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We propose a weak solution theory for the sharp interface limit of the Cahn-Hilliard reaction model, a variational PDE for lithium-ion batteries. An essential feature of this model is the use of Butler-Volmer kinetics for lithium-ion…

Analysis of PDEs · Mathematics 2022-09-16 Tim Laux , Kerrek Stinson

Lithium-ion batteries exhibit complex nonlinear dynamics, resulting from diffusion and phase transformations coupled to ion intercalation reactions. Using the recently developed Cahn-Hilliard reaction (CHR) theory, we investigate a simple…

Chemical Physics · Physics 2014-02-13 Yi Zeng , Martin Z. Bazant

In this article the Butler-Volmer equation used in describing Lithium-ion (Li-ion) batteries is discussed. First, a complete mathematical model based on a macro-homogeneous approach developed by Neuman is presented. Two common mistakes…

Chemical Physics · Physics 2015-03-20 A. M. Ramos , C. P. Please

The Cahn--Hilliard equation is one of the most common models to describe phase segregation processes in binary mixtures. In recent times, various dynamic boundary conditions have been introduced to model interactions of the materials with…

Analysis of PDEs · Mathematics 2021-10-12 Patrik Knopf , Andrea Signori

To study the electrochemical reaction on surfaces, phase interfaces, and crack surfaces in the lithium ion battery electrode particles, a phase-field model is developed, which describes fracture in large strains and anisotropic…

Materials Science · Physics 2016-05-31 Ying Zhao , Bai-Xiang Xu , Peter Stein , Dietmar Gross

The Cahn--Hilliard equation is one of the most common models to describe phase separation processes of a mixture of two materials. For a better description of short-range interactions between the material and the boundary, various dynamic…

Analysis of PDEs · Mathematics 2021-04-27 Patrik Knopf , Kei Fong Lam , Chun Liu , Stefan Metzger

A nonlinear phase-field model is developed to simulate corrosion damage. The motion of the electrode$-$ electrolyte interface follows the usual kinetic rate theory for chemical reactions based on the Butler-Volmer equation. The model links…

Chemical Physics · Physics 2024-08-28 M. Makuch , S. Kovacevic , M. R. Wenman , E. Martínez-Pañeda

We reformulate and extend porous electrode theory for non-ideal active materials, including those capable of phase transformations. Using principles of non-equilibrium thermodynamics, we relate the cell voltage, ionic fluxes, and Faradaic…

Chemical Physics · Physics 2012-08-24 Todd R. Ferguson , Martin Z. Bazant

An existence result is proved for a nonlinear diffusion problem of phase-field type, consisting of a parabolic system of two partial differential equations, complemented by Neumann homogeneous boundary conditions and initial conditions.…

Analysis of PDEs · Mathematics 2012-02-24 Pierluigi Colli , Gianni Gilardi , Paolo Podio-Guidugli , Jürgen Sprekels

In this article we investigate a model for the temperature within a Lithium-Ion battery. The model takes the form of a parabolic PDE for the temperature coupled with two elliptic PDE's for the electric potential within the solid and…

Analysis of PDEs · Mathematics 2024-06-06 Brock C. Price , Xiangsheng Xu

We build a transient multidimensional multiphysical model based on continuum theories, involving the coupled mechanical, thermal and electrochemical phenomena occurring simultaneously in the discharge or charge of lithium-ion batteries. The…

Numerical Analysis · Mathematics 2024-03-26 Jaime Mora-Paz

An appropriate description of the lithiation/delithiation dynamics in bi-phasic primary cathode particles of Li-ion batteries requires an accurate treatment of the conditions holding at the interface between the particle and the surrounding…

Materials Science · Physics 2024-11-01 Ahmed Yousfi , Arnaud Demortière , Guillaume Boussinot

In this paper we study a system of partial differential equations which models lithium-ion batteries. The system describes the conservation of Lithium and conservation of charges in the solid and electrolyte phases, together with the…

Analysis of PDEs · Mathematics 2022-02-08 Xiangsheng Xu

The Cahn--Hilliard equation is a widely used model that describes amongst others phase separation processes of binary mixtures or two-phase flows. In the recent years, different types of boundary conditions for the Cahn--Hilliard equation…

Numerical Analysis · Mathematics 2021-03-04 Stefan Metzger

We present a porous electrode model for lithium-ion batteries using Butler--Volmer reaction kinetics. We model lithium concentration in both the solid and fluid phase along with solid and liquid electric potential. Through asymptotic…

Applied Physics · Physics 2019-06-03 Iain R. Moyles , Matthew G. Hennessy , Timothy G. Myers , Brian R. Wetton

The Cahn--Hilliard equation is a fundamental model that describes phase separation processes of binary mixtures. In recent years, several types of dynamic boundary conditions have been proposed in order to account for possible short-range…

Analysis of PDEs · Mathematics 2023-07-28 Chun Liu , Hao Wu

We consider a differential model describing nonisothermal fast phase separation processes taking place in a three-dimensional bounded domain. This model consists of a viscous Cahn-Hilliard equation characterized by the presence of an…

Analysis of PDEs · Mathematics 2007-05-23 Maurizio Grasselli , Hana Petzeltova , Giulio Schimperna

This paper presents the current state of mathematical modelling of the electrochemical behaviour of lithium-ion batteries as they are charged and discharged. It reviews the models developed by Newman and co-workers, both in the cases of…

Chemical Physics · Physics 2020-02-04 Giles W Richardson , Jamie M Foster , Rahifa Ranom , Colin P Please , Angel M Ramos

A system with equation and dynamic boundary condition of Cahn-Hilliard type is considered. This system comes from a derivation performed in Liu-Wu (Arch. Ration. Mech. Anal. 233 (2019), 167--247) via an energetic variational approach.…

Analysis of PDEs · Mathematics 2022-08-02 Pierluigi Colli , Takeshi Fukao , Luca Scarpa

We consider a general class of bulk-surface convective Cahn--Hilliard systems with dynamic boundary conditions. In contrast to classical Neumann boundary conditions, the dynamic boundary conditions of Cahn--Hilliard type allow for dynamic…

Analysis of PDEs · Mathematics 2024-07-23 Patrik Knopf , Jonas Stange
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