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Highly active, durable and cost-effective electrocatalysts for water oxidation to evolve oxygen gas hold a key to a range of renewable energy solutions including water splitting and rechargeable metal-air batteries. Here, we report the…

An extremely efficient ethanol fuel cell electrode is produced by combining the large surface area of vertically oriented and highly conductive few-layer graphene sheets with electrochemically deposited palladium nanoparticles. The…

Chemical Physics · Physics 2016-10-18 Michael Höltig , Charlotte Ruhmlieb , Tobias Kipp , Alf Mews

In graphene based materials, the energy storage capacity is usually improved by rich porous structures with extremely high surface area. By utilizing surface corrugations, this work shows an alternative strategy to activate graphene…

Applied Physics · Physics 2021-10-07 Longsheng Zhong , Chang Wu , Xiaojing Zhu , Shulai Lei , Guijie Liang , Sepidar Sayyar , Biao Gao , Liangxu Lin

In order for the widely discussed benefits of flow batteries for electrochemical energy storage to be applied at large scale, the cost of the electrochemical stack must come down substantially. One promising avenue for reducing stack cost…

Chemical Physics · Physics 2015-06-19 W. A. Braff , M. Z. Bazant , C. R. Buie

A method of electronic conductivity measurement is presented. It combines two well known methods of electrochemistry: cyclic voltammetry and chronoamperometry. This DC technique uses the Hebb/Wagner approach to block ionic conduction when…

Systems and Control · Electrical Eng. & Systems 2024-10-01 Veyis Gunes , Jean-Yves Botquelen , Odile Bohnke

In recent years, impressive advances in harvesting renewable energy have led to pressing demand for the complimentary energy storage technology. Here, a high coulombic efficiency (~ 99.7%) Al battery is developed using earth-abundant…

Chemical Physics · Physics 2022-06-08 Michael Angell , Chun-Jern Pan , Youmin Rong , Chunze Yuan , Meng-Chang Lin , BingJoe Hwang , Hongjie Dai

In recent years, constant applied potential molecular dynamics has allowed to study the structure and dynamics of the electrochemical double-layer of a large variety of nanoscale capacitors. Nevertheless it remained impossible to simulate…

Materials Science · Physics 2021-09-03 Thomas Dufils , Michiel Sprik , Mathieu Salanne

Lithium fluorinated carbon is one of the most promising chemistries for high-energy-density primary energy storage systems in applications where rechargeability is not required. Though Li/CFx demonstrates high energy density under ambient…

NiCo2O4 of varying nanostrucutures ranging from nanowires, nanoplates to nano-plates@nanowires were successfully grown on microporous (MP) Ni foams via one-step hydrothermal process. The investigation of electrochemical capacitance favors…

Materials Science · Physics 2016-04-05 Qin Guo , Mengjie Xu , Rongjun Xu , Ying Zhao , Boyun Huang

Lithium-sulfur (Li-S) batteries offer substantial theoretical energy density gains over Li-ion bat-teries, a crucial factor for transportation electrification. In addition, sulfur is an earth-abundant, inexpensive material obtainable from…

Materials Science · Physics 2025-01-22 Praveen Balaji T , Soumyadip Choudhury , Ernesto E. Marinero

Electrochemical water splitting technology for producing "green hydrogen" is important for the global mission of carbon neutrality. Electrocatalysts with decent performance at high current densities play a central role in the industrial…

Chemical Physics · Physics 2022-02-16 Yuting Luo , Zhiyuan Zhang , Manish Chhowalla , Bilu Liu

Molecular dynamics computer simulations which employ the embedded-atom potential show that nanowires of gold exist as multishelled structures. We simulate double-walled gold nanowires and calculate the capacitance of a finite nanometer-size…

Materials Science · Physics 2007-05-23 J. Stepanic , G. Bilalbegovic

The distribution of electric fields within the electrochemical double layer depends on both the electrode and electrolyte in complex ways. These fields strongly influence chemical dynamics in the electrode-electrolyte interface, but cannot…

Electric double layer (EDL) formation underlies the functioning of supercapacitors and several other electrochemical technologies. Here, we study how the EDL formation near two flat blocking electrodes separated by $2L$ is affected by…

Chemical Physics · Physics 2025-09-23 David Fertig , Mathijs Janssen

Although photoelectrochemical water splitting is likely to be an important and powerful tool to provide environmentally friendly hydrogen, most developments in this field have been conducted on a laboratory scale so far. In order for the…

Despite several decades of development, microfluidics lacks a sealing material that can be readily fabricated, leak-tight under high liquid water pressure, stable over a long time, and vacuum compatible. In this paper, we report the…

A new type of a capacitor with a very high volumetric capacitance is proposed. It is based upon the known phenomenon of a sharp increase of the dielectric constant of the metal-insulator composite in the vicinity of the percolation…

Mesoscale and Nanoscale Physics · Physics 2015-05-27 A. L. Efros

We firstly demonstrate physically-prepared compliant PVA hydrogel electrodes as a promising supplement in dielectric elastomer actuators. They are capable of conducting high voltages over 5 kV without electrolysis by an electrical double…

Materials Science · Physics 2014-09-10 Chengyi Xu , Chunye Xu , Jianming Zheng

It was aimed to determine whether plasma processing could contribute to enhanced capacitance and energy density of activated carbon electrode based electrochemical capacitors, through the formation of additional surface charges. While an…

Materials Science · Physics 2016-07-13 M. Muriel , R. Narayanan , P. R. Bandaru

Reliable first-principles calculations of electrochemical processes require accurate prediction of the interfacial capacitance, a challenge for current computationally-efficient continuum solvation methodologies. We develop a model for the…

Chemical Physics · Physics 2018-04-12 Ravishankar Sundararaman , Kendra Letchworth-Weaver , Kathleen Schwarz
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