Related papers: Probing the force field sensitivity of entropy and…
Accurate characterization of entropy plays a pivotal role in capturing reversible and irreversible heating in supercapacitors during charging/discharging cycles. However, numerical methods that can faithfully capture entropy variation in…
Electrical charges are conserved. The same would be expected to hold for magnetic charges, yet magnetic monopoles have never been observed. It is therefore surprising that the laws of non-equilibrium thermodynamics, combined with Maxwell's…
We developed a new technique for measuring the thermodynamic entropy as a function of the magnetic field angle. This technique enables high-resolution angle-resolved measurements of the entropy in an unprecedentedly short measuring time.…
The correct calculation of formation enthalpy is one of the enablers of ab-initio computational materials design. For several classes of systems (e.g. oxides) standard density functional theory produces incorrect values. Here we propose the…
The net entropy change corresponding to the charge carriers in a Ni-doped FeRh bulk polycrystal was experimentally evaluated in a single sample using low temperature heat capacity experiments with applied magnetic field, and using Seebeck…
Understanding the phase stability of elemental lithium (Li) is crucial for optimizing its performance in lithium-metal battery anodes, yet this seemingly simple metal exhibits complex polymorphism that requires proper accounting for quantum…
Thermodynamic quantities, like heat, entropy, or work, are random variables, in stochastic systems. Here, we investigate the statistics of the heat exchanged by a Brownian particle subjected to a logarithm-harmonic potential. We derive…
We show that entropy is globally concave with respect to energy for a rich class of mean field interactions, including regularizations of the the point-vortex model in the plane, plasmas and self-gravitating matter in 2D, as well as the…
It is important to be able to calculate the moist-air entropy of the atmosphere with precision. A potential temperature has already been defined from the third law of thermodynamics for this purpose. However, a doubt remains as to whether…
We calculate the far-from-equilibrium dynamics and thermalization both for the quantum and the classical O(N)--model. The early and late-time behavior can be described from the 2PI--loop expansion for weak couplings or the nonperturbative…
When the difference between changes in energy and entropy at a given temperature is correlated with the ratio between the same changes in energy and entropy at zero average free energy of an ensemble of similar but distinct molecule-sized…
The entropy of the two-dimensional $t$-$J$ model is investigated using its 12th order high temperature series. A direct Pad\'{e} extrapolation of the entropy series doesn't converge well for temperatures below $T\sim J$. The series…
The effective potential of $\lambda\phi^4_{1+3}$ model with both sign of parameter $m^2$ is evaluated at T=0 by means of a simple but effective method for regularization and renormalization. Then at $T\ne 0$, the effective potential is…
Controlling electrochemical reactivity requires a detailed understanding of the charging behavior and thermodynamics of the electrochemical interface. Experiments can independently probe the overall charge response of the electrochemical…
We introduce a new parametrization of the AMOEBA polarizable force field for water denoted Q-AMOEBA, for use in simulations that explicitly account for nuclear quantum effects (NQEs). This study is made possible thanks to the recently…
In a dense plasma environment, the energy levels of an ion shift relative to the isolated ion values. This shift is reflected in the optical spectrum of the plasma and can be measured in, for example, emission experiments. In this work, we…
Electroweak precision observables (EWPO) measured at the W and Z poles provide stringent limits on possible beyond the Standard Model physics scenarios. In an effective field theory (EFT) framework, the next-to-leading order QCD and…
We employ the recently introduced generalized microcanonical inflection point method for the statistical analysis of phase transitions in flexible and semiflexible polymers and study the impact of the bending stiffness upon the character…
The so-called Froehlich entropy is the entropy variation of a material under the application of an electric field. This quantity can be calculated, under suitable hypotheses, directly from the measured real part of the dielectric function.…
According to the second law of thermodynamics the total entropy of a system is increased during almost any dynamical process. The positivity of the specific heat implies that the entropy increase is associated with heating. This is…