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We have developed a McMurchie-Davidson-like recursion formula for efficient evaluation of the Coulomb attraction and interaction matrix elements between two-dimensional primitive Cartesian Gaussian type orbitals. We also present recurrence…

Computational Physics · Physics 2021-11-30 Øyvind Sigmundson Schøyen , Håkon Emil Kristiansen , Alfred Alocias Mariadason

A method is given to obtain the Green's function for the Poisson equation in any arbitrary integer dimension under periodic boundary conditions. We obtain recursion relations which relate the solution in d-dimensional space to that in…

Mathematical Physics · Physics 2009-11-11 Sandeep Tyagi

We present a reciprocal space technique for the calculation of the Coulomb integral in two dimensions in systems with reduced periodicity, i.e., finite systems, or systems that are periodic only in one dimension. The technique consists in…

Other Condensed Matter · Physics 2009-10-09 Alberto Castro , Esa Rasanen , Carlo Andrea Rozzi

An integral scheme for the efficient evaluation of two-center integrals over contracted solid harmonic Gaussian functions is presented. Integral expressions are derived for local operators that depend on the position vector of one of the…

Chemical Physics · Physics 2017-02-07 Dorothea Golze , Niels Benedikter , Marcella Iannuzzi , Jan Wilhelm , Jürg Hutter

To improve the efficiency of Gaussian integral evaluation on modern accelerated architectures FLOP-efficient Obara-Saika-based recursive evaluation schemes are optimized for the memory footprint. For the 3-center 2-particle integrals that…

Computational Physics · Physics 2024-07-30 Andrey Asadchev , Edward F. Valeev

We implement an efficient method of computation of two dimensional Fourier-type integrals based on approximation of the integrand by Gaussian radial basis functions, which constitute a standard tool in approximation theory. As a result, we…

Numerical Analysis · Mathematics 2022-02-07 A. Martinez-Finkelshtein , D. Ramos-Lopez , D. R. Iskander

We present an efficient implementation of periodic Gaussian density fitting (GDF) using the Coulomb metric. The three-center integrals are divided into two parts by range-separating the Coulomb kernel, with the short-range part evaluated in…

Chemical Physics · Physics 2021-04-08 Hong-Zhou Ye , Timothy C. Berkelbach

This article presents two methods, in parallel, of solving more complex integrals, among which is the Poisson's integral, in order to emphasize the obvious advantages of a new method of integration, which uses the supermathematics circular…

General Mathematics · Mathematics 2007-06-29 Florentin Smarandache , Mircea Eugen Selariu

We present an efficient algorithm for the all-electron periodic Coulomb matrix based on the Ewald summation combined with the Fourier-transformed Coulomb method. The short-range contributions involving compact densities are evaluated in…

Chemical Physics · Physics 2025-09-23 Hieu Q. Dinh , Adam Rettig , Xintian Feng , Joonho Lee

We introduce an accurate and efficient method for a class of nonlocal potential evaluations with free boundary condition, including the 3D/2D Coulomb, 2D Poisson and 3D dipolar potentials. Our method is based on a Gaussian-sum approximation…

Computational Physics · Physics 2016-12-09 Lukas Exl , Norbert J. Mauser , Yong Zhang

1D lattice summations of the 3D Green's function are needed in many applications such as photonic crystals, antenna arrays, and so on. Such summations are usually divided into two cases, depending on the location of the observer: Out of the…

Optics · Physics 2017-03-02 Yarden Mazor , Yakir Hadad , Ben Z. Steinberg

We present a $GW$ space-time algorithm for periodic systems in a Gaussian basis including spin-orbit coupling. We employ lattice summation to compute the irreducible density response and the self-energy, while we employ $k$-point sampling…

We discuss the efficient computation of the auxiliary integrals that arise when resolutions of two-electron operators (specifically, the Coulomb and long-range Ewald operators) are employed in quantum chemical calculations. We derive a…

Chemical Physics · Physics 2013-01-10 Taweetham Limpanuparb , Joshua W. Hollett , Peter M. W. Gill

We give an efficient algorithm for robustly clustering of a mixture of two arbitrary Gaussians, a central open problem in the theory of computationally efficient robust estimation, assuming only that the the means of the component Gaussians…

Data Structures and Algorithms · Computer Science 2020-06-02 He Jia , Santosh Vempala

The partition function of the two-dimensional Ising model on a square lattice with nearest-neighbour interactions and periodic boundary conditions is investigated. Kaufman [Phys. Rev. 76, 1232--1243 (1949)] gave a solution for this function…

Statistical Mechanics · Physics 2007-05-23 Michael Kastner

We present a new reciprocal space analytical method to cutoff the long range interactions in supercell calculations for systems that are infinite and periodic in 1 or 2 dimensions, extending previous works for finite systems. The proposed…

Other Condensed Matter · Physics 2009-11-11 Carlo A. Rozzi , Daniele Varsano , Andrea Marini , Eberhard K. U. Gross , Angel Rubio

We present an efficient approach for simulating Coulomb systems confined by planar polarizable surfaces. The method is based on the solution of Poisson equation using periodic Green functions. It is shown that the electrostatic energy…

Soft Condensed Matter · Physics 2017-12-12 Alexandre P. dos Santos , Matheus Girotto , Yan Levin

We give explicit, polynomial-time computable formulas for the number of integer points in any two-dimensional rational polygon. A rational polygon is one whose vertices have rational coordinates. We find that the basic building blocks of…

Combinatorics · Mathematics 2007-05-23 Matthias Beck , Sinai Robins

The 1/r Coulomb potential is calculated for a two dimensional system with periodic boundary conditions. Using polynomial splines in real space and a summation in reciprocal space we obtain numerically optimized potentials which allow us…

Other Condensed Matter · Physics 2016-03-15 Markus Holzmann , Bernard Bernu

An alternative methodology to evaluate two-electron-repulsion integrals based on numerical approximation is proposed. Computational chemistry has branched into two major fields with methodologies based on quantum mechanics and classical…

Chemical Physics · Physics 2016-09-22 Pedro E. M. Lopes
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