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New diffuse interface and sharp interface models for soluble and insoluble surfactants fulfilling energy inequalities are introduced. We discuss their relation with the help of asymptotic analysis and present an existence result for a…

Fluid Dynamics · Physics 2016-10-27 Helmut Abels , Harald Garcke , Kei Fong Lam , Josef Weber

We introduce a systematic classification method for the analogs of phase transitions in finite systems. This completely general analysis, which is applicable to any physical system and extends towards the thermodynamic limit, is based on…

Statistical Mechanics · Physics 2015-05-28 Stefan Schnabel , Daniel T. Seaton , David P. Landau , Michael Bachmann

Surface-active agents (surfactants) release potential energy as they migrate from one of two adjacent fluids onto their fluid-fluid interface, a process that profoundly impacts the system's energy and entropy householding. The continuum…

Fluid Dynamics · Physics 2024-05-29 T. B. van Sluijs , S. K. F. Stoter , E. H. van Brummelen

This work is devoted to the consistent modeling of a three-phase mixture of a gas, a liquid and its vapor. Since the gas and the vapor are mis-cible, the mixture is subjected to a non-symmetric constraint on the volume. Adopting the Gibbs…

Analysis of PDEs · Mathematics 2017-10-13 Hélène Mathis

The aim of this work is to propose a provably convergent finite volume scheme for the so-called Stefan-Maxwell model, which describes the evolution of the composition of a multi-component mixture and reads as a cross-diffusion system. The…

Numerical Analysis · Mathematics 2020-07-21 Clément Cancès , Virginie Ehrlacher , Laurent Monasse

This paper presents a method for modelling interfacial mass transfer in Interface Capturing simulations of two-phase flow with phase change. The model enables mechanistic prediction of the local rate of phase change at the vapour-liquid…

Fluid Dynamics · Physics 2021-08-25 G. Giustini , R. I. Issa , M. J. Bluck

According to the dynamic van der Waals theory, we propose a thermodynamically consistent model for non-isothermal compressible two-phase flows with contact line motion. In this model, fluid temperature is treated as a primary variable,…

Fluid Dynamics · Physics 2025-08-11 Junkai Wang , Qiaolin He

A comprehensive scheme for the spatial discretisation of continuity equation, momentum advection and normal and shear stresses at the fluid interfaces is presented for numerically simulating the incompressible two phase flows based on the…

Fluid Dynamics · Physics 2014-08-11 Jun-De Li

The emerging field of stochastic thermodynamics extends classical ideas of entropy, heat and work to non-equilibrium systems. One notable finding is that the second law of thermodynamics typically only holds after taking appropriate…

Statistical Mechanics · Physics 2024-02-27 Paul C Bressloff

We propose a two-point flux approximation finite-volume scheme for the approximation of two cross-diffusion systems coupled by a free interface to account for vapor deposition. The moving interface is addressed with a cut-cell approach,…

Numerical Analysis · Mathematics 2023-07-14 Clément Cancès , Jean Cauvin-Vila , Claire Chainais-Hillairet , Virginie Ehrlacher

In earlier work \cite{bedeaux/vdW/I, bedeaux/vdW/II, bedeaux/vdW/III} a systematic extension of the van der Waals square gradient model to non-equilibrium one-component systems was given. In this work the focus was on heat and mass transfer…

Soft Condensed Matter · Physics 2007-11-08 K. S. Glavatskiy , D. Bedeaux

A diffuse interface model for surfactants in multi-phase flow with three or more fluids is derived. A system of Cahn-Hilliard equations is coupled with a Navier-Stokes system and an advection-diffusion equation for the surfactant ensuring…

Numerical Analysis · Mathematics 2018-10-30 Oliver R. A. Dunbar , Kei Fong Lam , Bjorn Stinner

This work focuses on the interfacial dynamics with interfacial mass flux in the presence of acceleration and surface tension. We employ the general matrix method to find the fundamental solutions for the linearized boundary value problem…

Fluid Dynamics · Physics 2021-07-07 D. V. Ilyin , S. I. Abarzhi

We present a numerical method for the solution of interfacial growth governed by the Stefan model coupled with incompressible fluid flow. An algorithm is presented which takes special care to enforce sharp interfacial conditions on the…

Fluid Dynamics · Physics 2022-10-19 Elyce Bayat , Raphael Egan , Daniil Bochkov , Alban Sauret , Frederic Gibou

Based on the thermodynamic variation, we rigorously derive the sharp-interface model for solid-state dewetting on a flat substrate in the form of cylindrical symmetry. The governing equations for the model belong to fourth-order geometric…

Materials Science · Physics 2018-05-22 Quan Zhao

In this paper we calculate the transfer coefficients for evaporation and condensation of mixtures. We use the continuous profiles of various thermodynamic quantities through the interface, obtained in our previous works using the square…

Soft Condensed Matter · Physics 2009-07-14 K. S. Glavatskiy , D. Bedeaux

A type-I model of non-isothermal multicomponent systems of gases describing mass diffusive and heat conductive phenomena is presented. The derivation of the model and a convergence result among thermomechanical theories in the smooth regime…

Analysis of PDEs · Mathematics 2023-01-24 Stefanos Georgiadis , Ansgar Jüngel , Athanasios Tzavaras

We study the mechanical contact between a deformable body with a wavy surface and a rigid flat taking into account pressurized fluid trapped in the interface. A finite element model is formulated for a general problem of trapped fluid for…

Fluid Dynamics · Physics 2021-03-23 Andrei G. Shvarts , Vladislav A. Yastrebov

This paper presents a general and robust method for the fluid-structure interaction of membranes and shells undergoing large displacement and large added-mass effects by coupling an immersed-boundary method with a shell finite-element…

Fluid Dynamics · Physics 2023-08-15 Marin Lauber , Gabriel D. Weymouth , Georges Limbert

Reactive, semi-permeable interfaces play important roles in key biological processes such as targeted drug delivery, lipid metabolism, and signal transduction. These systems involve coupled surface reactions, transmembrane transport, and…

Numerical Analysis · Mathematics 2025-07-22 Weidong Shi , Shixin Xu , Zhen Zhang , Quan Zhao