Related papers: Water Ice Deposition and Growth in Molecular Cloud…
A model is proposed for the formation of water ice mantles on grains in interstellar clouds. This occurs by direct accretion of monomers from the gas, be they formed by gas or surface reactions. The model predicts the existence of a…
We search for frozen water and its processing around young stellar objects (YSOs of class I/II). We try to detect potential, regional differences in water ice evolution within YSOs, which is relevant to understanding the chemical structure…
Context. Millimetric observations have measured high degrees of molecular deuteration in several species seen around low-mass protostars. The Herschel Space Telescope, launched in 2009, is now providing new measures of the deuterium…
The properties of dust change during the transition from diffuse to dense clouds as a result of ice formation and dust coagulation, but much is still unclear about this transformation. We present 2-20 micron spectra of 49 field stars behind…
Infrared photometry and spectroscopy (1-25 um) of background stars reddened by the Lupus molecular cloud complex are used to determine the properties of the grains and the composition of the ices before they are incorporated into…
Observations of star forming environments revealed that the abundances of some deuterated interstellar molecules are markedly larger than the cosmic D/H ratio of 10-5. Possible reasons for this pointed to grain surface chemistry. How- ever,…
Context: Observations of scattered light in the 1-5 $\mu$m range have revealed dust grains in molecular cores with sizes larger than commonly inferred for the diffuse interstellar medium. It is currently unclear whether these grains are…
We model the temperature and chemical structure of molecular clouds as a function of depth into the cloud, assuming a cloud of constant density n illuminated by an external FUV (6 eV < E < 13.6 eV) flux G_0 (scaling factor in multiples of…
In regions where stars form, variations in density and temperature can cause gas to freeze-out onto dust grains forming ice mantles, which influences the chemical composition of a cloud. The aim of this paper is to understand in detail the…
Water (H2O) ice is an important solid constituent of many astrophysical environments. To comprehend the role of such ices in the chemistry and evolution of dense molecular clouds and comets, it is necessary to understand the freeze-out,…
To explain grain growth and destruction in warm media, ice mantle formation and sublimation in cold media, and gas line emission spectroscopy, astrochemical models must mimic the gas--solid abundance ratio. Ice-sublimation mechanisms…
The formation of clouds affects brown dwarf and planetary atmospheres of nearly all effective temperatures. Iron and silicate condense in L dwarf atmospheres and dissipate at the L/T transition. Minor species such as sulfides and salts…
Major components of ices on interstellar grains in molecular clouds - water and carbon oxides - occur at various optical depths. This implies that selective desorption mechanisms are at work. An astrochemical model of a contracting low-mass…
We present Herschel/HIFI observations of nine transitions of \hho and \hheo towards six high-mass star-forming regions, obtained as part of the PRISMAS Key Program. Water vapor in translucent clouds is detected in absorption along every…
Dust grains grow their sizes in the interstellar clouds (especially in molecular clouds) by accretion and coagulation. Here we model and test these processes by examining the consistency with the observed variation of the extinction curves…
Potential effects of sublimation of water ice from very slowly moving millimeter-sized and larger grains, a product of activity at ~10 AU or farther from the Sun driven presumably by annealing of amorphous water ice, are investigated by…
This paper reviews recent observations of water in Galactic interstellar clouds and nearby galactic nuclei. Two results are highlighted: (1) Multi-line H$_2$O mapping of the Orion Bar shows that the water chemistry in PDRs is driven by…
Data from the Five College Radio Astronomy Observatory CO Mapping Survey of the Taurus molecular cloud are combined with extinction data for a sample of 292 background field stars to investigate the uptake of CO from the gas to icy grain…
The depth-dependent abundance of both gas-phase and solid-state water within dense, quiescent, molecular clouds is important to both the cloud chemistry and gas cooling. Where water is in the gas phase, it's free to participate in the…
(abridged) We report a study of the relation between dust and gas over a 100deg^2 area in the Taurus molecular cloud. We compare the H2 column density derived from dust extinction with the CO column density derived from the 12CO and 13CO J=…