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We demonstrate and characterize a first-principles approach to modeling the mass action dynamics of metabolism. Starting from a basic definition of entropy expressed as a multinomial probability density using Boltzmann probabilities with…

Chemical Physics · Physics 2024-07-10 William R. Cannon , Samuel Britton , Mikahl Banwarth-Kuhn , Mark Alber

In a particle physics dynamics, we assume a uniform distribution as the physical measure and a measure-theoretic definition of entropy on the velocity configuration space. This distribution is labeled as the physical solution in the…

Mathematical Physics · Physics 2022-11-29 James Glimm , Daniel Lazarev , Gui-Qiang Chen

We show that the naive application of the maximum entropy principle can yield answers which depend on the level of description, i.e. the result is not invariant under coarse-graining. We demonstrate that the correct approach, even for…

Statistical Mechanics · Physics 2007-05-23 Jayanth Banavar , Amos Maritan

Far-from-equilibrium thermodynamics underpins the emergence of life, but how has been a long-outstanding puzzle. Best candidate theories based on the maximum entropy production principle could not be unequivocally proven, in part due to…

Quantitative Methods · Quantitative Biology 2017-10-10 Robert G. Endres

We consider thermodynamic systems with finitely many degrees of freedom and subject to an external control action. We derive some basic results on the dependence of the relative entropy production rate on the controlling force. Applications…

Mathematical Physics · Physics 2007-05-23 M. Pavon , F. Ticozzi

The maximum entropy approach operating with quite general entropy measure and constraint is considered. It is demonstrated that for a conditional or parametrized probability distribution $f(x|\mu)$ there is a "universal" relation among the…

Statistical Mechanics · Physics 2015-05-19 E. V. Vakarin , J. P. Badiali

Extremal principles can generally be divided into two rather distinct classes. There are, on the one hand side, formulations based on the Lagrangian or Hamiltonian mechanics, respectively, dealing with time dependent problems, but…

Computational Engineering, Finance, and Science · Computer Science 2023-11-08 Klaus Hackl , Jiří Svoboda , Franz Dieter Fischer

The selection of an equilibrium state by maximising the entropy of a system, subject to certain constraints, is often powerfully motivated as an exercise in logical inference, a procedure where conclusions are reached on the basis of…

Statistical Mechanics · Physics 2015-12-03 Ian J. Ford

In addition to the Riemannian metricization of the thermodynamic state space, local relaxation times offer a natural time scale, too. Generalizing existing proposals, we relate {\it thermodynamic} time scale to the standard kinetic…

Condensed Matter · Physics 2008-02-03 L. Diosi , K. Kulacsy , B. Lukacs , A. Rácz

The new method is considered for identifying the perfect (optimal) scenario of climate engineering operations based on the optimal control theory. The application of this approach is demonstrated using zero-dimensional energy-balance…

Atmospheric and Oceanic Physics · Physics 2017-09-19 Sergei Soldatenko , Rafael Yusupov

Identifying the full entropy production of active particles is a challenging task. We introduce a microscopic, thermodynamically consistent model, which leads to active Ornstein-Uhlenbeck statistics in the continuum limit. Our minimal model…

Statistical Mechanics · Physics 2023-12-15 Jonas H. Fritz , Udo Seifert

The Earth, like other planets with a relatively thick atmosphere, is not locally in radiative equilibrium and the transport of energy by the geophysical fluids (atmosphere and ocean) plays a fundamental role in determining its climate.…

Atmospheric and Oceanic Physics · Physics 2015-05-27 Corentin Herbert , Didier Paillard , Masa Kageyama , Berengere Dubrulle

In this work, we propose an Action Principle for Action-dependent Lagrangian functions by generalizing the Herglotz variational problem to the case with several independent variables. We obtain a necessary condition for the extremum…

Mathematical Physics · Physics 2018-03-23 Matheus J. Lazo , Juilson Paiva , João T. S. Amaral , Gastão S. F. Frederico

From the previously obtained solutions of the Fokker - Planck equation for Rayleigh gas (small impurity of heavy particles in a thermostat of light particles) with sources and without them, the entropy production was calculated. In a system…

Statistical Mechanics · Physics 2016-10-11 P. A. Tadjibaev , D. P. Tadjibaev

Living systems maintain or increase local order by working against the Second Law of Thermodynamics. Thermodynamic consistency is restored as they dissipate heat, thereby increasing the net entropy of their environment. Recently introduced…

Biological Physics · Physics 2021-05-03 Dominic J. Skinner , Jörn Dunkel

We propose a formalization for dissipative fluids with interfaces in an inhomogeneous temperature field from the viewpoint of a variational principle. Generally, the Lagrangian of a fluid is given by the kinetic energy density minus the…

Fluid Dynamics · Physics 2015-07-10 Hiroki Fukagawa , Chun Liu , Takeshi Tsuji

The complete physical understanding of the optimization of the thermodynamic work still is an important open problem in stochastic thermodynamics. We address this issue using the Hamiltonian approach of linear response theory in finite time…

Statistical Mechanics · Physics 2022-08-18 Pierre Nazé , Sebastian Deffner , Marcus V. S. Bonança

The minimum entropy production principle provides an approximative variational characterization of close-to-equilibrium stationary states, both for macroscopic systems and for stochastic models. Analyzing the fluctuations of the empirical…

Mathematical Physics · Physics 2009-11-05 C. Maes , K. Netocny

The Markovian evolution of an open quantum system is characterized by a positive entropy production, while the global entropy gets redistributed between the system and the environment degrees of freedom. Starting from these premises, we…

Stochastic thermodynamics allows us to define heat and work for microscopic systems far from thermodynamic equilibrium, based on observations of their stochastic dynamics. However, a complete account of the energetics necessitates that all…

Statistical Mechanics · Physics 2021-08-31 Jannik Ehrich