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The static free energy of glassy systems can be expressed in terms of the Parisi order parameter function. When this function has a discontinuity, the location of the step is determined by maximizing the free energy. In dynamics a…

Condensed Matter · Physics 2009-10-28 Th. M. Nieuwenhuizen

Glasses feature a broad distribution of relaxation times and activation energies without an obvious characteristic scale. At the same time, macroscopic quantities such as Newtonian viscosity and nonlinear plastic deformation, are…

Soft Condensed Matter · Physics 2018-08-09 Edan Lerner , Eran Bouchbinder

We explain the findings by Di Leonardo et al. [Phys. Rev. Lett. 84, 6054 (2000)] that the effective temperature of a Lennard-Jones glass depends only on the final value of the density in the volume and/or temperature jump that produces the…

Statistical Mechanics · Physics 2013-05-14 Nicoletta Gnan , Claudio Maggi , Thomas B. Schroeder , Jeppe C. Dyre

A glass is conventionally obtained by cooling a bulk supercooled liquid through its glass transition temperature. The discovery of ultrastable glasses prepared using physical vapor deposition, together with the recent multiplication of…

Statistical Mechanics · Physics 2026-05-13 Leonardo Galliano , Ludovic Berthier

The microscopic approach to calculating the free energy of a three-dimensional Ising-like system in a homogeneous external field is developed in the higher non-Gaussian approximation (the $\rho^6$ model) at temperatures above the critical…

Statistical Mechanics · Physics 2008-12-11 I. V. Pylyuk , M. P. Kozlovskii

The richness of the mean-field solution of simple glasses leaves many of its features challenging to interpret. A minimal model that illuminates glass physics the same way the random energy model clarifies spin glass behavior would…

Disordered Systems and Neural Networks · Physics 2025-03-14 Gilles Bonnet , Patrick Charbonneau , Giampaolo Folena

We study the equilibrium thermodynamics of quantum hard spheres in the infinite-dimensional limit, determining the boundary between liquid and glass phases in the temperature-density plane by means of the Franz-Parisi potential. We find…

Statistical Mechanics · Physics 2023-11-10 Michael Winer , Christopher L. Baldwin , Richard Barney , Victor Galitski , Brian Swingle

By extending the concept of diffusion to the potential energy landscapes (PELs), we introduce the mean-squared energy difference (MSED) as a novel quantity to investigate the intrinsic properties of glass. MSED can provide a clear…

Disordered Systems and Neural Networks · Physics 2025-04-11 Dianmo Zhang , Deyan Sun , Xingao Gong

The glass transition refers to the non-equilibrium process by which an equilibrium liquid is transformed to a non-equilibrium disordered solid, or vice versa. Associated response functions, such as heat capacities, are markedly different on…

Soft Condensed Matter · Physics 2013-03-26 Aaron S. Keys , Juan P. Garrahan , David Chandler

We present a quantum statistical analysis of a microscopic mean-field model of structural glasses at low temperatures. The model can be thought of as arising from a random Born von Karman expansion of the full interaction potential. The…

Disordered Systems and Neural Networks · Physics 2015-05-14 J. van Baardewijk , R. Kuehn

To investigate the consequences of component confinement such as at a glass transition and the well-known energy or enthalpy gap (between the glass and the perfect crystal at absolute zero, see text), we follow our previous approach [Phys.…

Statistical Mechanics · Physics 2015-03-17 P. D. Gujrati

Ultrastable glasses have risen to prominence due to their potentially useful material properties and the tantalizing possibility of a general method of preparation via vapor deposition. Despite the importance of this novel class of…

Statistical Mechanics · Physics 2014-12-09 Glen M Hocky , Ludovic Berthier , David R. Reichman

In this paper we develop a method introduced by one of us to study metastable states in spin glasses. We consider a `potential function' defined as the free energy of a system at a given temperature $T$ constrained to have a fixed overlap…

Condensed Matter · Physics 2009-10-28 S. Franz , G. Parisi

A new mathematical model for non-equilibrium evaporation/condensation including boiling effect is proposed. A simplified differential-algebraic system of equations is obtained. A code to solve numerically this differential-algebraic system…

Statistical Mechanics · Physics 2018-03-09 B. V. Librovitch , A. F. Nowakowski , F. C. G. A. Nicolleau , T. M. Michelitsch

Recent numerical simulations of a disordered system (Preprint arXiv:condmat/0307554) have shown the existence of two different relaxational processes (called stimulated and spontaneous) characterizing the relaxation observed in structural…

Disordered Systems and Neural Networks · Physics 2007-05-23 F. Ritort

Computer simulations have been employed in recent years to evaluate the configurational entropy changes in model glass-forming liquids. We consider two methods, both of which involve the calculation of the `intra-basin' entropy as a means…

Statistical Mechanics · Physics 2009-10-31 Srikanth Sastry

We consider two non-mean-field models of structural glasses built on a hierarchical lattice. First, we consider a hierarchical version of the random energy model (HREM), and we prove the existence of the thermodynamic limit and…

Mathematical Physics · Physics 2014-09-09 Michele Castellana

The minimal cooling speed required to form a glass is obtained for a simple solvable energy landscape model. The model, made from a two-level system modified to include the topology of the energy landscape, is able to capture either a glass…

Soft Condensed Matter · Physics 2015-10-29 J. Quetzalcóatl Toledo-Marín , Isaac Pérez Castillo , Gerardo G. Naumis

We investigate both free energy and complexity of the spherical bipartite spin glass model. We first prove a variational formula in high temperature for the limiting free energy based on the well-known Crisanti-Sommers representation of the…

Probability · Mathematics 2015-06-19 Antonio Auffinger , Wei-Kuo Chen

We show that a glass transition, signaled by a peak in the specific heat vs. temperature, can occur because a glassy system that shows no signs of aging progresses so slowly through the energy landscape that the time needed to obtain an…

Disordered Systems and Neural Networks · Physics 2007-05-23 Clare C. Yu , Herve M. Carruzzo