English
Related papers

Related papers: Coupled Cluster Externally Corrected by Adaptive C…

200 papers

The combinatorial scaling of configuration interaction (CI) has long restricted its applicability to only the simplest molecular systems. Here, we report the first numerically exact CI calculation exceeding one quadrillion ($10^{15}$)…

Chemical Physics · Physics 2025-12-16 Agam Shayit , Can Liao , Shiv Upadhyay , Hang Hu , Tianyuan Zhang , Eugene DePrince , Chao Yang , Xiaosong Li

Heavy atom compounds represent a challenge for computational chemistry, due to the need for simultaneous treatment of relativistic and correlation effects. Often such systems exhibit also strong correlation which hampers the application of…

Chemical Physics · Physics 2025-02-10 Jakub Višňák , Jan Brandejs , Mihály Máté , Lucas Visscher , Örs Legeza , Jiří Pittner

We present a fully variational locally scaled self-interaction corrected (SIC) energy functional using complex optimal orbitals. This represents an important milestone for fully variational SIC energy functionals, which have been shown to…

Attributed graph clustering is challenging as it requires joint modelling of graph structures and node attributes. Recent progress on graph convolutional networks has proved that graph convolution is effective in combining structural and…

Machine Learning · Computer Science 2019-06-05 Xiaotong Zhang , Han Liu , Qimai Li , Xiao-Ming Wu

Federated Learning (FL) faces major challenges in real-world deployments due to statistical heterogeneity across clients and system heterogeneity arising from resource-constrained devices. While clustering-based approaches mitigate…

Machine Learning · Computer Science 2026-03-03 Om Govind Jha , Harsh Shukla , Haroon R. Lone

Adaptive Conformal Inference (ACI) provides distribution-free prediction intervals with asymptotic coverage guarantees for time series under distribution shift. However, ACI only adapts the quantile threshold -- it cannot shift the interval…

Machine Learning · Computer Science 2026-04-16 Ankit Lade , Sai Krishna J. , Indar Kumar

We consider analog over-the-air federated learning, where devices harvest energy from in-band and out-band radio frequency signals, with the former also causing co-channel interference (CCI). To mitigate the aggregation error, we propose an…

Information Theory · Computer Science 2025-09-15 Ahmad Massud Tota Khel , Aissa Ikhlef , Zhiguo Ding , Hongjian Sun

In this paper a novel possibilistic c-means clustering algorithm, called Adaptive Possibilistic c-means, is presented. Its main feature is that {\it all} its parameters, after their initialization, are properly adapted during its execution.…

Computer Vision and Pattern Recognition · Computer Science 2015-10-16 Spyridoula D. Xenaki , Konstantinos D. Koutroumbas , Athanasios A. Rontogiannis

Connectionist Temporal Classification (CTC) is a widely used approach for automatic speech recognition (ASR) that performs conditionally independent monotonic alignment. However for translation, CTC exhibits clear limitations due to the…

Computation and Language · Computer Science 2022-10-12 Brian Yan , Siddharth Dalmia , Yosuke Higuchi , Graham Neubig , Florian Metze , Alan W Black , Shinji Watanabe

In many health policy settings, adaptive interventions target a population of clusters (e.g., schools), with the ultimate intent of impacting outcomes at the level of individuals within the clusters. Health policy researchers can use…

We consider the simultaneous clustering of rows and columns of a matrix and more particularly the ability to measure the agreement between two co-clustering partitions. The new criterion we developed is based on the Adjusted Rand Index and…

Applications · Statistics 2020-12-16 Valerie Robert , Yann Vasseur , Vincent Brault

The fundamental non-Hermitian nature of the forms of coupled-cluster (CC) theory widely used in quantum chemistry has usually been viewed as a negative, but the present letter shows how this can be used to advantage. Specifically, the…

Conformal Inference (CI) is a popular approach for generating finite sample prediction intervals based on the output of any point prediction method when data are exchangeable. Adaptive Conformal Inference (ACI) algorithms extend CI to the…

Computation · Statistics 2023-12-04 Herbert Susmann , Antoine Chambaz , Julie Josse

Correlation Clustering (CC) is a foundational problem in unsupervised learning that models binary similarity relations using labeled graphs. While classical CC has been widely studied, many real-world applications involve more nuanced…

Data Structures and Algorithms · Computer Science 2025-09-23 Chenglin Fan , Dahoon Lee , Euiwoong Lee

Wave functions based on electron-pair states provide inexpensive and reliable models to describe quantum many-body problems containing strongly-correlated electrons, given that broken-pair states have been appropriately accounted for by,…

Chemical Physics · Physics 2021-03-17 Artur Nowak , Ors Legeza , Katharina Boguslawski

Time-dependent coupled-cluster method with time-varying orbital functions, called time-dependent optimized coupled- cluster (TD-OCC) method, is formulated for multielectron dynamics in an intense laser field. We have successfully derived…

Chemical Physics · Physics 2018-03-14 Takeshi Sato , Himadri Pathak , Yuki Orimo , Kenichi L. Ishikawa

Quantum embedding methods have recently developed significantly to model large molecular structures. This work proposes a novel wave function theory in density functional theory (WTF-in-DFT) embedding scheme based on pair-coupled cluster…

Chemical Physics · Physics 2024-01-10 Rahul Chakraborty , Katharina Boguslawski , Paweł Tecmer

This is a continuation of the previous work (arXiv:2403.10128). Additional aspects such as linear combinations of projections and hash-table canonicalizations are described. Implementations of the general-order partial-spin adaptation (PSA)…

Chemical Physics · Physics 2025-01-02 Cong Wang

The problem of orbital relaxation in computational core-hole spectroscopies, including x-ray absorption and x-ray photoionization, has long plagued linear response approaches, including equation-of-motion coupled cluster with singles and…

Chemical Physics · Physics 2025-03-26 Megan E. Simons , Devin A. Matthews

We tackle the challenge of estimating grouping structures and factor loadings in asset pricing models, where traditional regressions struggle due to sparse data and high noise. Existing approaches, such as those using fused penalties and…

Methodology · Statistics 2025-12-30 Liyuan Cui , Guanhao Feng , Yuefeng Han , Jiayan Li