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Polaritonic states arise when a bright optical transition of a molecular ensemble is resonantly matched to an optical cavity mode frequency. Here, we lay the groundwork to study the behavior of polaritons in clean, isolated systems by…

Chemical Physics · Physics 2023-10-20 Adam D. Wright , Jane C. Nelson , Marissa L. Weichman

Placing an atom and a molecule in a cavity opens the door to initialize molecular dynamics by exciting a level of the atom. This approach enlarges the range of choosing the light source to trigger molecular dynamics substantially. The…

Quantum Physics · Physics 2024-09-10 András Csehi , Ágnes Vibók , Lorenz S. Cederbaum , Gábor J. Halász

In the regime of ensemble vibrational strong coupling (VSC), a macroscopic number $N$ of molecular transitions couple to each resonant cavity mode, yielding two hybrid light-matter (polariton) modes, and a reservoir of $N-1$ dark states…

Chemical Physics · Physics 2020-04-03 Jorge Campos-Gonzalez-Angulo , Raphael F. Ribeiro , Joel Yuen-Zhou

In this article, we show that the collective light-matter strong coupling regime, where $N$ molecular emitters couple to the photon mode of an optical cavity, can be mapped to a quantum impurity model where the photon is the impurity that…

Quantum Physics · Physics 2023-10-25 Joel Yuen-Zhou , Arghadip Koner

Gas-phase molecules are a promising platform through which to elucidate the mechanisms of action and scope of polaritons for optical control of chemistry. Polaritons arise from the strong coupling of a dipole-allowed molecular transition…

Chemical Physics · Physics 2024-08-20 Jane C. Nelson , Marissa L. Weichman

We study a system of interacting matter quasiparticles strongly coupled to photons inside an optomechanical cavity. The resulting normal modes of the system are represented by hybrid polaritonic quasiparticles, which acquire effective…

Quantum Gases · Physics 2017-02-27 N. Bobrovska , M. Matuszewski , T. C. H. Liew , O. Kyriienko

Plasmonic nanocavities enable the confinement of molecules and electromagnetic fields within nano-metric volumes. As a consequence, the molecules experience a remarkably strong interaction with the electromagnetic field, to such an extent…

Chemical Physics · Physics 2021-09-01 Jacopo Fregoni , Tor S. Haugland , Silvio Pipolo , Tommaso Giovannini , Henrik Koch , Stefano Corni

We report on time-resolved photoluminescence from semiconductor microcavities showing that an optically controllable mechanism exists to turn on and off memory effects in a polariton system. By increasing the laser pumping pulse intensity…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 F. J. Rodriguez , L. Quiroga , C. Tejedor , M. D. Martin , L. Vina , R. Andre

In this work, we systematically investigate the spectral and transport properties of exciton-polaritons under the explicit influence of intermolecular vibrational coupling, which introduces dynamic disorder. In the context of a…

Chemical Physics · Physics 2025-12-03 Guangming Liu , Hsing-Ta Chen

The emerging field of molecular cavity polaritons has stimulated a surge of experimental and theoretical activities and presents a unique opportunity to develop the many-body simulation methodology. This paper presents a numerical scheme…

Quantum Physics · Physics 2024-03-12 Andrew Wu , Javier Cerrillo , Jianshu Cao

Motivated by the recent advances in optical imaging and tracking of wave-packet propagation in optical cavities, we systematically explore the non-Hermitian polariton dynamics within a decay-tunable multimode cavity model. The complex…

Quantum Physics · Physics 2025-07-29 Md Qutubuddin , Ilia Tutunnikov , Jianshu Cao

The emission dynamics of a GaAs microcavity at different angles of observation with respect to the sample normal under conditions of nonresonant picosecond-pulse excitation is measured. At sufficiently high excitation densities, the decay…

Mesoscale and Nanoscale Physics · Physics 2011-05-11 V. V. Belykh , V. A. Tsvetkov , M. L. Skorikov , N. N. Sibeldin

We investigate the chemical reactivity of molecular populations confined inside a nanofluidic Fabry-P{\'e}rot cavity. Due to strong light-matter interactions developing between a resonant electromagnetic cavity-mode and the electric dipole…

Mesoscale and Nanoscale Physics · Physics 2021-04-21 L Mauro , K Caicedo , G Jonusauskas , Rémi Avriller

We study the resonant electronic excitation dynamics for ultracold atoms trapped in a deep optical lattice prepared in a Mott insulator state. Excitons in these artificial crystals are similar to Frenkel excitons in Noble atom or molecular…

Quantum Physics · Physics 2009-08-11 Hashem Zoubi , Helmut Ritsch

We consider a new approach to the problem of Bose-Einstein condensation (BEC) of polaritons for atom-field interaction under the strong coupling regime in the cavity. We investigate the dynamics of two macroscopically populated polariton…

Quantum Physics · Physics 2007-09-20 A. P. Alodjants , S. M. Arakelian , S. N. Bagayev , V. S. Egorov , A. Yu. Leksin

The effect of phonons on a nonlinear optical response of a quantum dot-cavity system in quantum strong coupling regime can be accounted for by a fully analytical treatment, provided that the exciton-phonon dynamics is much faster than the…

Mesoscale and Nanoscale Physics · Physics 2023-06-30 L. S. Sirkina , E. A. Muljarov

We introduce a theory of chemical equilibrium in optical microcavities, which allows us to relate equilibrium reaction quotients in different electromagnetic environments. Our theory shows that in planar microcavities under strong coupling…

Chemical Physics · Physics 2023-05-02 Kaihong Sun , Raphael F. Ribeiro

Breaking the time-reversal symmetry of light is of great importance for fundamental physics and has attracted increasing interest in the study of non-reciprocal photonic devices. Here, we experimentally demonstrate a chiral cavity QED…

Quantum Physics · Physics 2023-04-20 Pengfei Yang , Ming Li , Xing Han , Hai He , Gang Li , Chang-Ling Zou , Pengfei Zhang , Yuhua Qian , Tiancai Zhang

Organic semiconductors are a promising platform for ambient polaritonics. Several applications, such as polariton routers, and many-body condensed matter phenomena are currently hindered due to the ultra-short polariton lifetimes in…

The recent progress in nanotechnology [1,2] and single-molecule spectroscopy [3-5] paves the way for cost-effective organic quantum optical technologies emergent with a promise to real-life devices operating at ambient conditions. In this…