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Developing new multiferroics at the two-dimensional (2D) limit with energy-efficient magnetoelectric coupling can inform the interplay physics of novel orders and advance on-chip high-performance computing applications. Here we apply…

Two-dimensional (2D) van der Waals ferroelectrics are recognized for enabling many applications, from memory and logic to neuromorphic computing, as well as transforming other materials to control electronic phase transitions and…

Sliding ferroelectricity is a phenomenon that arises from the insurgence of spontaneous electronic polarization perpendicular to the layers of two-dimensional (2D) systems upon the relative sliding of the atomic layer constituents. Because…

Materials Science · Physics 2026-04-21 Matteo D'Alessio , Daniele Varsano , Elisa Molinari , Massimo Rontani

Out-of-plane and in-plane electric polarization, which rarely coexist in a two-dimensional (2D) ferroelectric material, offer different advantages in ferroelectricity-based devices. Here, we report the coexistence of in-plane and…

Materials Science · Physics 2026-03-24 A. D. Molchanova , L. H. Yin , L. P. Gao , W. H. Song , Y. P. Sun , K. R. Allahverdiyev , M. N. Popova

Two-dimensional (2D) ferroelectricity has attracted extensive attention since its discovery in the monolayers of van der Waals materials. Here we show that 2D ferroelectricity induced by octahedral rotation distortion is widely present in…

Materials Science · Physics 2022-02-11 Ying Zhou , Shuai Dong , Changxun Shan , Ke Ji , Junting Zhang

Two-dimensional (2D) van der Waals ferroelectrics provide an unprecedented architectural freedom for the creation of artificial multiferroics and non-volatile electronic devices based on vertical and co-planar heterojunctions of 2D ferroic…

The van der Waals layered semiconductor CrSBr, which exhibits A-type antiferromagnetism and a relatively high N\'{e}el temperature, has been successfully exfoliated into atomically thin sheets. In this study, we investigate the structural,…

Materials Science · Physics 2025-02-07 Huicong Li , Yali Yang , Zhonghao Xia , Yateng Wang , Jiacheng Wei , Jiangang He , Rongming Wang

Stacking ferroelectricity (SFE) has been discovered in a wide range of van der Waals materials and holds promise for applications, including photovoltaics and high-density memory devices. We show that the microscopic origin of out-of-plane…

Materials Science · Physics 2024-05-13 Benjamin T. Zhou , Vedangi Pathak , Marcel Franz

Low dimensional ferroelectrics are highly desired for applications and full of exotic physics. Here a functionalized MXene Hf$_2$CF$_2$ monolayer is theoretically studied, which manifests a nonpolar to polar transition upon moderate biaxial…

Materials Science · Physics 2021-11-17 Ziwen Wang , Ning Ding , Churen Gui , Shanshan Wang , Ming An , Shuai Dong

Strain, both naturally occurring and deliberately engineered, can have a considerable effect on the structural and electronic properties of 2D and layered materials. Uniaxial or biaxial heterostrain modifies the stacking arrangement of…

Materials Science · Physics 2022-10-19 Nina C. Georgoulea , Stephen R. Power , Nuala M. Caffrey

We study the dielectric response of few layered crystals of various transition metal dichalcogenides (TMDs) and hexagonal Boron Nitride (hBN). We showed that the out-of-plane polarizability of a multilayer crystal (which characterizes…

Mesoscale and Nanoscale Physics · Physics 2022-10-14 Fábio Ferreira , Vladimir Enaldiev , Vladimir Fal'ko

Stacking order in van der Waals materials determines the coupling between atomic layers and is therefore key to the materials' properties. By exploring different stacking orders, many novel physical phenomena have been realized in…

Ferroelectric HfO2 is a promising candidate for next-generation memory devices due to its CMOS compatibility and ability to retain polarization at nanometer scales. However, the polar orthorhombic phase (Pca2_1) responsible for…

Materials Science · Physics 2026-03-27 Jian Huang , Gwan Yeong Jung , Pravan Omprakash , Guodong Ren , Xin Li , Du Li , Xiaoshan Xu , Li Yang , Rohan Mishra

Two-dimensional van der Waals materials offer a highly tunable platform for generating emergent quantum phenomena through symmetry breaking. Stacking-induced symmetry breaking at interfaces provides an effective method to modulate their…

Mesoscale and Nanoscale Physics · Physics 2025-01-23 Xing-Guo Ye , Zhen-Tao Zhang , Peng-Fei Zhu , Wen-Zheng Xu , An-Qi Wang , Zhi-Min Liao

Two-dimensional (2D) hexagonal boron nitride (hBN) is a wide-bandgap van der Waals crystal with a unique combination of properties, including exceptional strength, large oxidation resistance at high temperatures and optical functionalities.…

Mesoscale and Nanoscale Physics · Physics 2025-10-27 P. Ares , T. Cea , M. Holwill , Y. B. Wang , R. Roldan , F. Guinea , D. V. Andreeva , L. Fumagalli , K. S. Novoselov , C. R. Woods

Van der Waals (vdW) layered materials have rather weaker interlayer bonding than the intra-layer bonding, therefore the exfoliation along the stacking direction enables the achievement of monolayer or few layers vdW materials with emerging…

Moire superlattices formed in van der Waals heterostructures due to twisting, lattice mismatch and strain present an opportunity for creating novel metamaterials with unique properties not present in the individual layers themselves.…

We report a high throughput computational search for two-dimensional ferroelectric materials. The starting point is 252 pyroelectric materials from the computational 2D materials database (C2DB) and from these we identify 64 ferroelectric…

Ferroelectricity is usually found in compound materials composed by different elements. Here, based on first-principles calculations, we reveal the first example of spontaneous electrical polarization and ferroelectricity in stable…

Materials Science · Physics 2017-06-20 Chengcheng Xiao , Fang Wang , Shengyuan A. Yang , Yunhao Lu

Two-dimensional (2D) hexagonal boron nitride (BN) nanosheets are excellent dielectric substrate for graphene, molybdenum disulfide and many other 2D nanomaterials based electronic and photonic devices. To optimize the performance of these…

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