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This paper aims to study the convergence of adaptive finite element method for control constrained elliptic optimal control problems under $L^2$-norm. We prove the contraction property and quasi-optimal complexity for the $L^2$-norm errors…

Numerical Analysis · Mathematics 2016-11-16 Wei Gong , Ningning Yan , Zhaojie Zhou

The recent advances in machine learning, in general, and Artificial Neural Networks (ANN), in particular, has made smart embedded systems an attractive option for a larger number of application areas. However, the high computational…

Hardware Architecture · Computer Science 2023-09-06 Suresh Nambi , Salim Ullah , Aditya Lohana , Siva Satyendra Sahoo , Farhad Merchant , Akash Kumar

Most torsional barriers are predicted to high accuracy (about 1kJ/mol) by standard semilocal functionals, but a small subset has been found to have much larger errors. We create a database of almost 300 carbon-carbon torsional barriers,…

Chemical Physics · Physics 2021-02-16 Seungsoo Nam , Eunbyol Cho , Kieron Burke , Eunji Sim

We present a novel $n$EPT ($n$th-order Eulerian Perturbation Theory) scheme to model the nonlinear density field by the summation up to $n$th-order density fields in perturbation theory. The obtained analytical power spectrum shows…

Cosmology and Nongalactic Astrophysics · Physics 2023-06-13 Zhenyuan Wang , Donghui Jeong , Atsushi Taruya , Takahiro Nishimichi , Ken Osato

Electronic structures are fully determined by the exchange-correlation (XC) potential. In this work, we develop a new method to construct reliable XC potentials by properly mixing the exact exchange and the local density approximation…

Chemical Physics · Physics 2024-08-06 Chen Huang

We present an approach based on density-functional theory for the calculation of fundamental gaps of both finite and periodic two-dimensional (2D) electronic systems. The computational cost of our approach is comparable to that of total…

Materials Science · Physics 2021-08-11 Alberto Guandalini , Alice Ruini , Esa Räsänen , Carlo Andrea Rozzi , Stefano Pittalis

In this work, we developed and showcased the occ-RI-K algorithm to compute the exact exchange contribution in density functional calculations of solids near the basis set limit. Within the gaussian planewave (GPW) density fitting, our…

Chemical Physics · Physics 2022-11-09 Joonho Lee , Adam Rettig , Xintian Feng , Evgeny Epifanovsky , Martin Head-Gordon

The effective field theory (EFT) framework is a precise approximation procedure when the inherent assumptions of a large-scale separation between the Standard Model (SM) and new interactions alongside perturbativity are realised.…

High Energy Physics - Phenomenology · Physics 2024-03-22 Upalaparna Banerjee , Joydeep Chakrabortty , Christoph Englert , Wrishik Naskar , Shakeel Ur Rahaman , Michael Spannowsky

We develop an Effective Field Theory (EFT) formalism to solve for the conservative dynamics of binary systems in gravity via Post-Minkowskian (PM) scattering data. Our framework combines a systematic EFT approach to compute the deflection…

High Energy Physics - Theory · Physics 2020-12-30 Gregor Kälin , Rafael A. Porto

Chemical accuracy serves as an important metric for assessing the effectiveness of the numerical method in Kohn--Sham density functional theory. It is found that to achieve chemical accuracy, not only the Kohn--Sham wavefunctions but also…

Computational Physics · Physics 2023-10-25 Yang Kuang , Yedan Shen , Guanghui Hu

Molecule-optimized basis sets, based on approximate natural orbitals, are developed for accelerating the convergence of quantum calculations with strongly correlated (multi-referenced) electrons. We use a low-cost approximate solution of…

Chemical Physics · Physics 2014-02-12 Gergely Gidofalvi , David A. Mazziotti

Effective Field Theory (EFT) extensions of the Standard Model are tools to compute observables $\big(e.g.$ cross sections with partonic center-of-mass energy $\sqrt{\hat{s}}\,\big)$ as a systematically improvable expansion suppressed by a…

High Energy Physics - Phenomenology · Physics 2022-06-07 Timothy Cohen , Joel Doss , Xiaochuan Lu

The reported new algorithm determines the exact exchange potential v_x in a iterative way using energy and orbital shifts (ES, OS) obtained - with finite-difference formulas - from the solutions (occupied orbitals and their energies) of the…

Atomic Physics · Physics 2015-05-20 M. Cinal , A. Holas

We develop a framework to compute the redshift space power spectrum (PS), with kernels beyond Einstein-de Sitter (EdS), that can be applied to a wide variety of generalized cosmologies. We build upon a formalism that was recently employed…

Cosmology and Nongalactic Astrophysics · Physics 2021-04-16 Alejandro Aviles , Georgios Valogiannis , Mario A. Rodriguez-Meza , Jorge L. Cervantes-Cota , Baojiu Li , Rachel Bean

We propose a way to improve energy density functionals (EDFs) in the density functional theory based on the combination of the inverse Kohn--Sham method and the density functional perturbation theory. Difference between the known EDF and…

Chemical Physics · Physics 2019-11-22 Tomoya Naito , Daisuke Ohashi , Haozhao Liang

We present model-assisted density fitting (MADF) basis set generator, an algorithm for generating primitive atomic Gaussian density fitting (DF) basis sets (DFBSs) from a contracted Gaussian orbital basis set (OBS). The MADF algorithm…

Chemical Physics · Physics 2025-10-14 Kshitijkumar A. Surjuse , Edward F. Valeev

This paper presents an approach for obtaining accurate interaction energies at the DFT level for systems where dispersion interactions are important. This approach combines Becke and Johnson's [J. Chem. Phys. 127, 154108 (2007)] method for…

Density functional theory is the workhorse of modern electronic structure calculations, with wide-ranging applications in chemistry, physics, materials science, and machine learning. At its heart lies the exchange-correlation functional, a…

Chemical Physics · Physics 2026-02-20 Fabien Tran , Susi Lehtola , Stefano Pittalis , Miguel A. L. Marques

We derive an exact representation of the exchange-correlation energy within density functional theory (DFT) which spawns a class of approximations leading to correct long-range asymptotic behavior. In what amounts to be the simplest…

Materials Science · Physics 2009-11-10 Roi Baer , Daniel Neuhauser

The spin density wave (SDW) state of the uniform electron gas is investigated in the exact exchange approximation of noncollinear spin density functional theory (DFT). Unlike in Hartree-Fock theory, where the uniform paramagnetic state of…

Materials Science · Physics 2009-09-29 S. Kurth , F. G. Eich