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The dipole flexoelectric (FE) polarization in liquid crystals is derived in the thermodynamic limit at small distortions and small density. General microscopic expressions for the FE coefficients are obtained in the case of the uniaxial and…

Soft Condensed Matter · Physics 2009-10-15 A. Kapanowski

The propagation front of a crack generates large strain gradients and it is therefore a strong source of gradient-induced polarization (flexoelectricity). Herein, we demonstrate that, in piezoelectric materials, a consequence of…

Materials Science · Physics 2019-04-10 Kumara Cordero-Edwards , Hoda Kianirad , Jordi Sort , Carlota Canalias , Gustau Catalan

We predict a large in-plane polarization response to bending in a broad class of trigonal two-dimensional crystals. We define and compute the relevant flexoelectric coefficients from first principles as linear-response properties of the…

Materials Science · Physics 2023-08-01 Matteo Springolo , Miquel Royo , Massimiliano Stengel

The electrical conductivity of graphene with a nonzero mass-gap parameter is investigated starting from the first principles of quantum electrodynamics in (2+1)-dimensional space-time at any temperature. The formalism of the polarization…

Mesoscale and Nanoscale Physics · Physics 2016-11-07 G. L. Klimchitskaya , V. M. Mostepanenko

Upon application of a uniform strain, internal sub-lattice shifts within the unit cell of a non-centrosymmetric dielectric crystal result in the appearance of a net dipole moment: a phenomenon well known as piezoelectricity. A macroscopic…

Materials Science · Physics 2015-05-13 R. Maranganti , P. Sharma

We present a computationally efficient method to incorporate density-functional theory into the calculation of reflectivity in low-energy electron microscopy. The reflectivity is determined by matching plane waves representing the electron…

Materials Science · Physics 2013-11-13 John F. McClain , Jiebing Sun , Karsten Pohl , Jian-Ming Tang

We study the influence of transverse electric fields on the interfacial forces between a graphene layer and a carbon nanotube tip by means of atomistic simulations, in which a Gaussian regularized charge-dipole potential is combined with…

Materials Science · Physics 2019-07-18 Zhao Wang

The flexoelectric (FE) effect provides a linear coupling between electric polarization and orientational deformation in liquid crystals. It influences many electrooptical phenomena and it is used in some bistable nematic devices. A…

Soft Condensed Matter · Physics 2023-07-19 A. Kapanowski

We theoretically demonstrate that an external magnetic field can be used to control quantum reflection of matter waves in graphene due to its extraordinary magneto-optical properties. We calculate the quantum reflection probabilities in…

Quantum Physics · Physics 2019-09-06 Marcius Silvestre , Tarik P. Cysne , Daniela Szilard , Felipe A. Pinheiro , Carlos Farina

The Seebeck coefficient is an important quantity in determining the thermoelectric efficiency of a material. Phosphorene is a two-dimensional material with a puckered structure, which makes its properties anisotropic. In this work, a…

Materials Science · Physics 2023-01-05 M. Amir Bazrafshan , Farhad Khoeini

We review existing manifestations and prospects for ferroelectricity in electronically and optically active carbon-based materials. The focus point is the proposal for the electronic ferroelectricity in conjugated polymers from the family…

Materials Science · Physics 2015-12-15 Natasha Kirova , Serguei Brazovskii

The recently discovered ferroelectric nematic liquids incorporate to the functional combination of fluidity, processability and anisotropic optical properties of nematic liquids, an astonishing range of physical properties derived from the…

Graphene's structure bears on both the material's electronic properties and fundamental questions about long range order in two-dimensional crystals. We present an analytic calculation of selected area electron diffraction from multi-layer…

Mesoscale and Nanoscale Physics · Physics 2015-03-20 Brian Shevitski , Matthew Mecklenburg , William A. Hubbard , E. R. White , Ben Dawson , M. S. Lodge , Masa Ishigami , B. C. Regan

Flexoelectricity is the polar response of an insulator to strain gradients such as bending. While the size dependence of this effect makes it weak in bulk systems in comparison to piezoelectricity, it suggests that it plays a bigger role in…

Mesoscale and Nanoscale Physics · Physics 2022-08-12 Daniel Bennett

The behavior of ferroelectricity at the nanoscale is the focus of increasing research activity because of intense interest in the fundamental nature of spontaneous order in condensed-matter systems and because of the many practical…

In this Chapter we provide an overview of the current first-principles perspective on flexoelectric effects in crystalline solids. We base our theoretical formalism on the long-wave expansion of the electrical response of a crystal to an…

Materials Science · Physics 2015-07-29 Massimiliano Stengel , David Vanderbilt

We present a tight-binding parametrization for penta-graphene that correctly describes its electronic band structure and linear optical response. The set of parameters is validated by comparing to ab-initio density functional theory…

Materials Science · Physics 2020-12-25 Sergio Bravo , J. D. Correa , Leonor Chico , M. Pacheco

Proximity ferroelectricity is a novel paradigm for inducing ferroelectricity in a non-ferroelectric polar material such as AlN or ZnO that are typically unswitchable with an external field below their dielectric breakdown field. When placed…

The in-plane infinitesimal deformations of graphene are well understood: they can be computed by solving the equilibrium problem for a sheet of isotropic elastic material with suitable stretching stiffness and Poisson coefficient…

Materials Science · Physics 2017-08-02 Cesare Davini , Antonino Favata , Roberto Paroni

Understanding the nature of brittle failure in ferroelectric materials is essential, but difficult due to the complex interaction between mechanical and electrical concentrated fields near the crack tip. In this work, an extended…

Materials Science · Physics 2024-05-22 Chang Liu , Yu Tan , Yong Zhang , Zhaoyi Liu , Takahiro Shimada , Xiangyu Li , Jie Wang