Related papers: Extending the view of ArH+ chemistry in diffuse cl…

The H3O+ molecule probes the oxygen chemistry and the ionization rate of dense circumnuclear gas in galaxies. In particular, recent H3O+ observations show variations in the cosmic-ray ionization rate by factors of $>$10 within our Galaxy.…

Chemistry in diffuse molecular clouds relies primarily on rapid ion-molecule reactions. Formation of the initial ions, H$^+$ and H$_2^+$, is dominated by cosmic-ray ionization of H and H$_2$, making the cosmic-ray ionization rate (denoted…

Near ultraviolet observations of OH+ and OH in diffuse molecular clouds reveal a preference for different environments. The dominant absorption feature in OH+ arises from a main component seen in CH+ (that with the highest CH+/CH column…

We describe the assignment of a previously unidentified interstellar absorption line to ArH$^+$ and discuss its relevance in the context of hydride absorption in diffuse gas with a low H$_2$ fraction. The column densities along several…

Absorption lines from the molecules OH+, H2O+, and H3+ have been observed in a diffuse molecular cloud along a line of sight near W51 IRS2. We present the first chemical analysis that combines the information provided by all three of these…

Ions (e.g., H$_3^+$, H$_2$O$^+$) have been used extensively to quantify the cosmic-ray ionization rate (CRIR) in diffuse sightlines. However, measurements of CRIR in low-to-intermediate density gas environments are rare, especially when…

We combine Herschel observations of a total of 12 sources to construct the most uniform survey of HF and H2O in our Galactic disk. Both molecules are detected in absorption along all sight lines. The high spectral resolution of the…

We have observed CH absorption lines ($J=3/2, N=1 \leftarrow J=1/2, N=1$) against the continuum source Sgr~B2(M) using the \textit{Herschel}/HIFI instrument. With the high spectral resolution and wide velocity coverage provided by HIFI, 31…

The cosmic-ray ionization rate (zeta) of dense molecular clouds is a key parameter for their dynamics and chemistry. Variations of zeta are well established, but it is unclear if these are related to source column density or to Galactic…

We report the detection of OH+ and H2O+ in the z=0.89 absorber toward the lensed quasar PKS1830-211. The abundance ratio of OH+ and H2O+ is used to quantify the molecular hydrogen fraction (fH2) and the cosmic-ray ionization rate of atomic…

Observations of H3+ in the Galactic diffuse interstellar medium (ISM) have led to various surprising results, including the conclusion that the cosmic-ray ionization rate (zeta_2) is about 1 order of magnitude larger than previously…

To date O2 has definitely been detected in only two sources, namely rho Oph A and Orion, reflecting the extremely low abundance of O2 in the interstellar medium. One of the sources in the HOP program is the +50 km/s Cloud in the Sgr A…

The ``integral-shaped filament'' of the Orion A giant molecular cloud was mapped in N2H+, and its northern end, the OMC-2/3 region was observed also in HC3N and CCS. The N2H+ distribution is similar to the dust continuum distribution,…

We report on the first far-IR detection of H2D+, using the Infrared Space Observatory, in the line of sight toward Sgr B2 in the galactic center. The transition at 126.853 um connecting the ground level of o-H2D+, 1_1,1 with the the 2_1,2…

Noble gas molecules have not hitherto been detected in space. From spectra obtained with the Herschel Space Observatory, we report the detection of emission in the 617.5 GHz and 1234.6 GHz J = 1-0 and 2-1 rotational lines of {36}ArH^+ at…

We identify a prominent absorption feature at 1115 GHz, detected in first HIFI spectra towards high-mass star-forming regions, and interpret its astrophysical origin. The characteristic hyperfine pattern of the H2O+ ground-state rotational…

The understanding of interstellar nitrogen chemistry has improved significantly with recent results from the Herschel Space Observatory. To set even better constraints, we report here on deep searches for the NH+ ground state rotational…

We present interferometric observations of the CN 1-0 (113.491 GHz), N2H+ 1-0 (93.173 GHz), H(41)a (92.034 GHz), CH3CN (91.987 GHz), CS 3-2 (146.969 GHz), c-C3H2 3-2 (145.089 GHz), H2CO 2-1 (145.603 GHz) and HC3N 16-15 (145.601 GHz) lines…

We present follow-up observations to those of Geballe & Oka (2010), who found high column densities of H3+ ~100 pc off of the Galactic center (GC) on the lines of sight to 2MASS J17432173-2951430 (J1743) and 2MASS J17470898-2829561 (J1747).…

Observations of OH$^+$ are used to infer the interstellar cosmic ray ionization rate in diffuse atomic clouds, thereby constraining the propagation of cosmic rays through and the shielding by interstellar clouds, as well as the low energy…