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Similarity between quantum mechanics and thermodynamics is discussed. It is found that if the Clausius equality is imposed on the Shannon entropy and the analogue of the heat quantity, then the value of the Shannon entropy comes to formally…

Statistical Mechanics · Physics 2015-05-20 Sumiyoshi Abe , Shinji Okuyama

This short book is an elementary course on entropy, leading up to a calculation of the entropy of hydrogen gas at standard temperature and pressure. Topics covered include information, Shannon entropy and Gibbs entropy, the principle of…

Statistical Mechanics · Physics 2025-11-18 John C. Baez

Shannon and Khinchin showed that assuming four information theoretic axioms the entropy must be of Boltzmann-Gibbs type, $S=-\sum_i p_i \log p_i$. Here we note that in physical systems one of these axioms may be violated. For non-ergodic…

Statistical Mechanics · Physics 2015-03-19 Stefan Thurner , Rudolf Hanel

The classical thermostatics of equilibrium processes is shown to possess a quantum-mechanical dual theory with a finite-dimensional Hilbert space of quantum states. Specifically, the kernel of a certain Hamiltonian operator becomes the…

Mathematical Physics · Physics 2017-04-05 D. Cabrera , P. Fernandez de Cordoba , J. M. Isidro , J. Vazquez Molina

Among various possible routes to extend entropy and thermodynamics to nonequilibrium steady states (NESS), we take the one which is guided by operational thermodynamics and the Clausius relation. In our previous study, we derived the…

Statistical Mechanics · Physics 2013-02-13 Teruhisa S. Komatsu , Naoko Nakagawa , Shin-ichi Sasa , Hal Tasaki

We propose an operational definition of the entropy of cosmological perturbations based on a truncation of the hierarchy of Green functions. The value of the entropy is unambiguous despite gauge invariance and the renormalization procedure.…

High Energy Physics - Theory · Physics 2008-11-26 David Campo , Renaud Parentani

We initially prepare a quantum linear oscillator weakly coupled to a bath in equilibrium at an arbitrary temperature. We disturb this system by varying a Hamiltonian parameter of the coupled oscillator, namely, either its spring constant or…

Statistical Mechanics · Physics 2015-05-27 Ilki Kim

Many branches of theoretical and applied mathematics require a quantifiable notion of complexity. One such circumstance is a topological dynamical system - which involves a continuous self-map on a metric space. There are many notions of…

Category Theory · Mathematics 2024-03-12 Suddhasattwa Das

Entropy is a quantity for counting physical degrees of freedom in a system. At a finite temperature, one can use thermal entropy to study thermodynamical properties. At zero temperature, entanglement entropy is expected to provide a…

High Energy Physics - Theory · Physics 2018-10-29 Chen-Te Ma

Entropic Dynamics is a framework in which dynamical laws are derived as an application of entropic methods of inference. No underlying action principle is postulated. Instead, the dynamics is driven by entropy subject to the constraints…

Quantum Physics · Physics 2015-09-11 Ariel Caticha

Jacobson's thermodynamic derivation of the Einstein equations was originally applied only to local Rindler horizons. But at least some parts of that construction can usefully be extended to give meaningful results for arbitrary bifurcate…

General Relativity and Quantum Cosmology · Physics 2017-11-29 Valentina Baccetti , Matt Visser

There is a long tradition of thinking of thermodynamics, not as a theory of fundamental physics (or even a candidate theory of fundamental physics), but as a theory of how manipulations of a physical system may be used to obtain desired…

History and Philosophy of Physics · Physics 2020-10-28 Wayne C. Myrvold

The concept of entropy in nonequilibrium macroscopic systems is investigated in the light of an extended equation of motion for the density matrix obtained in a previous study. It is found that a time-dependent information entropy can be…

Statistical Mechanics · Physics 2009-11-10 W. T. Grandy

For a dynamical system far from equilibrium, one has to deal with empirical probabilities defined through time-averages, and the main problem is then how to formulate an appropriate statistical thermodynamics. The common answer is that the…

Statistical Mechanics · Physics 2009-11-10 A. Carati

In a companion article it was shown in a certain precise sense that, for any thermodynamical theory that respects the Kelvin-Planck Second Law, the Hahn-Banach Theorem immediately ensures the existence of a pair of continuous functions of…

Mathematical Physics · Physics 2023-08-22 Martin Feinberg , Richard B. Lavine

In arXiv:1801.01238 a variation of Bowen's topological entropy that can be applied to the study of discontinuous semiflows on compact metric spaces was introduced. The main novetly is the use of certain family of pseudosemimetrics…

Dynamical Systems · Mathematics 2019-09-24 Nelda Jaque , Bernardo San Martín

In this work, the space of admissible entropy functions for the compressible multicomponent Euler equations is explored, following up on [Harten, \textit{J. Comput. Phys.}, 49 (1), 1983, pp. 151-164]. This effort allows us to prove a…

Analysis of PDEs · Mathematics 2019-09-24 Ayoub Gouasmi , Karthik Duraisamy , Scott M. Murman , Eitan Tadmor

In this paper, unambiguous redefinitions of heat and work are presented for quantum thermodynamic systems. We will use genuine reasoning based on which Clausius originally defined work and heat in establishing thermodynamics. The change in…

Quantum Physics · Physics 2023-03-15 B. Ahmadi , S. Salimi , A. S. Khorashad

Physical meaning and a duality of concepts of wave function, action functional, entropy, the Pointing vector, the Einstein tensor and so on can be disclosed by investigating the state of material systems such as thermodynamic and gas…

General Physics · Physics 2010-01-12 L. I. Petrova

Defining the entropy of classical particles raises a number of paradoxes and ambiguities, some of which have been known for over a century. Several, such as Gibbs' paradox, involve the fact that classical particles are distinguishable, and…

Soft Condensed Matter · Physics 2016-12-28 Michael E. Cates , Vinothan N. Manoharan