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Which phenomenon slows down the dynamics in super-cooled liquids and turns them into glasses is a long-standing question of condensed-matter. Most popular theories posit that as the temperature decreases, many events must occur in a…

Soft Condensed Matter · Physics 2024-03-22 Massimo Pica Ciamarra , Wencheng Ji , Matthieu Wyart

We examine the structural relaxation of glassy materials at finite temperatures, considering the effect of activated rearrangements and long-range elastic interactions. Our three-dimensional mesoscopic relaxation model shows how the…

Soft Condensed Matter · Physics 2023-12-20 Gieberth Rodriguez-Lopez , Kirsten Martens , Ezequiel E. Ferrero

The origin of stretched exponential relaxation in supercooled glass-forming liquids is one of the central questions regarding the anomalous dynamics of these fluids. The dominant explanation for this phenomenon has long been the proposition…

Soft Condensed Matter · Physics 2021-02-03 Daniel Diaz Vela , David S. Simmons

The question of whether glass continues to relax at low temperature is of fundamental and practical interest. Here, we report a novel atomistic simulation method allowing us to directly access the long-term dynamics of glass relaxation at…

Disordered Systems and Neural Networks · Physics 2015-10-27 Yingtian Yu , Mengyi Wang , Dawei Zhang , Bu Wang , Gaurav Sant , Mathieu Bauchy

Elastic models of the glass transition relate the relaxation dynamics and the elastic properties of structural glasses. They are based on the assumption that the relaxation dynamics occurs through activated events in the energy landscape…

Soft Condensed Matter · Physics 2015-08-20 M. Pica Ciamarra , Peter Sollich

Minimalist theories of complex systems are broadly of two kinds: mean-field and axiomatic. So far all theories of complex properties absent from simple systems and intrinsic to glasses are axiomatic. Stretched Exponential Relaxation (SER)…

Soft Condensed Matter · Physics 2013-05-29 J. C. Phillips

Amorphous solids or glasses are known to exhibit stretched-exponential decay over broad time intervals in several of their macroscopic observables: intermediate scattering function, dielectric relaxation modulus, time-elastic modulus etc.…

Soft Condensed Matter · Physics 2017-01-19 B. Cui , R. Milkus , A. Zaccone

We provide a theoretical description of dynamical heterogeneities in glass-forming liquids, based on the premise that relaxation occurs via local rearrangements coupled by elasticity. In our framework, the growth of the dynamical…

Soft Condensed Matter · Physics 2023-11-02 Ali Tahaei , Giulio Biroli , Misaki Ozawa , Marko Popović , Matthieu Wyart

Because the theory of SER is still a work in progress, the phenomenon itself can be said to be the oldest unsolved problem in science, as it started with Kohlrausch in 1847. Many electrical and optical phenomena exhibit SER with probe…

Soft Condensed Matter · Physics 2015-05-18 J. C. Phillips

The dynamical facilitation scenario, by which localized relaxation events promote nearby relaxation events in an avalanching process, has been suggested as the key mechanism connecting the microscopic and the macroscopic dynamics of…

Soft Condensed Matter · Physics 2015-11-03 Raffaele Pastore , Antonio Coniglio , Massimo Pica Ciamarra

While deeply supercooled liquids exhibit divergent viscosity and increasingly heterogeneous dynamics as the temperature drops, their structure shows only seemingly marginal changes. Understanding the nature of relaxation processes in this…

Materials Science · Physics 2022-11-03 Matthias Lerbinger , Armand Barbot , Damien Vandembroucq , Sylvain Patinet

The relaxation dynamics of glass-forming systems shows a multitude of features that are absent in normal liquids, such as non-exponential relaxation and a strong temperature-dependence of the relaxation time. Connecting these dynamic…

Disordered Systems and Neural Networks · Physics 2019-04-03 Zhen Wei Wu , Walter Kob , Wei-Hua Wang , Limei Xu

We investigate the origin of the breakdown of the Stokes-Einstein relation (SER) between diffusivity and viscosity in undercooled melts. A binary Lennard-Jones system, as a model for a metallic melt, is studied by molecular dynamics. A weak…

Disordered Systems and Neural Networks · Physics 2016-06-22 H. R. Schober , H. L. Peng

For several atomistic models of glass formers, at conditions below their glassy dynamics onset temperatures, ${T_\mathrm{o}}$, we use importance sampling of trajectory space to study the structure, statistics and dynamics of excitations…

Statistical Mechanics · Physics 2014-05-08 Aaron S. Keys , Lester O. Hedges , Juan P. Garrahan , Sharon C. Glotzer , David Chandler

We present a mean-field theory of a coarse-grained model of a super-cooled liquid in which relaxation occurs via local plastic rearrangements. Local relaxation can be induced by thermal fluctuations or by the long-range elastic consequences…

Soft Condensed Matter · Physics 2023-12-07 Joseph W. Baron , Giulio Biroli

The nonlinear rheological properties of dense suspensions are discussed within simplified models, suggested by a recent first principles approach to the model of Brownian particles in a constant-velocity-gradient solvent flow. Shear…

Soft Condensed Matter · Physics 2015-06-24 Matthias Fuchs , Michael E. Cates

Measured exponents associated with Stretched Exponential Relaxation (SER) are widely scattered in microscopically inhomogeneous glasses, but accurately bifurcate into two "magic" values, 3/5 and 3/7, in a wide variety of microscopically…

Soft Condensed Matter · Physics 2015-05-28 G. G. Naumis , J. C. Phillips

We propose a dynamic Kerr effect experiment for the distinction between dynamic heterogeneous and homogeneous relaxation in glassy systems. The possibility of this distinction is due to the inherent nonlinearity of the Kerr effect signal.…

Soft Condensed Matter · Physics 2009-11-11 Uli Haeberle , Gregor Diezemann

The interrelation of dynamic processes active on separated time-scales in glasses and viscous liquids is investigated using a model displaying two time-scale bifurcations both between fast and secondary relaxation and between secondary and…

Disordered Systems and Neural Networks · Physics 2015-03-19 Andrea Crisanti , Luca Leuzzi , Matteo Paoluzzi

Relaxation in glasses is often approximated by a stretched-exponential form: $f(t) = A \exp [-(t/\tau)^{\beta}]$. Here, we show that the relaxation in a model of sheared non-Brownian suspensions developed by Cort\'e et al. [Nature Phys. 4,…

Soft Condensed Matter · Physics 2017-02-02 Joseph D. Paulsen , Sidney R. Nagel
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