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The ability to minimize the thermal conductivity of dielectrics with minimal structural intervention that could affect electrical properties is an important capability for engineering thermoelectric efficiency in low-cost materials such as…

Boundary scattering in hierarchically disordered nanomaterials is an effective way to reduce the thermal conductivity of thermoelectric materials and increase their performance. In this work we investigate thermal transport in silicon based…

Materials Science · Physics 2019-02-27 Dhritiman Chakraborty , Laura de Sousa Oliveira , Neophytos Neophytou

In a typical semiconductor material, the majority of heat is carried by long wavelength, long mean-free-path phonons. Nanostructuring strategies to reduce thermal conductivity, a promising direction in the field of thermoelectrics, place…

Mesoscale and Nanoscale Physics · Physics 2024-05-08 Alex Greaney , S. Aria Hosseini , Laura de Sousa Oliveira , Alathea Davies , Neophytos Neophytou

Boundary-engineering in nanostructures has the potential to dramatically impact the development of materials for high-efficiency conversion of thermal energy directly into electricity. In particular, nanostructuring of semiconductors can…

Materials Science · Physics 2016-10-04 Giuseppe Romano , Alexie M. Kolpak

Nanostructured materials exhibit low thermal conductivity because of the additional scattering due to phonon-boundary interactions. As these interactions are highly sensitive to the mean free path (MFP) of a given phonon mode, MFP…

Materials Science · Physics 2016-01-13 Giuseppe Romano , Keivan Esfarjani , David A. Strubbe , David Broido , Alexie M. Kolpak

Tailoring thermal properties with nanostructured materials can be of vital importance for many applications. Generally classical phonon size effects are employed to reduce the thermal conductivity, where strong phonon scattering by…

Applied Physics · Physics 2019-10-14 Yue Xiao , Qiyu Chen , Dengke Ma , Nuo Yang , Qing Hao

Phonon properties of small Si nanowires in [110] direction have been analyzed using density functional perturbation theory. Several samples with varying diameters ranging from 0.38 to 1.5 nm have been calculated. It is found that the…

Materials Science · Physics 2022-07-06 Konstanze R. Hahn , Claudio Melis , Fabio Bernardini , Lorenzo Paulatto , Luciano Colombo

SiC is a robust semiconductor material considered ideal for high-power application due to its material stability and large bulk thermal conductivity defined by the very fast phonons. In this paper, however, we show that both…

Materials Science · Physics 2007-05-23 Eleni Ziambaras , Per Hyldgaard

We study heat current autocorrelation function and thermal conductivity in core-shell nanowires by using molecular dynamics simulations. Interestingly, a remarkable oscillation effect in heat current autocorrelation function is observed in…

Materials Science · Physics 2015-05-30 Jie Chen , Gang Zhang , Baowen Li

While thermal anisotropicity is a desirable materials property for many applications, including transverse thermoelectrics and thermal management in electronic devices, it remains elusive in practical natural compounds. In this work, we…

Materials Science · Physics 2017-04-05 Giuseppe Romano , Alexie M. Kolpak

Introducing hierarchical disorder from multiple defects into materials through nanostructuring is one of the most promising directions to achieve extremely low thermal conductivities and thus improve thermoelectric performance. The success…

Materials Science · Physics 2019-09-16 Laura de Sousa Oliveira , Vassilios Vargiamidis , Neophytos Neophytou

In nanostructures phonon transport behaviour is distinctly different to transport in bulk materials such that materials with ultra low thermal conductivities and enhanced thermoelectric performance can be realized. Low thermal…

Materials Science · Physics 2019-03-01 Dhritiman Chakraborty , Samuel Foster , Neophytos Neophytou

We have shown theoretically that a combination of cross-section modulation and acoustic mismatch in the core-shell Si/Ge nanowires can lead to a drastic reduction of the thermal conductivity. Our calculations, which utilized two different…

Mesoscale and Nanoscale Physics · Physics 2015-06-16 Denis L. Nika , Alexandr I. Cocemasov , Dmitrii V. Crismari , Alexander A. Balandin

Nanoporous materials are of broad interest for various applications, in particular advanced thermoelectric materials. The introduction of nanoscale porosity, even at modest levels, has been known to drastically reduce a materials thermal…

Mesoscale and Nanoscale Physics · Physics 2019-07-31 Laura de Sousa Oliveira , Neophytos Neophytou

Tuning thermal transport in nanostructured materials is a powerful approach to develop high-efficiency thermoelectric materials. Using a recently developed approach based on the phonon mean free path dependent Boltzmann transport equation,…

Mesoscale and Nanoscale Physics · Physics 2015-06-22 Giuseppe Romano , Jeffrey C. Grossman

We perform molecular dynamics simulations to investigate the reduction of the thermal conductivity by kinks in silicon nanowires. The reduction percentage can be as high as 70% at room temperature. The temperature dependence of the…

Materials Science · Physics 2013-08-14 Jin-Wu Jiang , Nuo Yang , Bing-Shen Wang , Timon Rabczuk

Porous materials provide a large surface to volume ratio, thereby providing a knob to alter fundamental properties in unprecedented ways. In thermal transport, porous nanomaterials can reduce thermal conductivity by not only enhancing…

Because of high surface-to-volume ratio, the most prominent size effect limiting thermal transport originates from phonon-surface scattering in nanostructures. Herein we propose the mechanism of phonon scattering by the bond strength…

Mesoscale and Nanoscale Physics · Physics 2019-01-16 Guofeng Xie , Gang Zhang

Prior experimental studies showed that nanowires are promising structures for improving the thermoelectric performance of practical thermoelectric materials due to the strongly induced phonon-boundary scattering. However, few studies…

Mesoscale and Nanoscale Physics · Physics 2017-09-13 Lei Ma , Riguo Mei , Mengmeng Liu , Xuxin Zhao , Qixing Wu , Hongyuan Sun

The mechanisms causing the reduction in lattice thermal conductivity in highly P- and B-doped Si are looked into in detail. Scattering rates of phonons by point defects, as well as by electrons, are calculated from first principles. Lattice…

Materials Science · Physics 2019-10-02 Bonny Dongre , Jesús Carrete , Shihao Wen , Jinlong Ma , Wu Li , Natalio Mingo , Georg K. H. Madsen
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