fine-structure constant and the small size of the atom. Overcoming these limitations is a long-standing challenge. Recent theoretical and…

We obtain an expression for the matrix element for a twisted (Laguerre-Gaussian profile) photon scattering from a hydrogen atom. We consider photons incoming with an orbital angular momentum (OAM) of $\ell \hbar$, carried by a factor of…

Quantum Physics · Physics 2013-02-06 Basil S. Davis , L. Kaplan , J. H. McGuire

Explicit and semi-explicit geometric integration schemes for dissipative perturbations of Hamiltonian systems are analyzed. The dissipation is characterized by a small parameter $\epsilon$, and the schemes under study preserve the…

Numerical Analysis · Mathematics 2015-03-19 Klas Modin , Gustaf Söderlind

Efficient coupling of light to single atomic systems has gained considerable attention over the past decades. This development is driven by the continuous growth of quantum technologies. The efficient coupling of light and matter is an…

Quantum Physics · Physics 2015-07-24 Markus Sondermann , Gerd Leuchs

We have developed a symmetry-adapted modeling procedure for molecules and crystals. By using the completeness of multipoles to express spatial and time-reversal parity-specific anisotropic distributions, we can generate systematically the…

Materials Science · Physics 2023-05-12 Hiroaki Kusunose , Rikuto Oiwa , Satoru Hayami

The formulation of the interaction of matter with singular light fields needs special care. In a recent article [Phys.~Rev.~A {\bf 91}, 033808 (2015)] we have shown that the Hamiltonian describing the interaction of a twisted light beam…

Optics · Physics 2017-02-01 G. F. Quinteiro , D. E. Reiter , T. Kuhn

A photonic circuit is generally described as a structure in which light propagates by unitary exchange and transfers reversibly between channels. In contrast, the term `diffusive' is more akin to a chaotic propagation in scattering media,…

We consider an atom (represented by a two-level system) moving in front of a dielectric plate, and study how traces of dissipation and decoherence (both effects induced by vacuum field fluctuations) can be found in the corrections to the…

Quantum Physics · Physics 2017-09-13 Fernando C. Lombardo , Paula I. Villar

We represent low dimensional quantum mechanical Hamiltonians by moderately sized finite matrices that reproduce the lowest O(10) boundstate energies and wave functions to machine precision. The method extends also to Hamiltonians that are…

Quantum Physics · Physics 2015-06-03 Johann Foerster , Alejandro Saenz , Ulli Wolff

The emergent photoactive materials through photochemistry make it possible to directly convert photon energy to mechanical work. There is much recent work in developing appropriate materials and a promising new system is semi-crystalline…

Soft Condensed Matter · Physics 2021-03-24 Ruobing Bai , Eric Ocegueda , Kaushik Bhattacharya

The collective response of a system is profoundly shaped by the interaction dynamics between its constituent elements. In physics, tailoring these interactions can enable the observation of unusual phenomena that are otherwise inaccessible…

For a prototype quadratic Hamiltonian describing a driven, dissipative system, exact matrix elements of the reduced density matrix are obtained from a generating function in terms of the normal characteristic functions. The approach is…

Quantum Physics · Physics 2021-08-24 Sh. Saedi , F. Kheirandish

In this paper we consider dynamics of a molecular system subjected to external pumping by a light source. Within a completely quantum mechanical treatment, we derive a general formula, which enables to asses effects of different light…

Biological Physics · Physics 2012-01-30 Tomas Mancal , Leonas Valkunas

We develop a density matrix formalism to describe coupled electron-nuclear dynamics. To this end we introduce an effective Hamiltonian formalism that describes electronic transitions and small (quantum) nuclear fluctuations along a…

Chemical Physics · Physics 2020-09-07 Eugene Stolyarov , Alexander White , Dmitry Mozyrsky

We investigate theoretically the influence of strong light-matter coupling on the initial steps of the photo-triggered singlet-fission process. In particular we focus on intra-molecular singlet fission in a TIPS-pentacene dimer derivative…

Chemical Physics · Physics 2024-06-07 Lisamaria Wallner , Charlotte Remnant , Oriol Vendrell