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In this study Mo-Nb-Ta-W refractory high-entropy alloys (R-HEAs) have been studied for their phase stability for a wide temperature range (100 K to 2000 K). The equilibrium thermodynamic phases are determined by the changes in enthalpy and…

Materials Science · Physics 2021-03-16 Varnita Bajpai , Soumyadipta Maiti , Shashank Mishra , Beena Rai

Recently, high-entropy alloys (HEAs) have attracted wide attention due to their extraordinary materials properties. A main challenge in identifying new HEAs is the lack of efficient approaches for exploring their huge compositional space.…

Materials Science · Physics 2019-05-07 Tatiana Kostiuchenko , Fritz Körmann , Jörg Neugebauer , Alexander Shapeev

In this paper we show that an effective Hamiltonian fit with first principles calculations predicts an order/disorder transition occurs in the high entropy alloy MoNbTaW. Using the Alloy Theoretic Automated Toolset, we find T=0K enthalpies…

Materials Science · Physics 2014-02-10 William Paul Huhn , Michael Widom

The high entropy alloy containing refractory metals Mo-Nb-Ta-W has a body centered cubic structure, which is not surprising given the complete mutual solubility in BCC solid solutions of all pairs of the constituent elements. However, first…

Materials Science · Physics 2014-02-10 Michael Widom , William Paul Huhn , Soumyadipta Maiti , Walter Steurer

High entropy alloys (HEAs) are the new class of materials with an attractive combination of tunable mechanical and physicochemical properties. They crystallize mainly in cubic structures, however, for practical applications, HEAs with…

High entropy alloys (HEAs) have been increasingly attractive as promising next-generation materials due to their various excellent properties. It's necessary to essentially characterize the degree of chemical ordering and identify…

Materials Science · Physics 2019-08-13 Jiaxin Zhang , Xianglin Liu , Sirui Bi , Junqi Yin , Guannan Zhang , Markus Eisenbach

High entropy alloys (HEA) show promise as a new type of high-performance structural material. Their vast degrees of freedom provide for extensive opportunities to design alloys with tailored properties. However, the compositional…

Disordered Systems and Neural Networks · Physics 2019-04-19 Qi Jie , Andrew Cheung , S. Joseph Poon

High entropy alloys (HEAs) are promising magnetocaloric materials with tunable operating temperature conditions using compositional modifications. Here, we combine experiments and first principles based spin modelling to engineer…

High entropy alloys (HEA) represent a class of materials with promising properties, such as high strength and ductility, radiation damage tolerance, etc. At the same time, a combinatorially large variety of compositions and a complex…

Materials Science · Physics 2025-10-03 Franco Moitzi , Lorenz Romaner , Andrei V. Ruban , Oleg E. Peil

We use high-throughput first-principles sampling to investigate competitive factors that determine the crystal structure of high-entropy alloys (HEAs) and the energetics dependence of the stable phase on the atomic configuration of fully…

Materials Science · Physics 2022-01-03 Hiroshi Mizuseki , Ryoji Sahara , Kenta Hongo

High-entropy alloys (HEAs) are a new class of materials constructed from multiple principal elements statistically arranged on simple crystallographic lattices. Due to the large amount of disorder present, they are excellent model systems…

Superconductivity · Physics 2018-03-28 Fabian O. von Rohr , Robert J. Cava

High Entropy Alloys (HEAs) contain near equimolar amounts of five or more elements and are a compelling space for materials design. Great emphasis is placed on identifying HEAs that form a homogeneous solid-solution, but the design of such…

Materials Science · Physics 2021-04-20 Daniel Evans , Jiadong Chen , Geoffroy Hautier , Wenhao Sun

High-entropy alloys (HEA) form through the random arrangement of five or more chemical elements on a crystalline lattice. Despite the significant amount of resulting compositional disorder, a subset of HEAs enters a superconducting state…

Superconductivity · Physics 2021-11-23 Casey K. W. Leung , Xiaofu Zhang , Fabian von Rohr , Rolf Lortz , Berthold Jäck

The technological performances of metallic compounds are largely influenced by atomic ordering. Although there is a general consensus that successful theories of metallic systems should account for the quantum nature of the electronic glue,…

Materials Science · Physics 2015-05-13 Ezio Bruno , Francesco Mammano , Beniamino Ginatempo

Predicting the melting temperature (Tm) of multi-component and high-entropy alloys (HEAs) is critical for high-temperature applications but computationally expensive using traditional CALPHAD or DFT methods. In this work, we develop a…

Materials Science · Physics 2026-01-08 Mohd Hasnain

High-entropy alloys (HEAs) have attracted extensive interest due to their exceptional mechanical properties and the vast compositional space for new HEAs. However, understanding their novel physical mechanisms and then using these…

Materials Science · Physics 2022-09-08 Xianglin Liu , Jiaxin Zhang , Zongrui Pei

The development of machine learning sheds new light on the traditionally complicated problem of thermodynamics in multicomponent alloys. Successful application of such a method, however, strongly depends on the quality of the data and…

Materials Science · Physics 2019-06-10 Xianglin Liu , Jiaxin Zhang , Markus Eisenbach , Yang Wang

Monte Carlo methods are used to study the phase transition in ammonium chloride from the orientationally ordered $\delta$ phase to the orientationally disordered $\gamma$ phase. An effective pair potential is used to model the interaction…

chem-ph · Physics 2008-02-03 Robert Q. Topper , David L. Freeman

The AlCrTiV high entropy alloy undergoes an order-disorder transition from body centered cubic (Strukturbericht A2) at high temperatures to the CsCl structure (B2) at intermediate temperatures. We model this transition using first…

Materials Science · Physics 2024-07-02 Michael Widom

Tailoring the performance of next-generation high entropy materials requires a deep understanding of the competition between entropy-driven random solid solution and enthalpy-driven chemical ordering. Investigating such order and disorder…

Materials Science · Physics 2026-03-24 Fanli Zhou , Hao Chen , Pengxiang Xu , Kai Yang , Zongrui Pei , Xianglin Liu
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