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Rutile GeO$_2$ is a visible and near-ultraviolet-transparent oxide that has not been explored for semiconducting applications in electronic and optoelectronic devices. We investigate the electronic and optical properties of rutile GeO$_2$…

Materials Science · Physics 2019-08-27 Kelsey A. Mengle , Sieun Chae , Emmanouil Kioupakis

Ultra-wide-band-gap (UWBG) semiconductors have tremendous potential to advance electronic devices as device performance improves superlinearly with increasing gap. Ambipolar doping, however, has been a major challenge for UWBG materials as…

Materials Science · Physics 2019-03-15 Sieun Chae , Jihang Lee , Kelsey A. Mengle , John T. Heron , Emmanouil Kioupakis

Rutile Germanium Dioxide (r-GeO$_2$) has been identified as an ultrawide bandgap (UWBG) semiconductor recently, featuring a bandgap of 4.68 eV, comparable to Ga$_2$O$_3$ but offering bipolar dopability, higher electron mobility, higher…

Applied Physics · Physics 2024-07-04 Imteaz Rahaman , Bobby Duersch , Hunter D. Ellis , Michael A. Scarpulla , Kai Fu

Rutile germanium dioxide (r-GeO$_2$) is a promising ultra-wide bandgap (UWBG) semiconductor, offering a high theoretical Baliga figure of merit, potential for p-type doping, and favorable thermal and electrical properties. In this work, we…

Materials Science · Physics 2025-08-05 Imteaz Rahaman , Anthony Bolda , Botong Li , Hunter D. Ellis , Kai Fu

VO2, of interest for decades due to both its phenomenology and its potential applications, has a monoclinic distortion of the rutile crystal structure at ambient temperature that is coupled to its metal-insulator transition (MIT). In…

Materials Science · Physics 2022-07-14 Xin Gui , Robert J. Cava

Rutile CrO$_2$ is an important half-metallic ferromagnetic material, which is also widely used in magnetic recording. In an attempt to find the conditions, which lead to the increase the Curie temperature ($T_{\rm C}$), we study…

Strongly Correlated Electrons · Physics 2016-05-03 I. V. Solovyev , I. V. Kashin , V. V. Mazurenko

We performed systematic thermal conductivity measurements on heavily hole-doped Ba$_{1-x}$K$_x$Fe$_2$As$_2$ single crystals with 0.747 $\leq x \leq$ 0.974. At $x$ = 0.747, the $\kappa_0/T$ is negligible, indicating nodeless superconducting…

Superconductivity · Physics 2016-01-20 X. C. Hong , A. F. Wang , Z. Zhang , J. Pan , L. P. He , X. G. Luo , X. H. Chen , S. Y. Li

High thermoelectric performance in oxides requires stable conductive materials that have suitable band structures. Here we show based on an analysis of the thermopower and related properties using first-principles calculations and Boltzmann…

Materials Science · Physics 2013-04-22 Xin Chen , David Parker , Mao-Hua Du , David J. Singh

The electronic and optical properties of self-trapped holes in kappa-phase orthorhombic Ga2O3 in conjunction with isoelectronic and acceptor dopants were studied using hybrid density functional theory. Hole trapping was found to be…

Materials Science · Physics 2026-05-18 Eric Welch , Nathan Rabelo Martins , Luisa Scolfaro , Luiz A. F. C. Viana , Pablo D. Borges

Rutile germanium dioxide (r-GeO2) has recently emerged as a promising ultrawide-bandgap (UWBG) semiconductor owing to its wide bandgap (~4.4-5.1 eV), ambipolar doping potential, and high theoretical thermal conductivity. However,…

Rutile Sn$_{1-x}$Ge$_x$O$_{2}$ alloys are promising materials for high-power electronic applications due to their dopability and tunable ultra-wide band gaps. We use first-principles density functional theory and statistical mechanics to…

Materials Science · Physics 2026-01-21 Yann L. Müller , Alp Umut Kurbay , Xiao Zhang , Emmanouil Kioupakis , Anirudh Raju Natarajan

As-Based Zintl compounds Ba1-xKxCd2As2 crystallized in the CaAl2Si2-type structure (space group P3-m1) were prepared using solid-state reactions followed by hot-pressing. We have successfully substituted K for Ba up to x = 0.08, producing…

Materials Science · Physics 2018-11-28 H. Kunioka , K. Kihou , H. Nishiate , a A. Yamamoto , H. Usui , K. Kuroki , C. H. Lee

Wide-bandgap two-dimensional (2D) beta-TeO2 has been reported as a high-mobility p-type transparent semiconductor (Nat. Electron. 2021, 4, 277-283), attracting significant attention. This "breakthrough" not only challenges the conventional…

Materials Science · Physics 2024-12-30 Zewen Xiao , Chen Qiu , Su-Huai Wei , Hideo Hosono

Rutile germanium oxide (r-GeO2) has shown potential for ultrawide bandgap semiconductor applications such as power conversion and UV optoelectronics. Homoepitaxial substrates will be key for achieving phase pure and doped r-GeO2 thin films…

Materials Science · Physics 2026-04-07 Avery-Ryan Ansbro , John T. Heron

RuO$_2$ was considered for a long time to be a paramagnetic metal with an ideal rutile-type structure down to low temperatures, but recent studies on single-crystals claimed evidence for antiferromagnetic order and some symmetry breaking in…

Large high-quality single crystals of hole-doped iron-based superconductor (Ba$_{1-x}$K$_x$)Fe$_2$As$_2$ were grown over a broad composition range $0.22 \leq x \leq 1$ by inverted temperature gradient method. We found that high soaking…

Semiconductor heterostructures capable of separating photogenerated electrons and holes have a wide range of optoelectronic applications, including photodetectors, solar cells, and photocatalysts. ${\beta}$-Ga$_2$O$_3$ and rutile GeO$_2$…

Materials Science · Physics 2025-09-25 D. Q. Fang

Although $\beta$-TeO$_2$ is a promising $p$-type transparent conducting oxide (TCO) due to the large optical gap ($\sim$ 3.7 eV) and a light effective hole mass, its hole dopability still remains unexplored. In this work, electronic…

Materials Science · Physics 2025-11-20 Vu Thi Ngoc Huyen , Soungmin Bae , Rafael Costa-Amaral , Yu Kumagai

Rutile germanium dioxide (r-GeO$_2$) is a recently predicted ultrawide-band-gap semiconductor with potential applications in high-power electronic devices, for which the carrier mobility is an important material parameter that controls the…

Materials Science · Physics 2020-11-10 Kyle Bushick , Kelsey A. Mengle , Sieun Chae , Emmanouil Kioupakis

Ultrawide bandgap (UWBG) semiconductors are promising for next-generation power electronics, largely attributed to their substantial bandgap and exceptional breakdown electric field. Rutile GeO2 (r-GeO2) emerges as a promising alternative,…

Materials Science · Physics 2024-10-18 Imteaz Rahaman , Botong Li , Hunter D. Ellis , Brian Roy Van Devener , Randy C Polson , Kai Fu
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