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Molecular chirality, a form of stereochemistry most often describing relative spatial arrangements of bonded neighbors around tetrahedral carbon centers, influences the set of 3D conformers accessible to the molecule without changing its 2D…

Machine Learning · Computer Science 2021-10-12 Keir Adams , Lagnajit Pattanaik , Connor W. Coley

Characterizing chirality is highly important for applications in the pharmaceutical industry, as well as in the study of dynamical chemical and biological systems. However, this task has remained challenging, especially due to the ongoing…

Chemical Physics · Physics 2022-01-28 Ofer Neufeld , Omri Wengrowicz , Or Peleg , Angel Rubio , Oren Cohen

Chirality plays a crucial role in a broad range of processes including light-matter interactions in physics, chemistry and biology, which opens up new applications in nanophotonics, quantum technologies and photochemistry. Quantum…

Optics · Physics 2026-04-10 Yuanyang Xie , Alexey V. Krasavin , Anatoly V. Zayats

Spectroscopic techniques that are sensitive to molecular chirality are important analytical tools to quantitatively determine enantiomeric excess and purity of chiral molecular samples. Many chiroptical processes however produce weak…

Chemical Physics · Physics 2026-04-02 Sebastian Hartweg , Dusan k. Bozanic , Gustavo A. Garcia-Macias , Laurent Nahon

Chiral crystals show promise for spintronic technologies on account of their high spin selectivity, which has led to significant recent interest in quantitative characterization and first-principles prediction of their spin-optoelectronics…

Materials Science · Physics 2023-12-05 Christian Multunas , Andrew Grieder , Junqing Xu , Yuan Ping , Ravishankar Sundararaman

Circular dichroism in the angular distribution (CDAD) is the effect that the angular intensity distribution of photoemitted electrons depends on the handedness of the incident circularly polarized light. A CDAD may arise from intrinsic…

It has been long recognized that the spatial polarization of the electronic clouds in molecules, and the spatial arrangements of atoms into chiral molecular structures, play crucial roles in physics, chemistry and biology. However, these…

Optics · Physics 2020-04-14 David Ayuso , Andres Ordonez , Piero Decleva , Misha Ivanov , Olga Smirnova

We present a combined classical and quantum electrodynamics description of the coupling between two circularly-polarized quantum emitters held above a metal surface supporting surface plasmons. Depending on their position and their natural…

Mesoscale and Nanoscale Physics · Physics 2019-02-11 C. A. Downing , J. C. López Carreño , F. P. Laussy , E. del Valle , A. I. Fernández-Domínguez

Here, we reported, for the first time, a chiral metasurface with multifunctional capabilities tailored for the near-infrared (NIR) wavelength range, garnering tremendous interest in applications such as optical communication and chiral…

Optics · Physics 2025-06-12 Md. Ehsanul Karim , Ahmed Zubair

We report the one-electron spectrum and eigenstates of infinite achiral and chiral $(2m,m)$ carbon nanotubes found by using the analytic solution to the Schr\"odinger equation for the tight-binding H\"uckel-type Hamiltonian. With the help…

Mesoscale and Nanoscale Physics · Physics 2022-11-23 L. Malysheva

Chiral emission, where the handedness of a transition dipole determines the direction in which a photon is emitted, has recently been observed from atoms and quantum dots coupled to nanophotonic waveguides. Here, we consider the case of…

Optics · Physics 2018-06-06 Diego Martín-Cano , Harald R. Haakh , Nir Rotenberg

Fabrication of chiral assemblies of plasmonic nanoparticles is a highly attractive and challenging task with promising applications in light emission, detection, and sensing. So far, primarily organic chiral templates have been used for…

Dark-field illumination is shown to make planar chiral nanoparticle arrangements exhibit circular dichroism in extinction analogous to true chiral scatterers. Circular dichrosim is experimentally observed at the maximum scattering of single…

A new scheme for enantiomer differentiation of chiral molecules using a pair of linearly polarized intense ultrashort laser pulses with skewed mutual polarization is presented. The technique relies on the fact that the off-diagonal…

Chemical Physics · Physics 2017-05-04 Andrey Yachmenev , Sergei N. Yurchenko

Optical chirality plays an essential role in chiral light-matter interactions with broad applications in sensing and spectroscopy. Conventional methods of generating optical chirality usually employ chiral structures or chiral excitations.…

Optics · Physics 2023-06-21 Shiqi Jia , Tong Fu , Jie Peng , Shubo Wang

Intimately connected to the rule of life, chirality remains a long-time fascination in biology, chemistry, physics and materials science. Chiral structures, e.g., nucleic acid and cholesteric phase developed from chiral molecules are common…

The article seeks to formulate a synergetic law that is posited to be of common physicochemical and biological nature: an evolving system, possessing free energy and elements with chiral asymmetry may change the type of symmetry inside one…

Adaptation and Self-Organizing Systems · Physics 2012-12-10 Vsevolod A. Tverdislov

Chiral materials display a property called optical activity, which is the capability to interact differentially with left and right circularly polarised light. This leads to the ability to manipulate the polarisation state of light, which…

Fine control of the chiral light-matter interaction at the nanoscale, by exploiting designed metamaterial architecture, represents a cutting-edge craft in the field of biosensing, quantum and classic nanophotonics. Recently, artificially…

Chirality is ubiquitous from microscopic to macroscopic phenomena in physics and biology, such as fermionic interactions and DNA duplication. In photonics, chirality has traditionally represented differentiated optical responses for right…

Optics · Physics 2019-09-02 Sunkyu Yu , Xianji Piao , Namkyoo Park
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