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Present-day thermodynamics has long outgrown the initial frames of the heat-engine theory and transmuted into a rather general macroscopic method for studying kinetics of various transfer processes in their inseparable connection with the…

General Physics · Physics 2014-04-02 V. A Etkin

Classical and multiscale non-equilibrium thermodynamics have different histories and different objectives. In this Note we explain the differences and review some topics in which the multiscale viewpoint of mesoscopic time evolution of…

Statistical Mechanics · Physics 2025-10-02 Miroslav Grmela , Michal Pavelka

A quantum system at equilibrium is represented by a corresponding classical system, chosen to reproduce thermodynamic and structural properties. The motivation is to allow application of classical strong coupling theories and molecular…

Statistical Mechanics · Physics 2013-03-14 James Dufty , Sandipan Dutta

Thermodynamics is usually developed starting from entropy and the maximum entropy principle. We investigate here to what extent one can replace entropy with relative entropy which has several advantages, for example in the context of local…

Statistical Mechanics · Physics 2020-11-17 Stefan Floerchinger , Tobias Haas

The purpose of this study is to consider the near future of civilization in the framework of thermodynamics. Kardashev's proposal to evaluate the development of celestial civilizations by the amount of energy they are able to use was…

Physics and Society · Physics 2021-07-12 Vladimir Kh. Dobruskin

In these decades, it has been revealed that there is rich information-theoretic structure in thermodynamics of out-of-equilibrium systems in both the classical and quantum regimes. This has led to the fruitful interplay among statistical…

Quantum Physics · Physics 2020-09-29 Takahiro Sagawa

We show that when the thermal wavelength is comparable to the spatial size of a system, thermodynamic observables like Pressure and Volume have quantum fluctuations that cannot be ignored. They are now represented by operators; conventional…

Statistical Mechanics · Physics 2008-07-30 Antonin Coutant , S. G. Rajeev

Microscopic thermal machines promise to play an important role in future quantum technologies. Making such devices widely applicable will require effective strategies to channel their output into easily accessible storage systems like…

Statistical Mechanics · Physics 2024-10-02 Joshua Eglinton , Federico Carollo , Igor Lesanovsky , Kay Brandner

A comparative analysis of two concepts aimed at microscopic substantiation of thermodynamics and kinetics has been performed. The first concept is based on the idea of microscopic reversibility of the dynamics of a system of particles,…

Statistical Mechanics · Physics 2024-02-28 A. Yu. Zakharov

Two approaches to describe the thermodynamics of a subsystem that interacts with a thermal bath are considered. Within the first approach, the mean system energy $E_{S}$ is identified with the expectation value of the system Hamiltonian,…

Statistical Mechanics · Physics 2009-07-08 M. F. Gelin , M. Thoss

Extremal principles can generally be divided into two rather distinct classes. There are, on the one hand side, formulations based on the Lagrangian or Hamiltonian mechanics, respectively, dealing with time dependent problems, but…

Computational Engineering, Finance, and Science · Computer Science 2023-11-08 Klaus Hackl , Jiří Svoboda , Franz Dieter Fischer

A gas in a box is perhaps the most important model system studied in thermodynamics and statistical mechanics. Usually, studies focus on the gas, whereas the box merely serves as an idealized confinement. The present article focuses on the…

A quantum system at equilibrium is represented by a corresponding classical system, chosen to reproduce the thermodynamic and structural properties. The objective is to develop a means for exploiting strong coupling classical methods (e.g.,…

Statistical Mechanics · Physics 2015-05-30 James W. Dufty , Sandipan Dutta

The development of a self-consistent thermodynamic theory of quantum systems is of fundamental importance for modern physics. Still, despite its essential role in quantum science and technology, there is no unifying formalism for…

Quantum Physics · Physics 2022-11-30 André Malavazi , Frederico Brito

The theory of quantum thermodynamics investigates how the concepts of heat, work, and temperature can be carried over to the quantum realm, where fluctuations and randomness are fundamentally unavoidable. Of particular practical relevance…

Quantum Physics · Physics 2019-09-23 Patrick P. Potts

Stochastic thermodynamics is a framework for describing non-equilibrium processes at the level of fluctuating trajectories, where the state of a system evolves as a stochastic time series, allowing thermodynamic quantities such as work,…

A thermodynamic approach to the description of economic systems and processes is developed. It is shown that there is a deep analogy between the parameters of thermodynamic and economic systems (markets); so each thermodynamic parameter can…

General Physics · Physics 2021-08-18 Sergey Rashkovskiy

On the basis of new, concise foundations, this paper establishes the four laws of thermodynamics, the Maxwell relations, and the stability requirements for response functions, in a form applicable to global (homogeneous), local…

Statistical Mechanics · Physics 2007-05-28 Arnold Neumaier

In a macroscopic (quantum or classical) Hamiltonian system, we prove the second law of thermodynamics in the forms of the minimum work principle and the law of entropy increase, under the assumption that the initial state is described by a…

Statistical Mechanics · Physics 2007-05-23 Hal Tasaki

The usual canonical Hamiltonian or Lagrangian formalism of classical mechanics applied to macroscopic systems describes energy conserving adiabatic motion. If irreversible diabatic processes are to be included, then the law of increasing…

Classical Physics · Physics 2009-11-13 J. Silverberg , A. Widom
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