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Vibrational spectroscopy is a ubiquitous technology that derives the species, constituents, and morphology of an object from its natural vibrations. However, the vibrational spectra of mesoscopic particles - including most biological cells…

Molecular ions can be held in a chain of laser-cooled atomic ions by sympathetic cooling. This system is ideal for performing high-precision molecular spectroscopy with applications in astrochemistry and fundamental physics. Here we show…

Atomic Physics · Physics 2015-08-20 Ncamiso B. Khanyile , Gang Shu , Kenneth R. Brown

We show that combining vibrational spectroscopy with signal processing can result in a scheme for ultrasensitive detection of molecules. We consider the vibrational spectrum as a signal on the energy axis and apply a matched filter on that…

Computational Physics · Physics 2018-12-10 Tay Yong Boon , Ian Tay Rongde , Loy Liang Yi , Aw Ke Fun , Ong Zhi Li , Sergei Manzhos

Transmission electron microscopy and spectroscopy currently enable the acquisition of spatially resolved spectral information from a specimen by focusing electron beams down to a sub-Angstrom spot and then analyzing the energy of the…

Materials Science · Physics 2022-09-12 Andrea Konečná , Fadil Iyikanat , F. Javier García de Abajo

We demonstrate a novel method to determine the longitudinal phase-space distribution of a cryogenic buffer gas beam of barium-fluoride molecules based on a two-step laser excitation scheme. The spatial resolution is achieved by a…

As molecular dynamics is increasingly used to characterize non-crystalline materials, it is crucial to verify that the numerical model is accurate enough, consistent with experimental data and can be used to extract various characteristics…

Disordered Systems and Neural Networks · Physics 2008-11-17 F. Gaspari , I. M. Kupchak , A. I. Shkrebtii , J. M. Perz

Analysis of signal fluctuations of a locally fixed probe, caused by molecules diffusing under the probe, can be used to determine diffusion coefficients. Theoretical treatments so far have been limited to point-like particles or to…

Statistical Mechanics · Physics 2015-06-18 Susanne Hahne , Philipp Maass

Recently, we have demonstrated a method to record the longitudinal phase-space distribution of a pulsed cryogenic buffer gas cooled beam of barium fluoride molecules. In this paper, we use this method to determine the influence of various…

The detection of vibrational excitations of individual molecules on surfaces by scanning tunneling spectroscopy does not obey strict selection rules but rather propensity rules. The experimental verification of these is challenging because…

Using the measurements collected at a number of known locations by a moving binary sensor, characterised by an unknown threshold, the problem is to estimate the parameters of a biochemical source, continuously releasing material into the…

Applications · Statistics 2016-08-24 Branko Ristic , Ajith Gunatilaka , Ralph Gailis

Understanding the interfacial properties of aerosol particles is important for science and medicine, crucial for air quality, human health, and environmental chemistry. Qian et al. presented vibrational sum frequency scattering (SFS)…

Chemical Physics · Physics 2023-05-04 Arianna Marchioro , Thaddeus W. Golbek , Adam S. Chatterley , Tobias Weidner , Sylvie Roke

High-bandwidth and multi-point acoustic and vibration sensing is a critical asset for real-time condition monitoring, maintenance, and surveillance applications. In the case of large scales and harsh environments, optical fiber distributed…

The evolution from 3rd to 4th generation synchrotron radiation (SR) sources provide promising potential improvements in X-ray techniques, particularly in spatial resolution for imaging, temporal resolution for dynamic studies, and beam size…

Optics · Physics 2025-03-19 Han Xu , Xiao Li , Ming Li , Zhe Ren , Yi Zhang , Peng Liu , Yuhui Dong , Liang Zhou

Single molecule Raman spectroscopy provides information on individual molecules with vibrational-level resolution. The unique mechanisms leading to the huge Raman cross-section enhancement necessary for single molecule sensitivity are under…

Materials Science · Physics 2007-05-23 Gilad Haran

A full density-matrix simulation is performed for optical deflection of a barium monofluoride ($^{138}$Ba$^{19}$F) beam using the bichromatic force, which employs pairs of counter-propagating laser beams that are offset in frequency. We…

Atomic Physics · Physics 2023-07-26 A. Marsman , M. Horbatsch , E. A. Hessels

A method is proposed for deriving the dispersion measure (related to the line-of-sight integrated free electron density) to high-redshift, powerful synchrotron radio sources by analysis of the temporal/spectral properties of the recorded…

Cosmology and Nongalactic Astrophysics · Physics 2015-06-15 R. V. E. Lovelace , D. W. Richards

In bulk systems, molecules are routinely identified by their vibrational spectrum using Raman or infrared spectroscopy. In recent years, vibrational excitation lines have been observed in low-temperature conductance measurements on single…

Mesoscale and Nanoscale Physics · Physics 2010-02-25 Johannes S. Seldenthuis , Herre S. J. van der Zant , Mark A. Ratner , Joseph M. Thijssen

We propose that fast radio bursts (FRBs) can be used as the probes to constrain the possible anisotropic distribution of baryon matter in the Universe. Monte Carlo simulations show that, 400 (800) FRBs are enough to detect the anisotropy at…

Cosmology and Nongalactic Astrophysics · Physics 2021-11-29 Hai-Nan Lin , Yu Sang

Granular gases are commonly characterized through their velocity distribution, which provides access to the granular temperature. In experiments, velocity distributions are typically obtained by particle tracking, which however becomes…

Methods of determining surface diffusion coefficients of molecules from signal fluctuations of a locally fixed probe are revisited and refined. Particular emphasis is put on the influence of the molecule's extent. In addition to the…

Mesoscale and Nanoscale Physics · Physics 2015-06-12 Susanne Hahne , Julian Ikonomov , Moritz Sokolowski , Philipp Maass
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