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A systematic study of the leading isotropic van der Waals coefficients for the alkali-metal atom + molecule and molecule + molecule systems is presented. Dipole moments and static and dynamic dipole polarizabilities are calculated employing…

Atomic Physics · Physics 2013-02-22 P. S. Zuchowski , M. Kosicki , M. Kodrycka , P. Soldan

We show that electrodynamic dipolar interactions, responsible for long-range fluctuations in matter, play a significant role in the stability of molecular crystals. Density functional theory calculations with van der Waals interactions…

A scheme within density functional theory is proposed that provides a practical way to generalize to unrestricted geometries the method applied with some success to layered geometries [H. Rydberg, et al., Phys. Rev. Lett. 91, 126402…

Materials Science · Physics 2009-11-10 M. Dion , H. Rydberg , E. Schroder , D. C. Langreth , B. I. Lundqvist

A van der Waals (vdW) density functional was implemented in the mixed basis approach previously developed for studying two dimensional systems, in which the vdW interaction plays an important role. The basis functions here are taken to be…

Computational Physics · Physics 2017-12-27 Chung-Yuan Ren , Yia-Chung Chang , Chen-Shiung Hsue

Heterostructures based on atomically thin semiconductors are considered a promising emerging technology for the realization of ultrathin and ultralight photovoltaic solar cells on flexible substrates. Much progress has been made in recent…

van der Waals stacking of two-dimensional (2D) materials offers a powerful platform for engineering material interfaces with tailored electronic and optical properties. While most van der Waals multilayers have featured inorganic…

Van der Waals forces as interactions between neutral and polarisable particles act at small distances between two objects. Their theoretical origin lies in the electromagnetic interaction between induced dipole moments caused by the vacuum…

Chemical Physics · Physics 2019-06-05 Johannes Fiedler , Clas Persson , Mathias Boström , Stefan Y. Buhmann

Theories for the effective polarisability of a small particle in a medium are presented using different levels of approximation: we consider the virtual cavity, real cavity and the hard-sphere models as well as a continuous interpolation of…

Path-integral molecular dynamics simulations based on density functional theory employing exchange-correlation density functionals capable of treating nonlocal van der Waals (vdW) interactions self-consistently provide a remarkably accurate…

Chemical Physics · Physics 2014-02-13 Jeffrey M. McMahon , Miguel A. Morales , Brian Kolb , Timo Thonhauser

The electronic structure of high-quality van der Waals NiPS$_3$ crystals was studied using near-edge x-ray absorption spectroscopy (NEXAFS) and resonant photoelectron spectroscopy (ResPES) in combination with density functional theory (DFT)…

To understand sparse systems we must account for both strong local atom bonds and weak nonlocal van der Waals forces between atoms separated by empty space. A fully nonlocal functional form [H. Rydberg, B.I. Lundqvist, D.C. Langreth, and M.…

Materials Science · Physics 2009-11-10 H. Rydberg , M. Dion , N. Jacobson , E. Schroder , P. Hyldgaard , S. I. Simak , D. C. Langreth , B. I. Lundqvist

The understanding of and control over light emission from quantum tunneling has challenged researchers for more than four decades due to the intricate interplay of electrical and optical properties in atomic scale volumes. Here we introduce…

Mesoscale and Nanoscale Physics · Physics 2019-01-23 Markus Parzefall , Áron Szabó , Takashi Taniguchi , Kenji Watanabe , Mathieu Luisier , Lukas Novotny

The ability to control the polarization of light at the extreme nanoscale has long been a major scientific and technological goal for photonics. Here we predict the phenomenon of polarization splitting through van der Waals heterostructures…

Optics · Physics 2018-07-20 Shahnawaz Shah , Xiao Lin , Lian Shen , Maturi Renuka , Baile Zhang , Hongsheng Chen

We have realized a hybrid solid-state quantum device in which a single-electron semiconductor double quantum dot is dipole coupled to a superconducting microwave frequency transmission line resonator. The dipolar interaction between the two…

We apply the modern technique of approximation of multivariate functions - tensor train cross approximation - to the problem of the description of physical interactions between complex-shaped bodies in a context of computational…

Computational Physics · Physics 2017-05-02 Grigory Drozdov , Igor Ostanin , Ivan Oseledets

The method recently developed to include Van der Waals interactions in the Density Functional Theory by using the Maximally-Localized Wannier functions, is improved and extended to the case of atoms and fragments weakly bonded (physisorbed)…

Other Condensed Matter · Physics 2009-11-13 Pier Luigi Silvestrelli , Karima Benyahia , Sonja Grubisic Francesco Ancilotto , Flavio Toigo

The electronic structure in unconventional superconductors holds a key to understand the momentum-dependent pairing interactions and the resulting superconducting gap function. In superconducting Fe-based chalcogenides, there have been…

Strongly Correlated Electrons · Physics 2021-02-24 Felix Lochner , Ilya M. Eremin , Tilmann Hickel , Jörg Neugebauer

Dispersion interactions are usually derived assuming fixed internal spectra of the interacting quantum systems. Here, we relax this assumption and study how self-consistent electromagnetic backaction modifies van der Waals interactions when…

Quantum Physics · Physics 2026-05-06 Johannes Fiedler

The van der Waals dispersion interaction between two chiral molecules in the presence of arbirary magnetoelectric media is derived using perturbation theory. To be general, the molecular polarisabilities are assumed to be of electric,…

Quantum Physics · Physics 2020-06-24 Hassan Safari , Pablo Barcellona , Stefan Yoshi Buhmann , Akbar Salam

We study the mutual interactions of simple, parallel polymers and nanotubes, and develop a scheme to include the van der Waals interactions in the framework of density functional theory (DFT) for these molecules at intermediate to…

Soft Condensed Matter · Physics 2007-05-23 Jesper Kleis , Per Hyldgaard , Elsebeth Schroder