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Thermoresponsive polymers hold both fundamental and technological importance, but the essential physics driving their intriguing behavior is not wholly understood. We introduce a lattice framework that incorporates elements of Flory-Huggins…

Soft Condensed Matter · Physics 2024-03-04 Satyen Dhamankar , Michael A. Webb

We address the response of a random heteropolymer to preferential solvation of certain monomer types at the globule-solvent interface. For each set of monomers that can comprise the molecule's surface, we represent the ensemble of allowed…

Soft Condensed Matter · Physics 2009-11-10 Philip Geissler , Eugene Shakhnovich , Alexander Grosberg

A theoretical study on the phase behaviors of a polymer solution confined between two coaxial cylindrical walls is presented. For the case of a neutral inner cylinder, the spinodal point derived through the Gaussian fluctuation theory is…

Soft Condensed Matter · Physics 2009-09-23 Tongchuan Suo , Dadong Yan

Various aspects of self-motility of chemically active colloids in Newtonian fluids can be captured by simple models for their chemical activity plus a phoretic slip hydrodynamic boundary condition on their surface. For particles of simple…

Soft Condensed Matter · Physics 2018-04-09 M. N. Popescu , W. E. Uspal , Z. Eskandari , M. Tasinkevych , S. Dietrich

We consider a stiff polymer chain in poor solvent and apply a force at one end of the chain. We find that by varying the stiffness parameter, polymer undergoes a transition from the globule state to the folded like state. The conformation…

Soft Condensed Matter · Physics 2015-05-13 Sanjay Kumar , Debaprasad Giri

We study the dynamics of an ideal polymer chain in a crowded, viscoelastic medium and in the presence of active forces. The motion of the centre of mass and of individual monomers is calculated. On time scales that are comparable to the…

Soft Condensed Matter · Physics 2015-12-23 Hans Vandebroek , Carlo Vanderzande

We demonstrate that the thermal Casimir-Polder forces on molecules near a conducting surface whose transition wavelengths are comparable to the molecule-surface separation are dependent on the ambient temperature and molecular polarization…

Atomic Physics · Physics 2015-06-12 Zhiying Zhu , Hongwei Yu , Bin Wang

Polymer chains undergoing a continuous adsorption-desorption transition are studied through extensive computer simulations. A three-dimensional self-avoiding walk lattice model of a polymer chain grafted onto a surface has been treated for…

Statistical Mechanics · Physics 2018-05-30 P. H. L. Martins , J. A. Plascak , M. Bachmann

Despite much current interest in active matter, little is known about osmosis in active systems. Using molecular dynamics simulations, we investigate how active solutes perturb osmotic steady states. We find that solute activity increases…

Soft Condensed Matter · Physics 2015-06-18 Thomas W. Lion , Rosalind J. Allen

Understanding multibody interactions between colloidal particles out of equilibrium has a profound impact on dynamical processes such as colloidal self assembly. However, traditional colloidal interactions are effectively quasi-static on…

Soft Condensed Matter · Physics 2023-03-17 Yaxin Xu , Kyu Hwan Choi , Sachit G. Nagella , Sho C. Takatori

Using a simple model, we study the fluctuating dynamics of inextensible, semiflexible polar filaments interacting with active and directed force generating centres such as molecular motors. Taking into account the fact that the activity…

Soft Condensed Matter · Physics 2009-11-07 Tanniemola B. Liverpool

We present single contact friction experiments between a glassy polymer and smooth silica substrates grafted with alkylsilane layers of different coverage densities and morphologies. This allows us to adjust the polymer/substrate…

Soft Condensed Matter · Physics 2007-05-23 Lionel Bureau , Christiane Caroli , Tristan Baumberger

Poly-N-isopropylacrylamide (PNIPAM) phase diagram is explored in a wide range of temperature and pressure using extensive all-atom molecular dynamics simulations. By exploiting a simple model of an atactic linear polymer chain, we provide…

Soft Condensed Matter · Physics 2021-07-23 Letizia Tavagnacco , Ester Chiessi , Emanuela Zaccarelli

We consider the dynamics of a translocation process of a flexible linear polymer through a nanopore into an environment of active rods in the {\it trans} side. Using Langevin dynamics simulations we find that the rods facilitate…

Soft Condensed Matter · Physics 2022-11-15 Hamidreza Khalilian , Jalal Sarabadani , Tapio Ala-Nissila

A directed polymer is considered on a flat substrate with randomly located parallel ridges. It prefers to lie inside wide regions between the ridges. When the transversel width $W=\exp(\lambda L^{1/3})$ is exponential in the longitudinal…

Disordered Systems and Neural Networks · Physics 2009-10-30 Th. M. Nieuwenhuizen

Folding and unfolding of biopolymers are often manipulated in experiment by tuning pH, temperature, single-molecule force or shear field. Here we carry out Brownian dynamics simulations to explore the behavior of a single self-attracting…

Soft Condensed Matter · Physics 2019-03-27 Yi-qi Xia , Wen-jie Shan , Wen-de Tian , Kang Chen , Yu-qiang Ma

Active colloids and externally actuated semi-flexible filaments provide basic building blocks for designing autonomously motile micro-machines. Here, we show that a passive semi-flexible filament can be actuated and transported by attaching…

Soft Condensed Matter · Physics 2017-04-05 Abhrajit Laskar , R. Adhikari

Self-avoiding walks are studied on the 3-simplex fractal lattice as a model of linear polymer conformations in a dilute, non-homogeneous solution. A model is supplemented with bending energies and attractive-interaction energies between…

Statistical Mechanics · Physics 2023-02-21 Dušanka Marčetić

We present a statistical model of a dilute polymer solution in good solvent in the presence of low-molecular weight cosolvent. We investigate the conformational changes of the polymer induced by a change of the cosolvent concentration and…

Statistical Mechanics · Physics 2014-11-10 Yu. A. Budkov , A. L. Kolesnikov , N. Georgi , M. G. Kiselev

A long flexible neutral polymer chain immersed in a poor solvent and interacting with an impenetrable attractive surface exhibits a phase known as surface attached globule ({\bf SAG}) in addition to other adsorbed and desorbed phases. In…

Statistical Mechanics · Physics 2009-11-07 Pramod Kumar Mishra , D. Giri , S. Kumar , Y. Singh
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