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Half Heusler (HH) thermoelectric alloys provide a wide platform to choose materials with non-toxic and earth abundant elements. This article presents an ab-initio theoretical evaluation of electrical and thermal transport properties of…

Materials Science · Physics 2016-10-21 Vikram , Jiban Kangsabanik , Enamullah , Aftab Alam

To understand the effect of isoelectronic substitution on thermoelectric properties of TiCoSb based half - Heusler (HH) alloys, we have systematically studied the transport properties with substitution of Zr at Ti and Bi at Sb sites. The…

Materials Science · Physics 2019-09-04 Mukesh K. Choudhary , P. Ravindran

Low-dimensional layered materials have attracted tremendous attentions due to their wide range of physical and chemical properties and potential applications in electronic devices. Using first-principles method taking into account the…

Materials Science · Physics 2018-08-16 Z. Z. Zhou , H. J. Liu , D. D. Fan , C. Y. Sheng , G. H. Cao

Over the last two decades a plethora of new thermoelectric materials, their alloys, and their nanostructures were synthesized. The ZT figure of merit, which quantifies the thermoelectric efficiency of these materials increased from values…

Materials Science · Physics 2023-07-27 Neophytos Neophytou , Pankaj Priyadarshi , Zhen Li , Patrizio Graziosi

We investigate the strain-rate-dependent mechanical behavior and deformation mechanisms of a refractory high entropy alloy, Ti29Zr24Nb23Hf24 (at.%), with a single-phase body-centered cubic (BCC) structure. High-temperature compression tests…

Materials Science · Physics 2020-12-03 Tangqing Cao , Wenqi Guo , Wang Lu , Yunfei Xue , Wenjun Lu , Jing Su , Christian H. Liebscher , Chang Liu , Gerhard Dehm

Achieving high thermoelectric performance requires efficient manipulation of thermal conductivity and a fundamental understanding of the microscopic mechanisms of phonon transport in crystalline solids. One of the major challenges in…

Materials Science · Physics 2023-05-18 Jiaoyue Yuan , Yubi Chen , Bolin Liao

Whereas thermoelectric performance is normally limited by the figure of merit ZT, transverse thermoelectrics can achieve arbitrarily large temperature differences in a single leg even with inferior ZT by being geometrically tapered. We…

Materials Science · Physics 2015-06-15 Chuanle Zhou , S. Birner , Yang Tang , K. Heinselman , M. Grayson

The mechanisms that govern a previously unexplained hardening effect of a single phase Cu-30wt%Zn {\alpha}-brass after heating have been investigated. After cold-work, the alloy possesses an increased yield strength and hardening rate only…

The field of thermoelectric materials has undergone a revolutionary transformation over the last couple of decades as a result of the ability to nanostructure and synthesize myriads of materials and their alloys. The ZT figure of merit,…

Thermoelectricity is a promising avenue for harvesting energy but large-scale applications are still hampered by the lack of highly-efficient low-cost materials. Recently, Fe$_2YZ$ Heusler compounds were predicted theoretically to be…

Materials Science · Physics 2019-11-21 Sébastien Lemal , Fabio Ricci , Daniel I. Bilc , Matthieu J. Verstraete , Philippe Ghosez

The knowledge of Half-Heusler compounds have attracted much attention as materials for thermoelectric applications. In this work, we investigate, using first-principles calculations, the electronic, vibrational, and defect properties of…

Materials Science · Physics 2024-10-30 Mateus Corradini Lopes , Alex Antonelli

In order to improve the thermoelectric performance of TiCoSb we have substituted 50% of Ti equally with Zr and Hf at Ti site and Sb with Sn and Se equally at Sb site. The electronic structure of Ti0.5Zr0.25Hf0.25CoSn0.5Se0.5 is investigated…

Materials Science · Physics 2018-05-09 Mukesh K. Choudhary , P Ravindran

Boltzmann transport calculations based on band structures generated with density functional theory (DFT) are often used in the discovery and analysis of thermoelectric materials. In standard implementations, such calculations require dense…

Materials Science · Physics 2018-07-04 Kristian Berland , Clas Persson

Achieving low thermal conductivity and good electrical properties is a crucial condition for thermal energy harvesting materials. Nanostructuring offers a very powerful tool to address both requirements: in nanostructured materials,…

Mesoscale and Nanoscale Physics · Physics 2018-09-14 Giuseppe Romano , Jesús Carrete , Alexie M. Kolpak , David Broido

Half-Heusler (HH) phases have garnered much attention as thermally stable and non-toxic thermoelectric materials for power conversion. The most studied alloys to date utilize Hf, Zr, and Ti as the base components. These alloys can achieve a…

Materials Science · Physics 2022-10-26 Mousumi Mitra , Allen Benton , Md Sabbir Akhanda , Jie Qi , Mona Zebarjadi , David J. Singh , S. Joseph Poon

We present a high-accuracy procedure for electronic structure calculations of strongly correlated materials. To address limitations in current electronic structure methods, we employ density functional theory in combination with the…

Wearable biosensors increasingly require continuous and battery-free power sources, but conventional skin-mounted thermoelectric generators are limited by the small temperature differences available in real environments. This work…

Computational Engineering, Finance, and Science · Computer Science 2025-12-10 Hamidreza Moradi , Melika Filvantorkaman

Measuring terahertz (THz) conductivity on an ultrafast time scale is an excellent way to observe charge-carrier dynamics in semiconductors as a function of time after photoexcitation. However, a conductivity measurement alone cannot…

Efficient thermoelectric materials are highly desirable, and the quest for finding them has intensified as they could be promising alternatives to fossil energy sources. Here we present a general first-principles approach to predict, in…

Materials Science · Physics 2017-10-10 Maribel Núñez-Valdez , Zahed Allahyari , Tao Fan , Artem R. Oganov

There is evidence that magnetism can potentially increase the thermopower of materials, most likely due to magnon scattering, suggesting the incorporation of intrinsic magnetic semiconductors in non-magnetic thermoelectric materials. Here,…