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The basic physics of nucleation in solid \hl{single-crystal} nanoparticles is revealed by a phase-field theory that includes surface energy, chemical reactions and coherency strain. In contrast to binary fluids, which form arbitrary contact…

Materials Science · Physics 2014-09-17 Daniel A. Cogswell , Martin Z. Bazant

Electrostatic interactions provide a convenient way to modulate interactions between nanoparticles, colloids, and biomolecules because they can be adjusted by the solution pH or salt concentration. While the presence of salt provides an…

Soft Condensed Matter · Physics 2019-09-04 Sawyer S. Hopkins , Amitabha Chakrabarti , Jeremy D. Schmit

It is well-known that the swelling behavior of ionic nanogels depends on their cross-link density, however it is unclear how different topologies should affect the response of the polyelectrolyte network. Here we perform Monte Carlo…

Soft Condensed Matter · Physics 2016-03-23 Leandro G. Rizzi , Yan Levin

Electric charge density in a metallic nanoparticle fluctuates due to inhomogeneities of various kinds. While in the bulk these fluctuations are compensated via Thomas--Fermi screening, residual surface charges give rise to a permanent…

Mesoscale and Nanoscale Physics · Physics 2010-08-27 A. V. Shytov , M. Pustilnik

The polar states of uniaxial ferroelectric nanoparticles interacting with a surface system of electronic and ionic charges with a broad distribution of mobilities is explored, which corresponds to the experimental case of nanoparticles in…

Bipolar nanopores have powerful rectification properties due to the asymmetry in the charge pattern on the wall of the nanopore. In particular, bipolar nanopores have positive and negative surface charges along the pore axis. Rectification…

Soft Condensed Matter · Physics 2020-11-25 Dávid Fertig , Mónika Valiskó , Dezső Boda

Nanocrystal gelation provides a powerful framework to translate nanoscale properties into bulk materials and to engineer emergent properties through the assembled microstructure. However, many established gelation strategies rely on…

Magnetohydrodynamically induced interface instability in liquid metal batteries is analyzed. The batteries are represented by a simplified system in the form of a rectangular cell, in which strong vertical electric current flows through…

Fluid Dynamics · Physics 2018-04-12 Oleg Zikanov

Ionic liquids are promising candidates for novel electrolytes as they possess large electrochemical and thermodynamic stability and offer a high degree of tunability. As purely-ionic electrolyte without neutral solvent they exhibit…

Chemical Physics · Physics 2022-01-12 Max Schammer , Birger Horstmann , Arnulf Latz

Electrostatic correlations and variable permittivity of electrolytes are essential for exploring many chemical and physical properties of interfaces in aqueous solutions. We propose a continuum electrostatic model for the treatment of these…

Soft Condensed Matter · Physics 2015-06-23 Manman Ma , Zhenli Xu

A self-consistent theory of bulk electrolytes incorporating electrostatic and hard-core interactions on an equal level is applied to the two-dimensional Coulomb liquid with finite ion size. The ionic pair distributions, the structure…

Soft Condensed Matter · Physics 2026-04-10 Sahin Buyukdagli

Applying electric fields is an attractive way to control and manipulate single particles or molecules, e.g., in lab-on-a-chip devices. However, the response of nanosize objects in electrolyte solution to external fields is far from trivial.…

Soft Condensed Matter · Physics 2015-11-09 Jiajia Zhou , Friederike Schmid

The ionic selectivity of nanopores is crucial for the energy conversion based on nanoporous membranes. It can be significantly affected by various parameters of nanopores and the applied fields driving ions through porous membranes. Here,…

Soft Condensed Matter · Physics 2024-10-29 Chao Zhang , Mengnan Guo , Hongwen Zhang , Xiuhua Ren , Yinghao Gao , Yinghua Qiu

We investigate active electrolytes within the mean-field level of description. The focus is on how the double-layer structure of passive, thermalized charges is affected by active dynamics of all constituting ions. One feature of active…

Soft Condensed Matter · Physics 2018-05-23 Derek Frydel , Rudolf Podgornik

Polarizability tensor of a strongly magnetized plasma and the polarization vectors and opacities of normal electromagnetic waves are studied for the conditions typical of neutron star atmospheres, taking account of partial ionization…

Astrophysics · Physics 2009-11-10 A. Y. Potekhin , Dong Lai , G. Chabrier , W. C. G. Ho

Charge profiles in liquid electrolytes are of crucial importance for applications, such as supercapacitors, fuel cells, batteries, or the self-assembly of particles in colloidal or biological settings. However, creating localised (screened)…

Soft Condensed Matter · Physics 2021-03-17 Jeffrey C. Everts , Miha Ravnik

Freezing of simple liquid metals and the relative stabilities of competing crystalline solids are investigated using thermodynamic perturbation theory, the interactions between ions being modeled by effective pair potentials derived from…

Materials Science · Physics 2009-10-31 A. R. Denton , G. Kahl , J. Hafner

A cluster consisting of many atoms or molecules may be considered, in some circustances, to be a single large molecule with a well defined polarizability. Once the polarizability of such a cluster is known, one can evaluate certain…

Materials Science · Physics 2009-11-11 Hye-Young Kim , Jorge O. Sofo , Darrell Velegol , Milton W. Cole , Gautam Mukhopadhyay

Magnetic nanoparticles have many applications in biomedicine and other technical areas. Despite their huge economic impact, there are no standardised procedures available to measure their basic magnetic properties. The International…

Correlative light and electron microscopy promises to combine molecular specificity with nanoscale imaging resolution. However, there are substantial technical challenges including reliable co-registration of optical and electron images,…