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Understanding the coupling between lattice vibrations and magnetic order is crucial for controlling properties of two-dimensional magnetic materials. Here, we investigate the vibrational properties of bulk and thick-flake CrCl$_\textrm{3}$…

The quadruple Calcium manganite (CaMn7O12) is a multiferroic material that exhibits a giant magnetically-induced ferroelectric polarization which makes it very interesting for magnetoelectric applications. Here, we report the Raman…

Strongly Correlated Electrons · Physics 2019-01-16 C. Toulouse , C. Martin , M-A. Measson , Y. Gallais , A. Sacuto , M. Cazayous

Layered antiferromagnetic materials have emerged as a novel subset of the two-dimensional family providing a highly accessible regime with prospects for layer-number-dependent magnetism. Furthermore, transition metal phosphorous…

Materials Science · Physics 2024-01-09 Daniel J. Gillard , Daniel Wolverson , Oscar M. Hutchings , Alexander I. Tartakovskii

Magneto-Raman spectroscopy is applied to study spin-phonon coupling in the layered two-dimensional (2D) van der Waals antiferromagnet CrSBr. We report on the effects of temperature and external magnetic field on Raman-active phonons of…

Materials Science · Physics 2025-03-20 Urszula D. Wdowik , Vaibhav Varade , Jana Vejpravova , Dominik Legut

We report detailed Raman spectroscopic and magnetic susceptibility studies on the spin-driven ferroelectric compounds Mn4Nb2O9 (MNO) and Mn4Ta2O9 (MTO). Both systems exhibit strong spin-phonon coupling below the short-range magnetic…

Materials Science · Physics 2026-02-09 Rajesh Jana , Alka Garg , Rekha Rao , Thomas Meier

We report inelastic neutron scattering measurements over 7-1251 K in CaMnO3 covering various phase transitions, and over 6-150 K in PrMnO3 covering the magnetic transition. The excitations around 20 meV in CaMnO3 and at 17 meV in PrMnO3 are…

Materials Science · Physics 2016-06-29 S. K. Mishra , M. K. Gupta , R. Mittal , A. I. Kolesnikov , S. L. Chaplot

The spin-phonon coupling in magnetic materials is due to the modulation of the exchange integral by lattice vibrations. BaFe12O19 M-type hexaferrite, which is the most used magnetic material as permanent magnet, transforms into ferromagnet…

Materials Science · Physics 2015-06-22 Flávio M. Silva Júnior , Carlos W. A. Paschoal

Polarized Raman scattering and infrared reflection spectra of hexagonal HoMnO$_3$ single crystals in the temperature range 10-300 K are reported. Group-theoretical analysis is performed and scattering selection rules for the second order…

Strongly Correlated Electrons · Physics 2009-11-10 A. P. Litvinchuk , M. N. Iliev , V. N. Popov , M. M. Gospodinov

We have performed high resolution neutron diffraction and inelastic neutron scattering experiments in the frustrated multiferroic hexagonal compounds RMnO3 (R=Ho, Yb, Sc, Y), which provide evidence of a strong magneto-elastic coupling in…

Strongly Correlated Electrons · Physics 2009-06-01 X. Fabreges , S. Petit , I. Mirebeau , S. Pailhes , L. Pinsard , A. Forget , M. T. Fernandez-Diaz , F. Porcher

The quasi-one-dimensional Ising spin chain system $\alpha$-CoV$_2$O$_6$ is considered to exhibit fascinating magnetic properties at lower temperatures. We comprehensively study magnetic properties and lattice dynamics using a combination of…

The discovery of 2-dimensional (2D) materials, such as CrI3, that retain magnetic ordering at monolayer thickness has resulted in a surge of research in 2D magnetism from both pure and applied perspectives. Here, we report a magneto-Raman…

Resonance Raman scattering, a very effective and sensitive technique for atomically thin semiconducting transition metal dichalcogenide, can be used to observe the phonons from the entire Brillouin zone. In addition to the significance of…

Materials Science · Physics 2023-02-06 Deepu Kumar , Nasaru Khan , Rahul Kumar , Mahesh Kumar , Pradeep Kumar

The vibrational properties of ferrimagnetic $\mathrm{Mn_3Si_{2}Te_6}$ single crystals are investigated using Raman spectroscopy and density functional theory calculations. Eighteen Raman-active modes are identified, fourteen of which are…

Hexagonal RMnO3 is a multiferroic compound with a giant spin-lattice coupling at an antiferromagnetic transition temperature [1]. Despite extensive studies over the past two decades, however, the origin and underlying microscopic mechanism…

Strongly Correlated Electrons · Physics 2017-03-08 Seongil Choi , Hasung Sim , Sunmin Kang , Ki-Young Choi , Je-Geun Park

Raman study on a select few orthochromites, RCrO$_3$ (R = Y, Lu, Gd, Eu and Sm) shows that the phonon behavior at TN in compounds with magnetic R-ion (Gd and Sm) is remarkably different from that of non-magnetic R-ion (Y, Lu and Eu). While…

Materials Science · Physics 2013-06-11 Venkata Srinu Bhadram , B. Rajeswaran , A. Sundaresan , Chandrabhas Narayana

A prominent band centered at around 1000-1300 cm-1 and associated with resonant enhancement of two-phonon Raman scattering is reported in multiferroic BiFeO3 thin films and single crystals. A strong anomaly in this band occurs at the…

One- and multi-phonon excitations of the single crystalline LaCoO3 were studied using Raman spectroscopy in the temperature region of 5 K - 300 K. First-order Raman spectra show a larger number of phonon modes than allowed for the…

Strongly Correlated Electrons · Physics 2022-05-31 V. Gnezdilov , K. -Y. Choi , Yu. Pashkevich , P. Lemmens , S. Shiryaev , G. Bychkov , S. Barilo , V. Fomin , A. V. Yeremenko

We have performed Raman scattering investigations on the high energy magnetic excitations in a BiFeO$_3$ single crystal as a function of both temperature and laser excitation energy. A strong feature observed at 1250 cm$^{-1}$ in the Raman…

Strongly Correlated Electrons · Physics 2018-11-13 M. Cazayous , A. Sacuto , D. Lebeugle , D. Colson

The present work reports the preparation of polycrystalline multiferroic $GdFeO_3$ (GdFO) and characterization with x-ray diffraction (XRD), magnetization, temperature dependent Raman spectroscopy, temperature and magnetic field dependent…

Materials Science · Physics 2021-12-06 Anjali Panchwanee , V. Raghavendra Reddy , Ajay Gupta , V. G. Sathe

We have investigated the temperature-dependent Raman-active phonons and the magnetic properties of Gd(Co1/2Mn1/2)O3 perovskite ceramics in the temperature range from 40 K to 300 K. The samples crystallized in an orthorhombic distorted…

Materials Science · Physics 2015-06-17 R. X. Silva , H. Reichlova , X. Marti , D. A. B. Barbosa , M. W. Lufaso , A. P. Ayala , C. W. A. Paschoal