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Correlated band theory is employed to investigate the magnetic and electronic properties of different arrangements of oxygen di- and tri-vacancy clusters in SrTiO$_3$. Hole and electron doping of oxygen deficient SrTiO$_3$ yields various…

Materials Science · Physics 2016-03-30 Alejandro Lopez-Bezanilla , P. Ganesh , Peter B. Littlewood

It has been recently shown that under pressure trilayer Ruddlesden-Popper nickelate La$_4$Ni$_3$O$_{10}$ (LNO) becomes superconducting below a critical temperature $\sim$20 K, in addition to the infinite-layer and bilayer systems. Motivated…

Strongly Correlated Electrons · Physics 2024-06-12 I. V. Leonov

We elucidate the electronic structure and quantum many-body instabilities of the monolayer nickelate La2NiO4 under hydrostatic pressure using a combination of density functional theory, dynamical mean-field theory (DFT+DMFT), and random…

Strongly Correlated Electrons · Physics 2025-11-20 Shu-Hong Tang , Han-Yu Wang , Da-Yong Liu , Feng Lu , Wei-Hua Wang , H. -Q. Lin , Liang-Jian Zou

To explore how anion substitution modifies the existing magnetism in strongly correlated oxides, we investigate local electronic states and magnetic ordering in nickel oxide (NiO) induced by substituting oxygen (O) with nitrogen (N). Each N…

We investigate the crystal structure and the electronic properties of the trilayer nickelate La$_4$Ni$_3$O$_{10}$ by means of quantum mechanical calculations in the framework of the density functional theory. We find that, at low…

Strongly Correlated Electrons · Physics 2018-03-15 Danilo Puggioni , James M. Rondinelli

The optoelectronic properties induced by oxygen vacancy defects in MgO(111) monolayers have been studied using hybrid level of DFT method. HSE calculations shows significant reduction in electronic band gap of MgO monolayer as a result of…

Materials Science · Physics 2022-04-20 Rituparna Hazarika , Bulumoni Kalita

The interplay among orbital-selective Mott physics, Hund's coupling, tunable structural motifs, and Kondo-like scattering establishes a compelling paradigm for understanding and engineering correlated multi-orbital systems, as vividly…

Two-dimensional (2D) nitride materials such as hexagonal boron nitride (h-BN), graphitic carbon nitride (g-C$_3$N$_4$), and beryllonitrene (BeN$_4$) have emerged as promising candidates for next generation electronic, optoelectronic, and…

Materials Science · Physics 2025-10-16 Shreya G. Sarkar , Kuneh Parag Shah , Brahmananda Chakraborty

We present a diffuse neutron and x-ray scattering study of structural, spin- and charge-density-wave fluctuations in the electrical insulator La$_{2-x}$Sr$_x$NiO$_4$. This lamellar nickelate is an isostructural analogue of the…

Strongly Correlated Electrons · Physics 2025-12-30 R. J. Spieker , B. Krohnke , D. Zhai , A. Lopez Benet , M. Spaić , X. He , C. Y. Tan , Z. W. Anderson , F. Ye , H. Cao , M. J. Krogstad , R. Osborn , D. Pelc , M. Greven

Using the DFT+dynamical mean-field theory approach we study the effects of electronic correlations and doping on the normal state electronic structure of the double-layer nickelate superconductor La$_3$Ni$_2$O$_7$ under pressure. In…

Strongly Correlated Electrons · Physics 2026-04-27 I. V. Leonov

The emergence of magnetism in otherwise nonmagnetic compounds and its underlying mechanisms have become the subject of intense research. Here we demonstrate that the nonmagnetic oxygen vacancies are responsible for an unconventional…

Mesoscale and Nanoscale Physics · Physics 2013-11-15 N. Pavlenko , T. Kopp , J. Mannhart

We report nuclear magnetic resonance data in the bilayer nickelate La3Ni2O6. This material belongs to a family of low valence nickel oxides with square planar coordination of the Ni ions and is isoelectronic to the high temperature…

Strongly Correlated Electrons · Physics 2013-08-16 N. apRoberts-Warren , J. Crocker , A. P. Dioguardi , K. R. Shirer , V. V. Poltavets , M. Greenblatt , P. Klavins , N. J. Curro

We report that in unannealed LaAlO3/SrTiO3 (LAO/STO) heterostructures the critical thickness for the appearance of the two-dimensional electron gas can be less than 4 unit cell (uc), the interface is conducting even for STO substrates with…

Materials Science · Physics 2014-02-04 Z. Q. Liu , L. Sun , Z. Huang , C. J. Li , S. W. Zeng , K. Han , W. M. Lü , T Venkatesan , Ariando

At 750K, LaMnO_3 has a cooperative Jahn-Teller (JT) distortion, with Mn atoms in distorted oxygen octahedra. This lifts the degeneracy of the singly-occupied $e_g$ orbitals of the Mn$^{3+}$ ions, which then become orbitally ordered. We use…

Strongly Correlated Electrons · Physics 2015-06-25 Vasili Perebeinos , Philip B. Allen

Motivated by the absence of cooperative Jahn-Teller effect and of magnetic ordering in LiNiO$_2$, a layered oxide with triangular planes, we study a general spin-orbital model on the triangular lattice. A mean-field approach reveals the…

Strongly Correlated Electrons · Physics 2009-11-10 F. Vernay , K. Penc , P. Fazekas , F. Mila

I study the structural and magnetic instabilities in LaNiO$_3$ using density functional theory calculations. From the non-spin-polarized structural relaxations, I find that several structures with different Glazer tilts lie close in energy.…

Strongly Correlated Electrons · Physics 2018-09-05 Alaska Subedi

XAFS studies of Ni-doped Ba$_{1-x}$Sr$_x$TiO$_3$ solid solution reveal that the Ni oxidation state changes from 4 in SrTiO$_3$ to 2.5 in BaTiO$_3$ when varying $x$. This change is accompanied by a noticeable change in the interatomic Ni-O…

Materials Science · Physics 2016-10-28 A. I. Lebedev , I. A. Sluchinskaya

The magneto-optical properties of titanium dioxide systems are related to the presence of impurity states in the band gap due to oxygen vacancies. To understand about the interplay between localized electrons and structural distortions at…

Materials Science · Physics 2023-05-10 C. Echeverria-Arrondo , H. Raebiger , J. Perez-Conde , C. Gomez-Polo , A. Ayuela

The bilayer nickelate La$_3$Ni$_2$O$_7$ (LNO) exhibits a remarkably high-temperature superconductivity of approximately 80 K under pressure, sparking considerable attentions. However, the nature of the spin, charge, and orbital order in LNO…

Superconductivity · Physics 2024-07-29 Binhua Zhang , Changsong Xu , Hongjun Xiang

Exploration of novel resistive switching materials attracts attention to replace conventional Si-based transistors and to achieve neuromorphic computing that can surpass the limit of the current Von-Neumann computing for the time of…

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