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The chiral state of a molecule plays a crucial role in molecular recognition and biochemical reactions. Because of this and owing to the fact that most modern drugs are chiral, the sensitive and reliable detection of the chirality of…

Mesoscale and Nanoscale Physics · Physics 2019-04-30 Luisa M. Kneer , Eva-Maria Roller , Lucas V. Besteiro , Robert Schreiber , Alexander O. Govorov , Tim Liedl

Chirality is a fundamental feature in all domains of nature, ranging from particle physics over electromagnetism to chemistry and biology. Chiral objects lack a mirror plane and inversion symmetry and therefore cannot be spatially aligned…

The interaction between intense light-matter not only promotes emerging applications in quantum and nonlinear optics but also facilitates changes in material properties. Plasmons can significantly enhance not only molecular chirality but…

Optics · Physics 2025-02-03 Nan Gao , Haoran Liu , Yurui Fang

We present a rigorous finite element method to calculate circular dichroism (CD) in various systems consisting of nanostructures and oriented chiral molecules with electric quadrupole transitions. The interaction between oriented molecule…

Optics · Physics 2017-12-27 Weixuan Zhang , Tong Wu , Rongyao Wang , Xiangdong Zhang

The theory to calculate circular dichroism (CD) of chiral molecules in a finite cluster with arbitrarily disposed objects has been developed by means of T-matrix method. The interactions between chiral molecules and nanostructures have been…

Optics · Physics 2018-01-01 Tong Wu , Jun Ren , Rongyao Wang , Xiangdong Zhang

The ability to differentiate chiral molecules of different handedness is of great importance for chemical and life sciences. Since most of the relevant chiral molecules have their chiral transitions in the UV region, detecting their…

In plasmonic chirality, the phenomenon of circular dichroism for achiral nanoparitcles caused by Coulomb interaction between metal nanoparticles (NPs) and chiral molecules have been studied. At the same time, under the resonance condition,…

Mesoscale and Nanoscale Physics · Physics 2020-09-04 Yangzhe Guo , Guodong Zhu , Yurui Fang

We present a comprehensive overview of chirality and its optical manifestation in plasmonic nanosystems and nanostructures. We discuss top-down fabricated structures that range from solid metallic nanostructures to groupings of metallic…

Molecular chirality plays fundamental roles in biology. The chiral response of a molecule occurs at a specific spectral position, determined by its molecular structure. This fingerprint can be transferred to other spectral regions via the…

The plasmonic chirality has drawn a lot of attention because of the tunable circular dichroism (CD) and the enhancement for the signal of chiral molecules. Different mechanisms have been proposed for explaining the plasmonic CD, however, a…

Mesoscale and Nanoscale Physics · Physics 2016-03-23 Li Hu , Xiaorui Tian , Yingzhou Huang , Xinqiang Wang , Yurui Fang

Molecular chirality is a geometric property that is of great importance in chemistry, biology, and medicine. Recently, plasmonic nanostructures that exhibit distinct chiroptical responses have attracted tremendous interest, given their…

Optics · Physics 2021-05-17 Frank Neubrech , Mario Hentschel , Na Liu

Circular dichroism (CD), induced by chirality, is an important tool for manipulating light or for characterizing morphology of molecules, proteins, crystals and nano-structures. CD is manifested over a wide size-range, from molecules to…

The near-field interaction of plasmonic nanostructures and chiral molecules induces circular dichroism in achiral nanostructure. The induced circular dichroism (ICD) strength is several orders greater than the molecular inherent CD (MCD),…

We report on giant circular dichroism (CD) of a molecule inserted into a plasmonic hot spot. Naturally occurring molecules and biomolecules have typically CD signals in the UV range, whereas plasmonic nanocrystals exhibit strong plasmon…

Mesoscale and Nanoscale Physics · Physics 2015-06-05 Hui Zhang , A. O. Govorov

Plasmonic nanocrystals with hot spots are able to localize optical energy in small spaces. In such physical systems, near-field interactions between molecules and plasmons can become especially strong. This paper considers the case of a…

Mesoscale and Nanoscale Physics · Physics 2017-04-19 Lucas V. Besteiro , Hui Zhang , Jérôme Plain , Gil Markovich , Zhiming Wang , Alexander O. Govorov

In the close vicinity of a chiral nanostructure, the circular dichroism of a biomolecule could be greatly enhanced, due to the interaction with the local superchiral fields. Modest enhancement of optical activity using a planar…

When circularly polarized light interacts with a nanostructure, the optical response depends on the geometry of the structure. If the nanostructure is chiral (i.e., it cannot be superimposed on its mirror image), then its optical response,…

The circular dichroism (ICD) induced from interaction of chiral molecules with achiral plasmonic metal nanostructures has improved sensitivity of molecular chirality detection. Although experimental results have presented several orders…

Chiral nanophotonic devices are promising candidates for chiral molecules sensing, polarization diverse nanophotonics and display technologies. Active chiral nanophotonic devices, where the optical chirality can be controlled by an external…

We introduce and theoretically analyze the concept of manipulating optical chirality via strong coupling of the optical modes of chiral nanostructures with excitonic transitions in molecular layers or semiconductors. With chirality being…

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