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Glass formers exhibit a viscoelastic behavior: at the laboratory timescale, they behave like (glassy) solids at low temperatures, and like liquids at high temperatures. Based on this observation, elastic models relate the long time…

Chemical Physics · Physics 2017-08-01 Emmanuel Guillaud , Laurent Joly , Dominique De Ligny , Samy Merabia

In supercooled liquids, dynamical facilitation refers to a phenomenon where microscopic motion begets further motion nearby, resulting in spatially heterogeneous dynamics. This is central to the glassy relaxation dynamics of such liquids,…

Statistical Mechanics · Physics 2023-10-11 Muhammad R. Hasyim , Kranthi K. Mandadapu

Glassy systems are disordered systems characterized by extremely slow dynamics. Examples are supercooled liquids, whose dynamics slow down under cooling. The specific pattern of slowing-down depends on the material considered. This…

Disordered Systems and Neural Networks · Physics 2016-04-12 Le Yan

With molecular dynamics simulations of a fluid mixture of classical particles interacting with pair-wise additive Weeks-Chandler-Andersen potentials, we consider the time series of particle displacements and thereby determine distributions…

Statistical Mechanics · Physics 2011-11-10 Lester O. Hedges , Lutz Maibaum , David Chandler , Juan P. Garrahan

Recent numerical simulations of a disordered system (Preprint arXiv:condmat/0307554) have shown the existence of two different relaxational processes (called stimulated and spontaneous) characterizing the relaxation observed in structural…

Disordered Systems and Neural Networks · Physics 2007-05-23 F. Ritort

We present a study of the relaxation dynamics of the photoexcited conductivity of the impurity states in the low-density electronic glass, phosphorous-doped silicon Si:P. Using optical pump-terahertz probe spectroscopy we find strongly…

Disordered Systems and Neural Networks · Physics 2010-09-16 V. K. Thorsmølle , N. P. Armitage

We study the Stokes-Einstein (SE) and the Stokes-Einstein-Debye (SED) relations using molecular dynamics simulations of the extended simple point charge model of water. We find that both the SE and SED relations break down at low…

Statistical Mechanics · Physics 2007-06-01 Marco G. Mazza , Nicolas Giovambattista , H. Eugene Stanley , Francis W. Starr

We consider the relaxation process and the out-of-equilibrium dynamics of natural generalizations to arbitrary dimensions of the well known one dimensional East process. These facilitated models are supposed to catch some of the main…

Statistical Mechanics · Physics 2015-06-22 Paul Chleboun , Alessandra Faggionato , Fabio Martinelli

Glass-forming liquids have only a modest tendency to crystallize and hence their dynamics can be studied even below the melting temperature. The relaxation dynamics of most of these liquids shows at a temperature $T_c$, somewhat above the…

Soft Condensed Matter · Physics 2025-01-17 Francesco Rusciano , Raffaele Pastore , Francesco Greco , Walter Kob

Governing equations are derived for the kinetics of physical aging in polymeric glasses. An amorphous polymer is treated as an ensemble of cooperatively rearranged regions (CRR). Any CRR is thought of as a string of elementary clusters…

Soft Condensed Matter · Physics 2007-05-23 Aleksey D. Drozdov

The interplay between the structural relaxation and the rheological response of a binary LJ glass former is studied via MD simulations. In the quiescent state, the model is well known for its sluggish dynamics and a two step relaxation of…

Soft Condensed Matter · Physics 2015-05-14 Fathollah Varnik

Atomistic deformation simulations in the nominally elastic regime are performed for a model binary glass with strain rates as low as $10^{4}$/sec (corresponding to 0.01 shear strain per 1$\mu$sec). A robust elasticity is revealed that…

Soft Condensed Matter · Physics 2020-11-21 P. M. Derlet , R. Maass

We present simulation results for the dynamics of a schematic model based on the frustration-limited domain picture of glass-forming liquids. These results are compared with approximate theoretical predictions analogous to those commonly…

Statistical Mechanics · Physics 2009-11-10 Phillip L. Geissler , David R. Reichman

Glass forming liquids exhibit structural relaxation behaviors, reflecting underlying atomic rearrangements on a wide range of timescales. These behaviors play a crucial role in determining many material properties. However, the relaxation…

We numerically study the zero-temperature relaxation dynamics of several glass-forming models to their inherent structures, following quenches from equilibrium configurations sampled across a wide range of initial temperatures. In a…

Statistical Mechanics · Physics 2022-04-07 Yoshihiko Nishikawa , Misaki Ozawa , Atsushi Ikeda , Pinaki Chaudhuri , Ludovic Berthier

Supercooled liquids exhibit spatial heterogeneity in the dynamics of their fluctuating atomic arrangements. The length and time scales of the heterogeneous dynamics are central to the glass transition and influence nucleation and growth of…

Materials Science · Physics 2018-05-09 Pei Zhang , Jason J. Maldonis , Ze Liu , Jan Schroers , Paul M. Voyles

We present a model for glassy dynamics in supercooled liquid mixtures. Given the relaxation behavior of individual supercooled liquids, the model predicts the relaxation times of their mixtures as temperature is decreased. The model is…

Statistical Mechanics · Physics 2019-09-11 Shachi Katira , Juan P. Garrahan , Kranthi K. Mandadapu

By numerical integration, we study the relaxation dynamics of degenerate harmonic oscillator modes dispersively coupled to particle positions. Depending on whether the effective inertial potential induced by the oscillators keep the…

Mesoscale and Nanoscale Physics · Physics 2017-09-13 Christin Rhen , Andreas Isacsson

We numerically study dynamics and correlation length scales of a colloidal liquid in both quiescent and sheared conditions to further understand the origin of slow dynamics and dynamic heterogeneity in glass-forming systems. The simulation…

Soft Condensed Matter · Physics 2015-06-05 Wen-Sheng Xu , Zhao-Yan Sun , Li-Jia An

We present a dynamical description of slow relaxation processes based on the extension of Onsager's fluctuation theory to systems in local quasi-equilibrium. A non-Markovian Fokker-Planck equation for the conditional probability density is…

Statistical Mechanics · Physics 2009-11-10 I. Santamaria-Holek , A. Perez-Madrid , J. M. Rubi