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Graphynes offer a chemically heterogeneous $sp/sp^{2}$ carbon framework with distinct electronic regimes and site-selective reactivity. Here, Density Functional Theory and Reactive Molecular Dynamics Simulations are combined to evaluate…

Recent progress in porous carbon materials has highlighted the importance of structural design in controlling emergent physicochemical properties. In this context, hydrogen-substituted graphdiyne (HsGDY), a three-dimensional framework…

Graphene- the wonder material has attracted a great deal of attention from varied fields of condensed matter physics, materials science and chemistry in recent times. Its 2D atomic layer structure and unique electronic band structure makes…

Materials Science · Physics 2011-08-23 Deep Jariwala , Anchal Srivastava , Pulickel Ajayan

Atoms deposited on two-dimensional (2D) electronic materials, such as graphene, can exhibit unconventional many-body correlations, not accessible in other settings. All of these are driven by van der Waals forces: between the atoms…

Mesoscale and Nanoscale Physics · Physics 2022-01-13 Adrian Del Maestro , Carlos Wexler , Juan M. Vanegas , Taras Lakoba , Valeri N. Kotov

Graphyne nanotubes (GNTs) are nanostructures obtained from rolled up graphyne sheets, in the same way carbon nanotubes (CNTs) are obtained from graphene ones. Graphynes are 2D carbon-allotropes composed of atoms in sp and sp2 hybridized…

Recent intensive research on two-dimensional materials (2DMs) rekindle the interest in the intercalation of various atoms and molecules into layered compounds as a tool to manufacture 2DMs and tune their optoelectronic, magnetic and…

Mesoscale and Nanoscale Physics · Physics 2025-07-10 Arkady V. Krasheninnikov , Yung-Chang Lin , Kazu Suenaga

Pairing of $\pi$ electronic state structures with functional or metallic atoms makes them possible to engineer physical and chemical properties. Herein, we predict the reorientation of magnetization of Co on hexagonal BN (h-BN) and graphene…

Materials Science · Physics 2025-04-28 D. Odkhuu , T. Tsevelmaa , P. Taivansaikhan , N. Park , S. C. Hong , S. H. Rhim

Graphene is known as a two-dimensional Dirac semimetal, in which electron states are described by the Dirac equation of relativistic quantum mechanics. Three-dimensional analogues of graphene are characterized by Dirac points or lines in…

Mesoscale and Nanoscale Physics · Physics 2017-08-16 Ha-Jun Sung , Sunghyun Kim , In-Ho Lee , K. J. Chang

Monolithic structures can be built into graphene by the addition and subsequent re-arrangement of carbon atoms. To this end, ad-dimers of carbon are a particularly attractive building block because a number of emerging technologies offer…

Materials Science · Physics 2010-09-09 Mark T. Lusk , L. D. Carr

Starting from the planar molecule 1,3,5-trihydroxybenzene, Du et al. reported synthesizing one of a couple of possible 2D materials: graphenylene or 3-carbophene. 3-carbophene is a member of a novel class of two-dimensional covalent organic…

Materials Science · Physics 2022-03-10 Chad E. Junkermeier , George Psofogiannakis , Ricardo Paupitz

Searching for three-dimensional(3D) semiconducting carbon allotropes with proper bandgaps and excellent optoelectronic properties is always the chasing goal for the new emerging all-carbon optoelectronics. On the other side, 3D carbon…

Materials Science · Physics 2019-08-21 Chengyong Zhong , Wenxia Zhang , Guangqian Ding , Junjie He

The recent progress in formation of two-dimensional (2D) GaN by a migration-enhanced encapsulated technique opens up new possibilities for group III-V 2D semiconductors with a band gap within the visible energy spectrum. Using…

Materials Science · Physics 2017-11-01 C. Pashartis , O. Rubel

Penta-Graphene (PG) was theoretically proposed as a new carbon allotrope with a 2D structure. PG has revealed interesting gas sensing properties. Here, the structural and electronic properties of defective PG lattices interacting with an…

At present, Pt nanoparticle catalysts in fuel cells suffer from aggregation and loss of chemical activity. In this work, graphdiyne, which has natural porous structure, was proposed as substrate with high adsorption ability to stabilize Pt…

Mesoscale and Nanoscale Physics · Physics 2015-03-03 Zheng-Zhe Lin

We show that patterned defects can be used to disrupt the sub-lattice symmetry of graphene so as to open up a band gap. This way of modifying graphene's electronic structure does not rely on external agencies, the addition of new elements…

Mesoscale and Nanoscale Physics · Physics 2010-09-09 David J. Appelhans , Zhibin Lin , Mark T. Lusk

The folding of paper, hide, and woven fabric has been used for millennia to achieve enhanced articulation, curvature, and visual appeal for intrinsically flat, two-dimensional materials. For graphene, an ideal two-dimensional material,…

We have investigated the structural, mechanical and electronic properties of D-carbon by ab initio calculations, a new phase of crystalline sp3 carbon (pace group D2h5, Pmma-orthorhombic). Total-energy calculations demonstrate that D-carbon…

Materials Science · Physics 2020-04-15 Dong Fan , Shaohua Lu , Xiaojun Hu

Graphite oxide is an amorphous insulator. Although several models have been suggested, its structure remains controversial. To elucidate this issue, 5 samples were prepared by the Brodie process and the Staudenmaier process. The electronic…

Materials Science · Physics 2011-03-03 D. W. Lee , J. W. Seo

Nowadays sp carbon chains terminated by graphene or graphitic-like carbon are synthesized routinely in several nanotech labs. We propose an ab-initio study of such carbon-only materials, by computing their structure and stability, as well…

Mesoscale and Nanoscale Physics · Physics 2015-05-30 Ivano E. Castelli , Nicola Ferri , Giovanni Onida , Nicola Manini

Graphene monolayer is a material with zero band gap, because of which its applications in optoelectronics are limited. The question arises, can we modify the optoelectronic properties of graphene by doping it with other atoms? Synthesis of…

Materials Science · Physics 2026-03-18 Samayita Das , Alok Shukla