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Newton's method may exhibit slower convergence than vanilla Gradient Descent in its initial phase on strongly convex problems. Classical Newton-type multilevel methods mitigate this but, like Gradient Descent, achieve only linear…

Optimization and Control · Mathematics 2026-02-25 Nick Tsipinakis , Panos Parpas , Matthias Voigt

Newton's method may exhibit slower convergence than vanilla Gradient Descent in its initial phase on strongly convex problems. Classical Newton-type multilevel methods mitigate this but, like Gradient Descent, achieve only linear…

Optimization and Control · Mathematics 2026-03-05 Nick Tsipinakis , Panagiotis Tigkas , Panos Parpas

Bayesian inference often faces a trade-off between computational speed and sampling accuracy. We propose an adaptive workflow that integrates rapid amortized inference with gold-standard MCMC techniques to achieve a favorable combination of…

Machine Learning · Computer Science 2026-02-19 Chengkun Li , Aki Vehtari , Paul-Christian Bürkner , Stefan T. Radev , Luigi Acerbi , Marvin Schmitt

Based on a new coupling approach, we prove that the transition step of the Hamiltonian Monte Carlo algorithm is contractive w.r.t. a carefully designed Kantorovich (L1 Wasserstein) distance. The lower bound for the contraction rate is…

Probability · Mathematics 2020-07-30 Nawaf Bou-Rabee , Andreas Eberle , Raphael Zimmer

Model space quantum Monte Carlo (MSQMC) is an extension of full configuration interaction QMC (FCIQMC) that allows us to calculate quasi-degenerate and excited electronic states by sampling the effective Hamiltonian in the model space. We…

Chemical Physics · Physics 2017-12-29 Seiichiro L. Ten-no

Monte Carlo (MC) and Quasi-Monte Carlo (QMC) methods are classical approaches for the numerical integration of functions $f$ over $[0,1]^d$. While QMC methods can achieve faster convergence rates than MC in moderate dimensions, their…

Numerical Analysis · Mathematics 2025-08-27 Jiaheng Chen , Haotian Jiang , Nathan Kirk

A family of Variational Quantum Eigensolver (VQE) methods is designed to maximize the resource of existing noisy intermediate-scale quantum (NISQ) devices. However, VQE approaches encounter various difficulties in simulating molecules of…

Chemical Physics · Physics 2022-08-16 M. D. Sapova , A. K. Fedorov

Accurate determination of electronic properties of correlated oxides remains a significant challenge for computational theory. Traditional Hubbard-corrected density functional theory (DFT+U) frequently encounters limitations in precisely…

Materials Science · Physics 2024-03-19 Hyeondeok Shin , Kevin Gasperich , Tomas Rojas , Anh T. Ngo , Jaron T. Krogel , Anouar Benali

Adaptive gradient methods are typically used for training over-parameterized models. To better understand their behaviour, we study a simplistic setting -- smooth, convex losses with models over-parameterized enough to interpolate the data.…

Machine Learning · Computer Science 2021-02-22 Sharan Vaswani , Issam Laradji , Frederik Kunstner , Si Yi Meng , Mark Schmidt , Simon Lacoste-Julien

The computation time required by standard finite difference methods with fixed timesteps for solving fractional diffusion equations is usually very large because the number of operations required to find the solution scales as the square of…

Numerical Analysis · Mathematics 2024-06-28 Santos B. Yuste , Joaquin Quintana-Murillo

Many existing covariate shift adaptation methods estimate sample weights given to loss values to mitigate the gap between the source and the target distribution. However, estimating the optimal weights typically involves computationally…

Machine Learning · Statistics 2024-07-01 François Portier , Lionel Truquet , Ikko Yamane

In this paper, we propose offline and online adaptive enrichment algorithms for the generalized multiscale approximation of a mixed finite element method with velocity elimination to solve the subsurface flow problem in high-contrast and…

Numerical Analysis · Mathematics 2020-07-20 Zhengkang He , Eric T. Chung , Jie Chen , Zhangxin Chen

Incremental full configuration interaction (iFCI) is polynomial-cost approach to the FCI limit of electronic structure. This article introduces the many-body basis set amelioration (MBBSA) method, which is designed to allow iFCI to be…

Chemical Physics · Physics 2025-03-12 Jeffrey P Hatch , Alan E Rask , Duy-Khoi Dang , Paul M Zimmerman

Code switching is an established technique that facilitates a universal set of FT quantum gate operations by combining two QEC codes with complementary sets of gates, which each by themselves are easy to implement fault-tolerantly. In this…

Quantum Physics · Physics 2025-09-10 Sascha Heußen , Janine Hilder

High dimensional integrals can be approximated well by quasi-Monte Carlo methods. However, determining the number of function values needed to obtain the desired accuracy is difficult without some upper bound on an appropriate semi-norm of…

Numerical Analysis · Mathematics 2017-06-27 Fred J. Hickernell , Lluís Antoni Jiménez Rugama , Da Li

This paper studies a generalization of hyperinterpolation over the high-dimensional unit cube. Hyperinterpolation of degree \( m \) serves as a discrete approximation of the \( L_2 \)-orthogonal projection of the same degree, using Fourier…

Numerical Analysis · Mathematics 2025-07-08 Congpei An , Mou Cai , Takashi Goda

Due to their diverse nature, the faithful description of excited states within electronic structure theory methods remains one of the grand challenges of modern theoretical chemistry. Quantum Monte Carlo (QMC) methods have been applied very…

Chemical Physics · Physics 2020-06-05 Anthony Scemama , Michel Caffarel , Anouar Benali , Denis Jacquemin , Pierre-François Loos

In low-temperature high-density plasmas quantum effects of the electrons are becoming increasingly important. This requires the development of new theoretical and computational tools. Quantum Monte Carlo methods are among the most…

Statistical Mechanics · Physics 2014-08-12 T. Schoof , S. Groth , M. Bonitz

For a generalized Hodge Laplace equation, we prove the quasi-optimal convergence rate of an adaptive mixed finite element method. This adaptive method can control the error in the natural mixed variational norm when the space of harmonic…

Numerical Analysis · Mathematics 2021-03-02 Yuwen Li

This work surveys an r-adaptive moving mesh finite element method for the numerical solution of premixed laminar flame problems. Since the model of chemically reacting flow involves many different modes with diverse length scales, the…

Numerical Analysis · Mathematics 2020-08-26 Zhen Sun , Malte Braack , Jens Lang
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