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We present a general, systematic, and efficient method for decomposing any given exponential operator of bosonic mode operators, describing an arbitrary multi-mode Hamiltonian evolution, into a set of universal unitary gates. Although our…

Quantum Physics · Physics 2011-10-19 Seckin Sefi , Peter van Loock

The variational quantum eigensolver (VQE) is a hybrid quantum-classical algorithm used to find the ground state of a Hamiltonian using variational methods. In the context of this Lattice symposium, the procedure can be used to study lattice…

Quantum Physics · Physics 2021-12-02 Giovanni Iannelli , Karl Jansen

Quantum-enhanced computing methods are promising candidates to solve currently intractable problems. We consider here a variational quantum eigensolver (VQE), that delegates costly state preparations and measurements to quantum hardware,…

One of the main challenges in the Variational Quantum Eigensolver (VQE) framework is construction of the unitary transformation. The dimensionality of the space for unitary rotations of $N$ qubits is $4^N-1$, which makes the choice of a…

Quantum Physics · Physics 2021-12-21 Artur F. Izmaylov , Manuel Díaz-Tinoco , Robert A. Lang

We present a diagonalization method for generic matrix valued Hamiltonians based on a formal expansion in power of $\hbar $. Considering $\hbar $ as a running parameter, a differential equation connecting two diagonalization processes for…

Mesoscale and Nanoscale Physics · Physics 2008-11-26 Pierre Gosselin , Jocelyn Hanssen , Herve Mohrbach

We present a hybrid classical/quantum algorithm for efficiently solving the eigenvalue problem of many-particle Hamiltonians on quantum computers with limited resources by splitting the workload between classical and quantum processors.…

Quantum Physics · Physics 2022-03-01 John P. T. Stenger , Daniel Gunlycke , C. Stephen Hellberg

Electronic structure simulation is an anticipated application for quantum computers. Due to high-dimensional quantum entanglement in strongly correlated systems, the quantum resources required to perform such simulations are far beyond the…

Quantum Physics · Physics 2022-01-25 Jie Liu , Zhenyu Li , Jinlong Yang

We present a new method for state preparation using the Unitary Vibrational Coupled-Cluster (UVCC) technique. Our approach utilizes redundancies in the Hilbert space in the direct mapping of vibrational modes into qubits. By eliminating…

Quantum Physics · Physics 2024-12-06 Michal Szczepanik , Emil Zak

Variational quantum eigensolvers (VQEs) are among the most promising quantum algorithms for solving electronic structure problems in quantum chemistry, particularly during the Noisy Intermediate-Scale Quantum (NISQ) era. In this study, we…

Quantum Physics · Physics 2026-05-07 Abel Carreras , David Casanova , Román Orús

When does a variational quantum algorithm converge to a globally optimal solution? Despite the large literature around variational approaches to quantum computing, the answer is largely unknown. We address this open question by developing a…

Simulating molecules using the Variational Quantum Eigensolver method is one of the promising applications for NISQ-era quantum computers. Designing an efficient ansatz to represent the electronic wave function is crucial in such…

Chemical Physics · Physics 2022-05-09 Dmitry A. Fedorov , Yuri Alexeev , Stephen K. Gray , Matthew Otten

Quantum computing is entering a transformative phase with the emergence of logical quantum processors, which hold the potential to tackle complex problems beyond classical capabilities. While significant progress has been made, applying…

Quantum Physics · Physics 2025-01-29 Shunya Minami , Kouhei Nakaji , Yohichi Suzuki , Alán Aspuru-Guzik , Tadashi Kadowaki

We propose a computational protocol for quantum simulations of Fermionic Hamiltonians on a quantum computer, enabling calculations which were previously not feasible with conventional encoding and ansatses of variational quantum…

Quantum Physics · Physics 2023-03-15 Benchen Huang , Nan Sheng , Marco Govoni , Giulia Galli

Variational quantum eigensolvers (VQEs) are a promising class of quantum algorithms for preparing approximate ground states in near-term quantum devices. Minimizing the error in such an approximation requires designing ansatzes using…

Quantum Physics · Physics 2021-12-06 Y. Herasymenko , T. E. O'Brien

In this paper, we have developed a unitary variant of a double exponential coupled cluster theory, which is capable of mimicking the effects of connected excitations of arbitrarily high rank, using only rank-one and rank-two parametrization…

Chemical Physics · Physics 2022-11-23 Dipanjali Halder , V. S. Prasannaa , Rahul Maitra

Quantum computational chemistry has emerged as an important application of quantum computing. Hybrid quantum-classical computing methods, such as variational quantum eigensolvers (VQE), have been designed as promising solutions to quantum…

We developed a general framework for hybrid quantum-classical computing of molecular and periodic embedding approaches based on an orbital space separation of the fragment and environment degrees of freedom. We demonstrate its potential by…

Chemical Physics · Physics 2024-12-23 Stefano Battaglia , Max Rossmannek , Vladimir V. Rybkin , Ivano Tavernelli , Jürg Hutter

Quantum computing brings a promise of new approaches into computational quantum chemistry. While universal, fault-tolerant quantum computers are still not available, we want to utilize today's noisy quantum processors. One of their flagship…

Designing compact and accurate circuits for the variational quantum eigensolver (VQE) is a central challenge in near-term quantum chemistry. Existing adaptive methods such as ADAPT-VQE design circuits by iteratively selecting operators from…

Quantum Physics · Physics 2026-05-28 Jianpeng Chen , Zirui Sheng , Cunxi Gong , Weitang Li

Variational quantum algorithms are of special importance in the research on quantum computing applications because of their applicability to current Noisy Intermediate-Scale Quantum (NISQ) devices. The main building blocks of these…

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